Evaluation of the Morphology and Corrosion Behavior of Zn-Based Coatings Deposited on Low Carbon Steel Using a Sustainable Energy Source

Green energy sources offer a significant opportunity to make metallurgical processes more sustainable. In this regard, concentrated solar energy can be used to modify metallic surfaces. In this study, a Zn-22Al-2Cu coating was applied to an A36 steel substrate using a Fresnel lens. The coating was f...

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Main Authors: Rafael González-Parra, Alejandro de Jesús, Arturo Rodríguez-Gómez, Miguel A. Hernandez, Armando Rojas, Alejandro Jaramillo, Arturo Barba
Format: Article
Language:English
Published: Wiley 2025-01-01
Series:International Journal of Electrochemistry
Online Access:http://dx.doi.org/10.1155/ijel/9875900
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author Rafael González-Parra
Alejandro de Jesús
Arturo Rodríguez-Gómez
Miguel A. Hernandez
Armando Rojas
Alejandro Jaramillo
Arturo Barba
author_facet Rafael González-Parra
Alejandro de Jesús
Arturo Rodríguez-Gómez
Miguel A. Hernandez
Armando Rojas
Alejandro Jaramillo
Arturo Barba
author_sort Rafael González-Parra
collection DOAJ
description Green energy sources offer a significant opportunity to make metallurgical processes more sustainable. In this regard, concentrated solar energy can be used to modify metallic surfaces. In this study, a Zn-22Al-2Cu coating was applied to an A36 steel substrate using a Fresnel lens. The coating was formed through the addition of 5–15 layers of powder alloy over the steel substrate. The coating is composed of η-zinc-rich phases and zinc oxides. The compactness and porosity depend on the amount of layers used. The adhesion of the coating is in the range of 2.5–4.5 MPa. Electrochemical tests indicate that the coating promotes the formation of a protective layer. This behavior is in accordance with the time constants determined by electrochemical impedance spectroscopy which show the presence of two time constants for the coated samples, indicating the protective response of the corrosion products. Then, the addition of 15 layers of Zn-based alloy powder demonstrates the most optimal performance, as it promotes the formation of a compact layer that properly covers the substrate surface, increasing adhesion and corrosion resistance. The corrosion products were zinc oxides, hydrozincite, and iron corrosion products for the coated and blank samples, respectively.
format Article
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institution OA Journals
issn 2090-3537
language English
publishDate 2025-01-01
publisher Wiley
record_format Article
series International Journal of Electrochemistry
spelling doaj-art-de0861525ea348939b2e64056be439ee2025-08-20T02:38:29ZengWileyInternational Journal of Electrochemistry2090-35372025-01-01202510.1155/ijel/9875900Evaluation of the Morphology and Corrosion Behavior of Zn-Based Coatings Deposited on Low Carbon Steel Using a Sustainable Energy SourceRafael González-Parra0Alejandro de Jesús1Arturo Rodríguez-Gómez2Miguel A. Hernandez3Armando Rojas4Alejandro Jaramillo5Arturo Barba6Center for Surface Engineering and FinishesCenter for Surface Engineering and FinishesDepartment of Condensed MatterCenter for Surface Engineering and FinishesFaculty of EngineeringFaculty of EngineeringCenter for Surface Engineering and FinishesGreen energy sources offer a significant opportunity to make metallurgical processes more sustainable. In this regard, concentrated solar energy can be used to modify metallic surfaces. In this study, a Zn-22Al-2Cu coating was applied to an A36 steel substrate using a Fresnel lens. The coating was formed through the addition of 5–15 layers of powder alloy over the steel substrate. The coating is composed of η-zinc-rich phases and zinc oxides. The compactness and porosity depend on the amount of layers used. The adhesion of the coating is in the range of 2.5–4.5 MPa. Electrochemical tests indicate that the coating promotes the formation of a protective layer. This behavior is in accordance with the time constants determined by electrochemical impedance spectroscopy which show the presence of two time constants for the coated samples, indicating the protective response of the corrosion products. Then, the addition of 15 layers of Zn-based alloy powder demonstrates the most optimal performance, as it promotes the formation of a compact layer that properly covers the substrate surface, increasing adhesion and corrosion resistance. The corrosion products were zinc oxides, hydrozincite, and iron corrosion products for the coated and blank samples, respectively.http://dx.doi.org/10.1155/ijel/9875900
spellingShingle Rafael González-Parra
Alejandro de Jesús
Arturo Rodríguez-Gómez
Miguel A. Hernandez
Armando Rojas
Alejandro Jaramillo
Arturo Barba
Evaluation of the Morphology and Corrosion Behavior of Zn-Based Coatings Deposited on Low Carbon Steel Using a Sustainable Energy Source
International Journal of Electrochemistry
title Evaluation of the Morphology and Corrosion Behavior of Zn-Based Coatings Deposited on Low Carbon Steel Using a Sustainable Energy Source
title_full Evaluation of the Morphology and Corrosion Behavior of Zn-Based Coatings Deposited on Low Carbon Steel Using a Sustainable Energy Source
title_fullStr Evaluation of the Morphology and Corrosion Behavior of Zn-Based Coatings Deposited on Low Carbon Steel Using a Sustainable Energy Source
title_full_unstemmed Evaluation of the Morphology and Corrosion Behavior of Zn-Based Coatings Deposited on Low Carbon Steel Using a Sustainable Energy Source
title_short Evaluation of the Morphology and Corrosion Behavior of Zn-Based Coatings Deposited on Low Carbon Steel Using a Sustainable Energy Source
title_sort evaluation of the morphology and corrosion behavior of zn based coatings deposited on low carbon steel using a sustainable energy source
url http://dx.doi.org/10.1155/ijel/9875900
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