SnO2 Layer Treatment with Thioacetamide in Perovskite Solar Cell

The electron transport layer plays a pivotal role in shaping the photovoltaic attributes of perovskite solar cells. SnO2 stands out as an exemplary electron transport layer for perovskite solar cells due to its exceptional carrier mobility, deep conduction band, suitable band gap, and compatibility...

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Main Authors: Fatemeh Ghasemi, Razieh Keshtmand, Nima Taghavinia
Format: Article
Language:English
Published: Iranian Chemical Society 2023-10-01
Series:Nanochemistry Research
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Online Access:http://www.nanochemres.org/article_179401_4a55cd232b292a27212a574ec2ce0481.pdf
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author Fatemeh Ghasemi
Razieh Keshtmand
Nima Taghavinia
author_facet Fatemeh Ghasemi
Razieh Keshtmand
Nima Taghavinia
author_sort Fatemeh Ghasemi
collection DOAJ
description The electron transport layer plays a pivotal role in shaping the photovoltaic attributes of perovskite solar cells. SnO2 stands out as an exemplary electron transport layer for perovskite solar cells due to its exceptional carrier mobility, deep conduction band, suitable band gap, and compatibility with low-temperature processing. Although surface modification of SnO2 has yielded noteworthy enhancements in device performance over recent years, there remains considerable untapped potential to further refine its efficiency and long-term stability. In this study, thioacetamide was employed to modify the SnO2 surface, aiming to elevate the quality of the electron transport layer and establish a robust interface with perovskite. The findings underscored that the thioacetamide-modified SnO2 layer exhibited augmented perovskite absorption in the visible spectrum compared to the control sample. Additionally, the attenuation in photoluminescence intensity within the modified sample alludes to improved electron extraction and enhanced charge transport from the perovskite layer to the electron transport layer. Assessment of solar cell performance unveiled superior and more consistent photovoltaic parameters in the modified sample. Ultimately, the best efficiency was achieved with the perovskite solar cell using SnO2 modified with thioacetamide, boasting an efficiency of 15.15%
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language English
publishDate 2023-10-01
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series Nanochemistry Research
spelling doaj-art-de9cc04391264b00b5d006fd4aa1a4612025-01-12T10:24:56ZengIranian Chemical SocietyNanochemistry Research2538-42792423-818X2023-10-018429930510.22036/NCR.2023.04.08179401SnO2 Layer Treatment with Thioacetamide in Perovskite Solar CellFatemeh Ghasemi0Razieh Keshtmand1Nima Taghavinia2Department of Physics, Sharif University of Technology, Tehran, IranDepartment of Physics, Iran University of Science and Technology, Tehran, IranDepartment of Physics, Sharif University of Technology, Tehran, IranThe electron transport layer plays a pivotal role in shaping the photovoltaic attributes of perovskite solar cells. SnO2 stands out as an exemplary electron transport layer for perovskite solar cells due to its exceptional carrier mobility, deep conduction band, suitable band gap, and compatibility with low-temperature processing. Although surface modification of SnO2 has yielded noteworthy enhancements in device performance over recent years, there remains considerable untapped potential to further refine its efficiency and long-term stability. In this study, thioacetamide was employed to modify the SnO2 surface, aiming to elevate the quality of the electron transport layer and establish a robust interface with perovskite. The findings underscored that the thioacetamide-modified SnO2 layer exhibited augmented perovskite absorption in the visible spectrum compared to the control sample. Additionally, the attenuation in photoluminescence intensity within the modified sample alludes to improved electron extraction and enhanced charge transport from the perovskite layer to the electron transport layer. Assessment of solar cell performance unveiled superior and more consistent photovoltaic parameters in the modified sample. Ultimately, the best efficiency was achieved with the perovskite solar cell using SnO2 modified with thioacetamide, boasting an efficiency of 15.15%http://www.nanochemres.org/article_179401_4a55cd232b292a27212a574ec2ce0481.pdfperovskite solar cellelectron transport layersurface modificationsno2thioacetamide
spellingShingle Fatemeh Ghasemi
Razieh Keshtmand
Nima Taghavinia
SnO2 Layer Treatment with Thioacetamide in Perovskite Solar Cell
Nanochemistry Research
perovskite solar cell
electron transport layer
surface modification
sno2
thioacetamide
title SnO2 Layer Treatment with Thioacetamide in Perovskite Solar Cell
title_full SnO2 Layer Treatment with Thioacetamide in Perovskite Solar Cell
title_fullStr SnO2 Layer Treatment with Thioacetamide in Perovskite Solar Cell
title_full_unstemmed SnO2 Layer Treatment with Thioacetamide in Perovskite Solar Cell
title_short SnO2 Layer Treatment with Thioacetamide in Perovskite Solar Cell
title_sort sno2 layer treatment with thioacetamide in perovskite solar cell
topic perovskite solar cell
electron transport layer
surface modification
sno2
thioacetamide
url http://www.nanochemres.org/article_179401_4a55cd232b292a27212a574ec2ce0481.pdf
work_keys_str_mv AT fatemehghasemi sno2layertreatmentwiththioacetamideinperovskitesolarcell
AT raziehkeshtmand sno2layertreatmentwiththioacetamideinperovskitesolarcell
AT nimataghavinia sno2layertreatmentwiththioacetamideinperovskitesolarcell