Multicomponent dynamics in amorphous ice studied using X-ray photon correlation spectroscopy at elevated pressure and cryogenic temperatures
Abstract Knowing the pressure dependence of glass forming liquids is important in various contexts. Here, we study the case of supercooled water, which has at least two different amorphous states with different densities. The pressure dependencies of the two glass transitions are predicted to show o...
Saved in:
| Main Authors: | , , , , , , , , , , , , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2025-03-01
|
| Series: | Communications Chemistry |
| Online Access: | https://doi.org/10.1038/s42004-025-01480-8 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1850039436402753536 |
|---|---|
| author | Aigerim Karina Hailong Li Tobias Eklund Marjorie Ladd-Parada Bernhard Massani Mariia Filianina Neha Kondedan Andreas Rydh Klara Holl Ryan Trevorah Simo Huotari Robert P. C. Bauer Claudia Goy Nele N. Striker Francesco Dallari Fabian Westermeier Michael Sprung Felix Lehmkühler Katrin Amann-Winkel |
| author_facet | Aigerim Karina Hailong Li Tobias Eklund Marjorie Ladd-Parada Bernhard Massani Mariia Filianina Neha Kondedan Andreas Rydh Klara Holl Ryan Trevorah Simo Huotari Robert P. C. Bauer Claudia Goy Nele N. Striker Francesco Dallari Fabian Westermeier Michael Sprung Felix Lehmkühler Katrin Amann-Winkel |
| author_sort | Aigerim Karina |
| collection | DOAJ |
| description | Abstract Knowing the pressure dependence of glass forming liquids is important in various contexts. Here, we study the case of supercooled water, which has at least two different amorphous states with different densities. The pressure dependencies of the two glass transitions are predicted to show opposite behaviour, crossing in the P-T plane at elevated pressure. The experimental identification of the glass transition at elevated pressure and cryo-conditions is technically difficult. Moreover, in the case of amorphous ices, the glass transition is interrupted by crystallization, which makes it even more challenging. We show the feasibility of performing X-ray photon correlation spectroscopy experiments at elevated pressure using a diamond anvil cell at cryogenic temperatures. We observe two dynamic components when approaching the glass transition temperature. For high-density amorphous ice at a pressure of around (0.08 ± 0.02) GPa we determine the glass transition to be at higher temperatures compared to ambient conditions. |
| format | Article |
| id | doaj-art-dd7a700181914e58a67df56c04b8e398 |
| institution | DOAJ |
| issn | 2399-3669 |
| language | English |
| publishDate | 2025-03-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Communications Chemistry |
| spelling | doaj-art-dd7a700181914e58a67df56c04b8e3982025-08-20T02:56:20ZengNature PortfolioCommunications Chemistry2399-36692025-03-01811910.1038/s42004-025-01480-8Multicomponent dynamics in amorphous ice studied using X-ray photon correlation spectroscopy at elevated pressure and cryogenic temperaturesAigerim Karina0Hailong Li1Tobias Eklund2Marjorie Ladd-Parada3Bernhard Massani4Mariia Filianina5Neha Kondedan6Andreas Rydh7Klara Holl8Ryan Trevorah9Simo Huotari10Robert P. C. Bauer11Claudia Goy12Nele N. Striker13Francesco Dallari14Fabian Westermeier15Michael Sprung16Felix Lehmkühler17Katrin Amann-Winkel18Department of Physics, Stockholm UniversityMax-Planck-Institute for Polymer ResearchMax-Planck-Institute for Polymer ResearchDepartment of Chemistry, Glycoscience DivisionThe University of Edinburgh, School of Physics and Astronomy (SoPA), Centre for Science at Extreme Conditions (CSEC)Department of Physics, Stockholm UniversityDepartment of Physics, Stockholm UniversityDepartment of Physics, Stockholm UniversityMax-Planck-Institute for Polymer ResearchDepartment of Physics, University of HelsinkiDepartment of Physics, University of HelsinkiDeutsches Elektronen-Synchrotron DESYDeutsches Elektronen-Synchrotron DESYDeutsches Elektronen-Synchrotron DESYDeutsches Elektronen-Synchrotron DESYDeutsches Elektronen-Synchrotron DESYDeutsches Elektronen-Synchrotron DESYDeutsches Elektronen-Synchrotron DESYDepartment of Physics, Stockholm UniversityAbstract Knowing the pressure dependence of glass forming liquids is important in various contexts. Here, we study the case of supercooled water, which has at least two different amorphous states with different densities. The pressure dependencies of the two glass transitions are predicted to show opposite behaviour, crossing in the P-T plane at elevated pressure. The experimental identification of the glass transition at elevated pressure and cryo-conditions is technically difficult. Moreover, in the case of amorphous ices, the glass transition is interrupted by crystallization, which makes it even more challenging. We show the feasibility of performing X-ray photon correlation spectroscopy experiments at elevated pressure using a diamond anvil cell at cryogenic temperatures. We observe two dynamic components when approaching the glass transition temperature. For high-density amorphous ice at a pressure of around (0.08 ± 0.02) GPa we determine the glass transition to be at higher temperatures compared to ambient conditions.https://doi.org/10.1038/s42004-025-01480-8 |
