Determination of vapour–liquid equilibria diagram structure of five-component monoazeotropic system

In this paper algorithm of determination of vapour-liquid equilibria diagram structure for five-component system with and without five-component azeotrope was described. This algorithm allows determining existence, sign of Poincare index and type of five-component azeotrope using principle of azeptr...

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Main Authors: L. A. Serafimov, A. V. Frolkova, G. A. Syomin
Format: Article
Language:Russian
Published: MIREA - Russian Technological University 2014-06-01
Series:Тонкие химические технологии
Subjects:
Online Access:https://www.finechem-mirea.ru/jour/article/view/466
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author L. A. Serafimov
A. V. Frolkova
G. A. Syomin
author_facet L. A. Serafimov
A. V. Frolkova
G. A. Syomin
author_sort L. A. Serafimov
collection DOAJ
description In this paper algorithm of determination of vapour-liquid equilibria diagram structure for five-component system with and without five-component azeotrope was described. This algorithm allows determining existence, sign of Poincare index and type of five-component azeotrope using principle of azeptropy. One model and one real (acetone–methanol–methyl acetate–ethyl acetate–water) system was analyzed with this algorithm.
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institution DOAJ
issn 2410-6593
2686-7575
language Russian
publishDate 2014-06-01
publisher MIREA - Russian Technological University
record_format Article
series Тонкие химические технологии
spelling doaj-art-dcb372cbce75431fb0ee2b5a45bae39d2025-08-20T03:00:02ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752014-06-01933644460Determination of vapour–liquid equilibria diagram structure of five-component monoazeotropic systemL. A. Serafimov0A. V. Frolkova1G. A. Syomin2M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571In this paper algorithm of determination of vapour-liquid equilibria diagram structure for five-component system with and without five-component azeotrope was described. This algorithm allows determining existence, sign of Poincare index and type of five-component azeotrope using principle of azeptropy. One model and one real (acetone–methanol–methyl acetate–ethyl acetate–water) system was analyzed with this algorithm.https://www.finechem-mirea.ru/jour/article/view/466phase equilibrium diagram, concentration simplex, five-component system, pentatope, open distillation lines diagram, poincare index.
spellingShingle L. A. Serafimov
A. V. Frolkova
G. A. Syomin
Determination of vapour–liquid equilibria diagram structure of five-component monoazeotropic system
Тонкие химические технологии
phase equilibrium diagram, concentration simplex, five-component system, pentatope, open distillation lines diagram, poincare index.
title Determination of vapour–liquid equilibria diagram structure of five-component monoazeotropic system
title_full Determination of vapour–liquid equilibria diagram structure of five-component monoazeotropic system
title_fullStr Determination of vapour–liquid equilibria diagram structure of five-component monoazeotropic system
title_full_unstemmed Determination of vapour–liquid equilibria diagram structure of five-component monoazeotropic system
title_short Determination of vapour–liquid equilibria diagram structure of five-component monoazeotropic system
title_sort determination of vapour liquid equilibria diagram structure of five component monoazeotropic system
topic phase equilibrium diagram, concentration simplex, five-component system, pentatope, open distillation lines diagram, poincare index.
url https://www.finechem-mirea.ru/jour/article/view/466
work_keys_str_mv AT laserafimov determinationofvapourliquidequilibriadiagramstructureoffivecomponentmonoazeotropicsystem
AT avfrolkova determinationofvapourliquidequilibriadiagramstructureoffivecomponentmonoazeotropicsystem
AT gasyomin determinationofvapourliquidequilibriadiagramstructureoffivecomponentmonoazeotropicsystem