XPS and FT-IR Characterization of Selected Synthetic Corrosion Products of Zinc Expected in Neutral Environment Containing Chloride Ions
ZnO, Zn(OH)2, Zn5(OH)8Cl2·H2O, ZnCO3, and Zn5(CO3)2(OH)6 synthetic powders were prepared by chemical or solid-state method. Their crystalline phase structure, thermal behavior, and morphology were examined. Characteristic infrared absorbance bands were estimated by means of FT-IR ATR spectroscopy. X...
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Wiley
2018-01-01
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| Series: | Journal of Spectroscopy |
| Online Access: | http://dx.doi.org/10.1155/2018/2079278 |
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| author | Juliusz Winiarski Włodzimierz Tylus Katarzyna Winiarska Irena Szczygieł Bogdan Szczygieł |
| author_facet | Juliusz Winiarski Włodzimierz Tylus Katarzyna Winiarska Irena Szczygieł Bogdan Szczygieł |
| author_sort | Juliusz Winiarski |
| collection | DOAJ |
| description | ZnO, Zn(OH)2, Zn5(OH)8Cl2·H2O, ZnCO3, and Zn5(CO3)2(OH)6 synthetic powders were prepared by chemical or solid-state method. Their crystalline phase structure, thermal behavior, and morphology were examined. Characteristic infrared absorbance bands were estimated by means of FT-IR ATR spectroscopy. X-ray photoelectron spectroscopy (XPS) allowed to calculate the modified Auger parameters (α ′) thereof to 2010.2, 2009.3, 2009.4, 2009.7, and 2009.8 eV, respectively for ZnO, Zn(OH)2, Zn5(OH)8Cl2·H2O, ZnCO3, and Zn5(CO3)2(OH)6. Finally, comparison of surface composition may be crucial to evaluation of the unknown experimental spectra of corrosion products formed on the surface of zinc alloy coatings exposed in NaCl solution. |
| format | Article |
| id | doaj-art-de5b0ddfbf9b42118e54f08033d544a3 |
| institution | OA Journals |
| issn | 2314-4920 2314-4939 |
| language | English |
| publishDate | 2018-01-01 |
| publisher | Wiley |
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| series | Journal of Spectroscopy |
| spelling | doaj-art-de5b0ddfbf9b42118e54f08033d544a32025-08-20T02:21:21ZengWileyJournal of Spectroscopy2314-49202314-49392018-01-01201810.1155/2018/20792782079278XPS and FT-IR Characterization of Selected Synthetic Corrosion Products of Zinc Expected in Neutral Environment Containing Chloride IonsJuliusz Winiarski0Włodzimierz Tylus1Katarzyna Winiarska2Irena Szczygieł3Bogdan Szczygieł4Department of Advanced Material Technologies, Faculty of Chemistry, Wrocław University of Science and Technology, Wybrzeże Wyspiańskiego 27, PL50370 Wrocław, PolandDepartment of Advanced Material Technologies, Faculty of Chemistry, Wrocław University of Science and Technology, Wybrzeże Wyspiańskiego 27, PL50370 Wrocław, PolandDepartment of Inorganic Chemistry, Faculty of Engineering and Economics, Wrocław University of Economics, Komandorska 118/120 Street, PL53345 Wrocław, PolandDepartment of Inorganic Chemistry, Faculty of Engineering and Economics, Wrocław University of Economics, Komandorska 118/120 Street, PL53345 Wrocław, PolandDepartment of Advanced Material Technologies, Faculty of Chemistry, Wrocław University of Science and Technology, Wybrzeże Wyspiańskiego 27, PL50370 Wrocław, PolandZnO, Zn(OH)2, Zn5(OH)8Cl2·H2O, ZnCO3, and Zn5(CO3)2(OH)6 synthetic powders were prepared by chemical or solid-state method. Their crystalline phase structure, thermal behavior, and morphology were examined. Characteristic infrared absorbance bands were estimated by means of FT-IR ATR spectroscopy. X-ray photoelectron spectroscopy (XPS) allowed to calculate the modified Auger parameters (α ′) thereof to 2010.2, 2009.3, 2009.4, 2009.7, and 2009.8 eV, respectively for ZnO, Zn(OH)2, Zn5(OH)8Cl2·H2O, ZnCO3, and Zn5(CO3)2(OH)6. Finally, comparison of surface composition may be crucial to evaluation of the unknown experimental spectra of corrosion products formed on the surface of zinc alloy coatings exposed in NaCl solution.http://dx.doi.org/10.1155/2018/2079278 |
| spellingShingle | Juliusz Winiarski Włodzimierz Tylus Katarzyna Winiarska Irena Szczygieł Bogdan Szczygieł XPS and FT-IR Characterization of Selected Synthetic Corrosion Products of Zinc Expected in Neutral Environment Containing Chloride Ions Journal of Spectroscopy |
| title | XPS and FT-IR Characterization of Selected Synthetic Corrosion Products of Zinc Expected in Neutral Environment Containing Chloride Ions |
| title_full | XPS and FT-IR Characterization of Selected Synthetic Corrosion Products of Zinc Expected in Neutral Environment Containing Chloride Ions |
| title_fullStr | XPS and FT-IR Characterization of Selected Synthetic Corrosion Products of Zinc Expected in Neutral Environment Containing Chloride Ions |
| title_full_unstemmed | XPS and FT-IR Characterization of Selected Synthetic Corrosion Products of Zinc Expected in Neutral Environment Containing Chloride Ions |
| title_short | XPS and FT-IR Characterization of Selected Synthetic Corrosion Products of Zinc Expected in Neutral Environment Containing Chloride Ions |
| title_sort | xps and ft ir characterization of selected synthetic corrosion products of zinc expected in neutral environment containing chloride ions |
| url | http://dx.doi.org/10.1155/2018/2079278 |
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