Sulfonated Polyethersulfone Membranes for Brackish Water Desalination: Fabrication, Characterization, and Electrodialysis Performance Evaluation

The widespread application of electrodialysis is constrained by the high cost of ion exchange membranes, necessitating the development of affordable alternatives. This study focuses on the fabrication and performance evaluation of cation exchange membranes made from polyethersulfone (PES) and sulfon...

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Main Authors: Li Chen, Eva M. Deemer, XiuJun Li, W. Shane Walker
Format: Article
Language:English
Published: MDPI AG 2024-12-01
Series:Applied Sciences
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Online Access:https://www.mdpi.com/2076-3417/15/1/216
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author Li Chen
Eva M. Deemer
XiuJun Li
W. Shane Walker
author_facet Li Chen
Eva M. Deemer
XiuJun Li
W. Shane Walker
author_sort Li Chen
collection DOAJ
description The widespread application of electrodialysis is constrained by the high cost of ion exchange membranes, necessitating the development of affordable alternatives. This study focuses on the fabrication and performance evaluation of cation exchange membranes made from polyethersulfone (PES) and sulfonated polyethersulfone (sPES). Membranes were synthesized through phase inversion with varying solvent evaporation times, using N-Methyl-2-Pyrrolidone (NMP) as the solvent. The structural and functional modifications were confirmed using FTIR, XPS, and AFM techniques. Performance tests identified optimal electrodialysis results for PES membranes with a 3 h solvent evaporation time and for sPES membranes with a 1 h evaporation time. Under varying operational conditions, including applied voltage, flow rates, and feed solutions, sPES membranes demonstrated superior performance, underscoring their potential for cost-effective brackish water desalination applications.
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series Applied Sciences
spelling doaj-art-defd629a8d2b4128a193df6ebeaf4f192025-01-10T13:14:49ZengMDPI AGApplied Sciences2076-34172024-12-0115121610.3390/app15010216Sulfonated Polyethersulfone Membranes for Brackish Water Desalination: Fabrication, Characterization, and Electrodialysis Performance EvaluationLi Chen0Eva M. Deemer1XiuJun Li2W. Shane Walker3Center for Inland Desalination System (CIDS), The University of Texas at El Paso, 500 W. University Ave., El Paso, TX 79968, USAEnvironmental & Occupational Health Sciences, School of Public Health in El Paso, University of Texas Health Science Center at Houston, 5130 Gateway Boulevard East, El Paso, TX 79905, USADepartment of Chemistry and Biochemistry, The University of Texas at El Paso, 500 W. University Ave., El Paso, TX 79968, USADepartment of Civil, Environmental, and Construction Engineering, Water and the Environment Research (WATER) Center, Texas Tech University, 2500 Broadway W, Lubbock, TX 79409, USAThe widespread application of electrodialysis is constrained by the high cost of ion exchange membranes, necessitating the development of affordable alternatives. This study focuses on the fabrication and performance evaluation of cation exchange membranes made from polyethersulfone (PES) and sulfonated polyethersulfone (sPES). Membranes were synthesized through phase inversion with varying solvent evaporation times, using N-Methyl-2-Pyrrolidone (NMP) as the solvent. The structural and functional modifications were confirmed using FTIR, XPS, and AFM techniques. Performance tests identified optimal electrodialysis results for PES membranes with a 3 h solvent evaporation time and for sPES membranes with a 1 h evaporation time. Under varying operational conditions, including applied voltage, flow rates, and feed solutions, sPES membranes demonstrated superior performance, underscoring their potential for cost-effective brackish water desalination applications.https://www.mdpi.com/2076-3417/15/1/216electrodialysisdesalinationion exchange membranepolyethersulfonesulfonationreal brackish water
spellingShingle Li Chen
Eva M. Deemer
XiuJun Li
W. Shane Walker
Sulfonated Polyethersulfone Membranes for Brackish Water Desalination: Fabrication, Characterization, and Electrodialysis Performance Evaluation
Applied Sciences
electrodialysis
desalination
ion exchange membrane
polyethersulfone
sulfonation
real brackish water
title Sulfonated Polyethersulfone Membranes for Brackish Water Desalination: Fabrication, Characterization, and Electrodialysis Performance Evaluation
title_full Sulfonated Polyethersulfone Membranes for Brackish Water Desalination: Fabrication, Characterization, and Electrodialysis Performance Evaluation
title_fullStr Sulfonated Polyethersulfone Membranes for Brackish Water Desalination: Fabrication, Characterization, and Electrodialysis Performance Evaluation
title_full_unstemmed Sulfonated Polyethersulfone Membranes for Brackish Water Desalination: Fabrication, Characterization, and Electrodialysis Performance Evaluation
title_short Sulfonated Polyethersulfone Membranes for Brackish Water Desalination: Fabrication, Characterization, and Electrodialysis Performance Evaluation
title_sort sulfonated polyethersulfone membranes for brackish water desalination fabrication characterization and electrodialysis performance evaluation
topic electrodialysis
desalination
ion exchange membrane
polyethersulfone
sulfonation
real brackish water
url https://www.mdpi.com/2076-3417/15/1/216
work_keys_str_mv AT lichen sulfonatedpolyethersulfonemembranesforbrackishwaterdesalinationfabricationcharacterizationandelectrodialysisperformanceevaluation
AT evamdeemer sulfonatedpolyethersulfonemembranesforbrackishwaterdesalinationfabricationcharacterizationandelectrodialysisperformanceevaluation
AT xiujunli sulfonatedpolyethersulfonemembranesforbrackishwaterdesalinationfabricationcharacterizationandelectrodialysisperformanceevaluation
AT wshanewalker sulfonatedpolyethersulfonemembranesforbrackishwaterdesalinationfabricationcharacterizationandelectrodialysisperformanceevaluation