Non-Toxic Buffer Layers in Flexible Cu(In,Ga)Se2 Photovoltaic Cell Applications with Optimized Absorber Thickness

Absorber layer thickness gradient in Cu(In1−xGax)Se2 (CIGS) based solar cells and several substitutes for typical cadmium sulfide (CdS) buffer layers, such as ZnS, ZnO, ZnS(O,OH), Zn1−xSnxOy (ZTO), ZnSe, and In2S3, have been analyzed by a device emulation program and tool (ADEPT 2.1) to determine op...

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Main Authors: Md. Asaduzzaman, Md. Billal Hosen, Md. Karamot Ali, Ali Newaz Bahar
Format: Article
Language:English
Published: Wiley 2017-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2017/4561208
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author Md. Asaduzzaman
Md. Billal Hosen
Md. Karamot Ali
Ali Newaz Bahar
author_facet Md. Asaduzzaman
Md. Billal Hosen
Md. Karamot Ali
Ali Newaz Bahar
author_sort Md. Asaduzzaman
collection DOAJ
description Absorber layer thickness gradient in Cu(In1−xGax)Se2 (CIGS) based solar cells and several substitutes for typical cadmium sulfide (CdS) buffer layers, such as ZnS, ZnO, ZnS(O,OH), Zn1−xSnxOy (ZTO), ZnSe, and In2S3, have been analyzed by a device emulation program and tool (ADEPT 2.1) to determine optimum efficiency. As a reference type, the CIGS cell with CdS buffer provides a theoretical efficiency of 23.23% when the optimum absorber layer thickness was determined as 1.6 μm. It is also observed that this highly efficient CIGS cell would have an absorber layer thickness between 1 μm and 2 μm whereas the optimum buffer layer thickness would be within the range of 0.04–0.06 μm. Among all the cells with various buffer layers, the best energy conversion efficiency of 24.62% has been achieved for the ZnO buffer layer based cell. The simulation results with ZnS and ZnO based buffer layer materials instead of using CdS indicate that the cell performance would be better than that of the CdS buffer layer based cell. Although the cells with ZnS(O,OH), ZTO, ZnSe, and In2S3 buffer layers provide slightly lower efficiencies than that of the CdS buffer based cell, the use of these materials would not be deleterious for the environment because of their non-carcinogenic and non-toxic nature.
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institution Kabale University
issn 1110-662X
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language English
publishDate 2017-01-01
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series International Journal of Photoenergy
spelling doaj-art-ddacf6332efd41de8711b0ab19fcbcb12025-02-03T05:53:54ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2017-01-01201710.1155/2017/45612084561208Non-Toxic Buffer Layers in Flexible Cu(In,Ga)Se2 Photovoltaic Cell Applications with Optimized Absorber ThicknessMd. Asaduzzaman0Md. Billal Hosen1Md. Karamot Ali2Ali Newaz Bahar3Department of Information and Communication Technology (ICT), Mawlana Bhashani Science and Technology University (MBSTU), Santosh, Tangail 1902, BangladeshDepartment of Information and Communication Technology (ICT), Mawlana Bhashani Science and Technology University (MBSTU), Santosh, Tangail 1902, BangladeshDepartment of Information and Communication Technology (ICT), Mawlana Bhashani Science and Technology University (MBSTU), Santosh, Tangail 1902, BangladeshDepartment of Information and Communication Technology (ICT), Mawlana Bhashani Science and Technology University (MBSTU), Santosh, Tangail 1902, BangladeshAbsorber layer thickness gradient in Cu(In1−xGax)Se2 (CIGS) based solar cells and several substitutes for typical cadmium sulfide (CdS) buffer layers, such as ZnS, ZnO, ZnS(O,OH), Zn1−xSnxOy (ZTO), ZnSe, and In2S3, have been analyzed by a device emulation program and tool (ADEPT 2.1) to determine optimum efficiency. As a reference type, the CIGS cell with CdS buffer provides a theoretical efficiency of 23.23% when the optimum absorber layer thickness was determined as 1.6 μm. It is also observed that this highly efficient CIGS cell would have an absorber layer thickness between 1 μm and 2 μm whereas the optimum buffer layer thickness would be within the range of 0.04–0.06 μm. Among all the cells with various buffer layers, the best energy conversion efficiency of 24.62% has been achieved for the ZnO buffer layer based cell. The simulation results with ZnS and ZnO based buffer layer materials instead of using CdS indicate that the cell performance would be better than that of the CdS buffer layer based cell. Although the cells with ZnS(O,OH), ZTO, ZnSe, and In2S3 buffer layers provide slightly lower efficiencies than that of the CdS buffer based cell, the use of these materials would not be deleterious for the environment because of their non-carcinogenic and non-toxic nature.http://dx.doi.org/10.1155/2017/4561208
spellingShingle Md. Asaduzzaman
Md. Billal Hosen
Md. Karamot Ali
Ali Newaz Bahar
Non-Toxic Buffer Layers in Flexible Cu(In,Ga)Se2 Photovoltaic Cell Applications with Optimized Absorber Thickness
International Journal of Photoenergy
title Non-Toxic Buffer Layers in Flexible Cu(In,Ga)Se2 Photovoltaic Cell Applications with Optimized Absorber Thickness
title_full Non-Toxic Buffer Layers in Flexible Cu(In,Ga)Se2 Photovoltaic Cell Applications with Optimized Absorber Thickness
title_fullStr Non-Toxic Buffer Layers in Flexible Cu(In,Ga)Se2 Photovoltaic Cell Applications with Optimized Absorber Thickness
title_full_unstemmed Non-Toxic Buffer Layers in Flexible Cu(In,Ga)Se2 Photovoltaic Cell Applications with Optimized Absorber Thickness
title_short Non-Toxic Buffer Layers in Flexible Cu(In,Ga)Se2 Photovoltaic Cell Applications with Optimized Absorber Thickness
title_sort non toxic buffer layers in flexible cu in ga se2 photovoltaic cell applications with optimized absorber thickness
url http://dx.doi.org/10.1155/2017/4561208
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AT mdkaramotali nontoxicbufferlayersinflexiblecuingase2photovoltaiccellapplicationswithoptimizedabsorberthickness
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