Mechanically flexible mid-wave infrared imagers using black phosphorus ink films

Abstract The mid-wave infrared (MWIR) spectral range (λ = 3–8 μm) enables important sensing and imaging applications, including non-invasive bioimaging, night vision, and autonomous navigation. Commercial MWIR photodetectors are limited to rigid imagers based on heteroepitaxial materials. There is a...

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Main Authors: Theodorus Jonathan Wijaya, Naoki Higashitarumizu, Shifan Wang, Shogo Tajima, Hyong Min Kim, Shu Wang, Dehui Zhang, James Bullock, Tomoyuki Yokota, Takao Someya, Ali Javey
Format: Article
Language:English
Published: Nature Portfolio 2025-07-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-025-60942-8
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author Theodorus Jonathan Wijaya
Naoki Higashitarumizu
Shifan Wang
Shogo Tajima
Hyong Min Kim
Shu Wang
Dehui Zhang
James Bullock
Tomoyuki Yokota
Takao Someya
Ali Javey
author_facet Theodorus Jonathan Wijaya
Naoki Higashitarumizu
Shifan Wang
Shogo Tajima
Hyong Min Kim
Shu Wang
Dehui Zhang
James Bullock
Tomoyuki Yokota
Takao Someya
Ali Javey
author_sort Theodorus Jonathan Wijaya
collection DOAJ
description Abstract The mid-wave infrared (MWIR) spectral range (λ = 3–8 μm) enables important sensing and imaging applications, including non-invasive bioimaging, night vision, and autonomous navigation. Commercial MWIR photodetectors are limited to rigid imagers based on heteroepitaxial materials. There is an emerging need for mechanically flexible MWIR imagers to broaden their functionality and practicality. Recently, photodetectors using van der Waals (vdW) black phosphorus (BP) flakes have demonstrated highly sensitive room-temperature photodetection. Additionally, vdW materials are solution-processable, facilitating scalable processing and flexible device fabrication. In this work, we present flexible MWIR imagers consisting of photodiodes fabricated on thin plastic substrates using BP ink films. We demonstrate mechanically robust responsivity up to 2.5-mm bending radii and after 5000 bending cycles. Leveraging this flexibility, we achieve full-azimuthal imaging, detecting directional light sources with precision. These results establish a scalable approach for large-area, conformable MWIR imaging and pave the way for integration with flexible electronics.
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issn 2041-1723
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publishDate 2025-07-01
publisher Nature Portfolio
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series Nature Communications
spelling doaj-art-dcd38f9e8ed44ab49fca674d27d9e7512025-08-20T03:45:33ZengNature PortfolioNature Communications2041-17232025-07-0116111010.1038/s41467-025-60942-8Mechanically flexible mid-wave infrared imagers using black phosphorus ink filmsTheodorus Jonathan Wijaya0Naoki Higashitarumizu1Shifan Wang2Shogo Tajima3Hyong Min Kim4Shu Wang5Dehui Zhang6James Bullock7Tomoyuki Yokota8Takao Someya9Ali Javey10Department of Electrical Engineering and Computer Sciences, University of CaliforniaDepartment of Electrical Engineering and Computer Sciences, University of CaliforniaDepartment of Electrical Engineering and Computer Sciences, University of CaliforniaDepartment of Electrical Engineering and Computer Sciences, University of CaliforniaDepartment of Electrical Engineering and Computer Sciences, University of CaliforniaMaterials Sciences Division, Lawrence Berkeley National LaboratoryDepartment of Electrical Engineering and Computer Sciences, University of CaliforniaDepartment of Electrical and Electronic Engineering, University of MelbourneDepartment of Electrical Engineering and Information Systems, The University of Tokyo, 7-3-1 Hongo, Bunkyo-kuDepartment of Electrical Engineering and Information Systems, The University of Tokyo, 7-3-1 Hongo, Bunkyo-kuDepartment of Electrical Engineering and Computer Sciences, University of CaliforniaAbstract The mid-wave infrared (MWIR) spectral range (λ = 3–8 μm) enables important sensing and imaging applications, including non-invasive bioimaging, night vision, and autonomous navigation. Commercial MWIR photodetectors are limited to rigid imagers based on heteroepitaxial materials. There is an emerging need for mechanically flexible MWIR imagers to broaden their functionality and practicality. Recently, photodetectors using van der Waals (vdW) black phosphorus (BP) flakes have demonstrated highly sensitive room-temperature photodetection. Additionally, vdW materials are solution-processable, facilitating scalable processing and flexible device fabrication. In this work, we present flexible MWIR imagers consisting of photodiodes fabricated on thin plastic substrates using BP ink films. We demonstrate mechanically robust responsivity up to 2.5-mm bending radii and after 5000 bending cycles. Leveraging this flexibility, we achieve full-azimuthal imaging, detecting directional light sources with precision. These results establish a scalable approach for large-area, conformable MWIR imaging and pave the way for integration with flexible electronics.https://doi.org/10.1038/s41467-025-60942-8
spellingShingle Theodorus Jonathan Wijaya
Naoki Higashitarumizu
Shifan Wang
Shogo Tajima
Hyong Min Kim
Shu Wang
Dehui Zhang
James Bullock
Tomoyuki Yokota
Takao Someya
Ali Javey
Mechanically flexible mid-wave infrared imagers using black phosphorus ink films
Nature Communications
title Mechanically flexible mid-wave infrared imagers using black phosphorus ink films
title_full Mechanically flexible mid-wave infrared imagers using black phosphorus ink films
title_fullStr Mechanically flexible mid-wave infrared imagers using black phosphorus ink films
title_full_unstemmed Mechanically flexible mid-wave infrared imagers using black phosphorus ink films
title_short Mechanically flexible mid-wave infrared imagers using black phosphorus ink films
title_sort mechanically flexible mid wave infrared imagers using black phosphorus ink films
url https://doi.org/10.1038/s41467-025-60942-8
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