Coupling effect of fiber reinforcing and biomimetic chemically induced calcium carbonate precipitation cementing on mechanical performance of biomimetic mineralized mortar

Biomimetic mineralized mortar (BMM) is a green, low-carbon alternative to cement, yet its brittle failure restricts broader application. This study proposes novel fiber-reinforced biomimetic mineralized mortar (FBMM) with excellent ductility based on the coupling method of fiber reinforcement and bi...

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Main Authors: Yu Diao, Lingzhu Zhang, Chu Wang, Haikuo Hu, Chuan Yang, Zhiwei Li, Jianyou Huang
Format: Article
Language:English
Published: Elsevier 2025-03-01
Series:Journal of Materials Research and Technology
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Online Access:http://www.sciencedirect.com/science/article/pii/S2238785425004041
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author Yu Diao
Lingzhu Zhang
Chu Wang
Haikuo Hu
Chuan Yang
Zhiwei Li
Jianyou Huang
author_facet Yu Diao
Lingzhu Zhang
Chu Wang
Haikuo Hu
Chuan Yang
Zhiwei Li
Jianyou Huang
author_sort Yu Diao
collection DOAJ
description Biomimetic mineralized mortar (BMM) is a green, low-carbon alternative to cement, yet its brittle failure restricts broader application. This study proposes novel fiber-reinforced biomimetic mineralized mortar (FBMM) with excellent ductility based on the coupling method of fiber reinforcement and biomimetic chemically induced calcium carbonate precipitation (BCICP). The impact of polypropylene fiber (PF) with contents of 0%, 0.2%, 0.4%, 0.6%, and 0.8% on the mechanical properties of the FBMM was investigated. Moreover, the pore structure and microscopic characteristics of the FBMM were analyzed through mercury intrusion porosimetry (MIP) and scanning electron microscopy (SEM). The results demonstrate that the PF enhances the ductility of FBMM, improving residual strength and energy absorption under compression. Notably, lower PF content improves the compressive strength of biomimetic mineralized composites, while higher concentrations reduce the compressive strength. SEM images reveal that the calcium carbonate crystals, treated with polyacrylic acid (PAA), adhere well to the surface of sand particles and fibers, forming strong connections for cementing the composites. Furthermore, PF can promote more calcium carbonate to precipitate in the pores between fibers and sand particles and on the fiber surface by increasing the internal surface area of FBMM. This study investigates the synergistic effect of BCICP and fiber reinforcement, providing insights for potential practical applications of FBMM with high ductility.
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spelling doaj-art-dd73848bdbdb4e89a1a8cf56d64a40a92025-08-20T02:55:10ZengElsevierJournal of Materials Research and Technology2238-78542025-03-01355688569710.1016/j.jmrt.2025.02.157Coupling effect of fiber reinforcing and biomimetic chemically induced calcium carbonate precipitation cementing on mechanical performance of biomimetic mineralized mortarYu Diao0Lingzhu Zhang1Chu Wang2Haikuo Hu3Chuan Yang4Zhiwei Li5Jianyou Huang6School of Civil Engineering, Tianjin University, Tianjin, 300072, China; Key Laboratory of Coast Civil Structure Safety (Tianjin University), Ministry of Education, Tianjin, 300072, ChinaSchool of Civil Engineering, Tianjin University, Tianjin, 300072, ChinaSchool of Civil Engineering, Tianjin University, Tianjin, 300072, ChinaSchool of Civil Engineering, Tianjin University, Tianjin, 300072, ChinaSchool of Civil Engineering, Tianjin University, Tianjin, 300072, ChinaFujian Jianyan Engineering Consulting Co., Ltd, Fuzhou, 350108, China; Fujian Provincial Key Laboratory of Green Building Technology, Fuzhou, 350025, ChinaSchool of Civil Engineering, Tianjin University, Tianjin, 300072, China; Key Laboratory of Coast Civil Structure Safety (Tianjin University), Ministry of Education, Tianjin, 300072, China; Corresponding author. School of Civil Engineering, Tianjin University, Tianjin, 300072, China.Biomimetic mineralized mortar (BMM) is a green, low-carbon alternative to cement, yet its brittle failure restricts broader application. This study proposes novel fiber-reinforced biomimetic mineralized mortar (FBMM) with excellent ductility based on the coupling method of fiber reinforcement and biomimetic chemically induced calcium carbonate precipitation (BCICP). The impact of polypropylene fiber (PF) with contents of 0%, 0.2%, 0.4%, 0.6%, and 0.8% on the mechanical properties of the FBMM was investigated. Moreover, the pore structure and microscopic characteristics of the FBMM were analyzed through mercury intrusion porosimetry (MIP) and scanning electron microscopy (SEM). The results demonstrate that the PF enhances the ductility of FBMM, improving residual strength and energy absorption under compression. Notably, lower PF content improves the compressive strength of biomimetic mineralized composites, while higher concentrations reduce the compressive strength. SEM images reveal that the calcium carbonate crystals, treated with polyacrylic acid (PAA), adhere well to the surface of sand particles and fibers, forming strong connections for cementing the composites. Furthermore, PF can promote more calcium carbonate to precipitate in the pores between fibers and sand particles and on the fiber surface by increasing the internal surface area of FBMM. This study investigates the synergistic effect of BCICP and fiber reinforcement, providing insights for potential practical applications of FBMM with high ductility.http://www.sciencedirect.com/science/article/pii/S2238785425004041DuctilityPolypropylene fiberBiomimetic mineralized mortarBCICP
spellingShingle Yu Diao
Lingzhu Zhang
Chu Wang
Haikuo Hu
Chuan Yang
Zhiwei Li
Jianyou Huang
Coupling effect of fiber reinforcing and biomimetic chemically induced calcium carbonate precipitation cementing on mechanical performance of biomimetic mineralized mortar
Journal of Materials Research and Technology
Ductility
Polypropylene fiber
Biomimetic mineralized mortar
BCICP
title Coupling effect of fiber reinforcing and biomimetic chemically induced calcium carbonate precipitation cementing on mechanical performance of biomimetic mineralized mortar
title_full Coupling effect of fiber reinforcing and biomimetic chemically induced calcium carbonate precipitation cementing on mechanical performance of biomimetic mineralized mortar
title_fullStr Coupling effect of fiber reinforcing and biomimetic chemically induced calcium carbonate precipitation cementing on mechanical performance of biomimetic mineralized mortar
title_full_unstemmed Coupling effect of fiber reinforcing and biomimetic chemically induced calcium carbonate precipitation cementing on mechanical performance of biomimetic mineralized mortar
title_short Coupling effect of fiber reinforcing and biomimetic chemically induced calcium carbonate precipitation cementing on mechanical performance of biomimetic mineralized mortar
title_sort coupling effect of fiber reinforcing and biomimetic chemically induced calcium carbonate precipitation cementing on mechanical performance of biomimetic mineralized mortar
topic Ductility
Polypropylene fiber
Biomimetic mineralized mortar
BCICP
url http://www.sciencedirect.com/science/article/pii/S2238785425004041
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