| spellingShingle | Aigerim Karina Hailong Li Tobias Eklund Marjorie Ladd-Parada Bernhard Massani Mariia Filianina Neha Kondedan Andreas Rydh Klara Holl Ryan Trevorah Simo Huotari Robert P. C. Bauer Claudia Goy Nele N. Striker Francesco Dallari Fabian Westermeier Michael Sprung Felix Lehmkühler Katrin Amann-Winkel Multicomponent dynamics in amorphous ice studied using X-ray photon correlation spectroscopy at elevated pressure and cryogenic temperatures Communications Chemistry |
| title | Multicomponent dynamics in amorphous ice studied using X-ray photon correlation spectroscopy at elevated pressure and cryogenic temperatures |
| title_full | Multicomponent dynamics in amorphous ice studied using X-ray photon correlation spectroscopy at elevated pressure and cryogenic temperatures |
| title_fullStr | Multicomponent dynamics in amorphous ice studied using X-ray photon correlation spectroscopy at elevated pressure and cryogenic temperatures |
| title_full_unstemmed | Multicomponent dynamics in amorphous ice studied using X-ray photon correlation spectroscopy at elevated pressure and cryogenic temperatures |
| title_short | Multicomponent dynamics in amorphous ice studied using X-ray photon correlation spectroscopy at elevated pressure and cryogenic temperatures |
| title_sort | multicomponent dynamics in amorphous ice studied using x ray photon correlation spectroscopy at elevated pressure and cryogenic temperatures |
| url | https://doi.org/10.1038/s42004-025-01480-8 |
| work_keys_str_mv | AT aigerimkarina multicomponentdynamicsinamorphousicestudiedusingxrayphotoncorrelationspectroscopyatelevatedpressureandcryogenictemperatures AT hailongli multicomponentdynamicsinamorphousicestudiedusingxrayphotoncorrelationspectroscopyatelevatedpressureandcryogenictemperatures AT tobiaseklund multicomponentdynamicsinamorphousicestudiedusingxrayphotoncorrelationspectroscopyatelevatedpressureandcryogenictemperatures AT marjorieladdparada multicomponentdynamicsinamorphousicestudiedusingxrayphotoncorrelationspectroscopyatelevatedpressureandcryogenictemperatures AT bernhardmassani multicomponentdynamicsinamorphousicestudiedusingxrayphotoncorrelationspectroscopyatelevatedpressureandcryogenictemperatures AT mariiafilianina multicomponentdynamicsinamorphousicestudiedusingxrayphotoncorrelationspectroscopyatelevatedpressureandcryogenictemperatures AT nehakondedan multicomponentdynamicsinamorphousicestudiedusingxrayphotoncorrelationspectroscopyatelevatedpressureandcryogenictemperatures AT andreasrydh multicomponentdynamicsinamorphousicestudiedusingxrayphotoncorrelationspectroscopyatelevatedpressureandcryogenictemperatures AT klaraholl multicomponentdynamicsinamorphousicestudiedusingxrayphotoncorrelationspectroscopyatelevatedpressureandcryogenictemperatures AT ryantrevorah multicomponentdynamicsinamorphousicestudiedusingxrayphotoncorrelationspectroscopyatelevatedpressureandcryogenictemperatures AT simohuotari multicomponentdynamicsinamorphousicestudiedusingxrayphotoncorrelationspectroscopyatelevatedpressureandcryogenictemperatures AT robertpcbauer multicomponentdynamicsinamorphousicestudiedusingxrayphotoncorrelationspectroscopyatelevatedpressureandcryogenictemperatures AT claudiagoy multicomponentdynamicsinamorphousicestudiedusingxrayphotoncorrelationspectroscopyatelevatedpressureandcryogenictemperatures AT nelenstriker multicomponentdynamicsinamorphousicestudiedusingxrayphotoncorrelationspectroscopyatelevatedpressureandcryogenictemperatures AT francescodallari multicomponentdynamicsinamorphousicestudiedusingxrayphotoncorrelationspectroscopyatelevatedpressureandcryogenictemperatures AT fabianwestermeier multicomponentdynamicsinamorphousicestudiedusingxrayphotoncorrelationspectroscopyatelevatedpressureandcryogenictemperatures AT michaelsprung multicomponentdynamicsinamorphousicestudiedusingxrayphotoncorrelationspectroscopyatelevatedpressureandcryogenictemperatures AT felixlehmkuhler multicomponentdynamicsinamorphousicestudiedusingxrayphotoncorrelationspectroscopyatelevatedpressureandcryogenictemperatures AT katrinamannwinkel multicomponentdynamicsinamorphousicestudiedusingxrayphotoncorrelationspectroscopyatelevatedpressureandcryogenictemperatures |