Polystyrene Backbone Polymers Consisting of Alkyl-Substituted Triazine Side Groups for Phosphorescent OLEDs

This paper describes the synthesis of new electron-transporting styrene monomers and their corresponding polystyrenes all with a 2,4,6-triphenyl-1,3,5-triazine basic structure in the side group. The monomers differ in the alkyl substitution and in the meta-/paralinkage of the triazine to the polymer...

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Main Authors: Beatrice Ch. D. Salert, Armin Wedel, Lutz Grubert, Thomas Eberle, Rémi Anémian, Hartmut Krueger
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:Advances in Materials Science and Engineering
Online Access:http://dx.doi.org/10.1155/2012/385178
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author Beatrice Ch. D. Salert
Armin Wedel
Lutz Grubert
Thomas Eberle
Rémi Anémian
Hartmut Krueger
author_facet Beatrice Ch. D. Salert
Armin Wedel
Lutz Grubert
Thomas Eberle
Rémi Anémian
Hartmut Krueger
author_sort Beatrice Ch. D. Salert
collection DOAJ
description This paper describes the synthesis of new electron-transporting styrene monomers and their corresponding polystyrenes all with a 2,4,6-triphenyl-1,3,5-triazine basic structure in the side group. The monomers differ in the alkyl substitution and in the meta-/paralinkage of the triazine to the polymer backbone. The thermal and spectroscopic properties of the new electron-transporting polymers are discussed in regard to their chemical structures. Phosphorescent OLEDs were prepared using the obtained electron-transporting polymers as the emissive layer material in blend systems together with a green iridium-based emitter 13 and a small molecule as an additional cohost with wideband gap characteristics (CoH-001). The performance of the OLEDs was characterized and discussed in regard to the chemical structure of the new electron-transporting polymers.
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spelling doaj-art-dc32f69e9ad0417384eea61285bbd2ed2025-08-20T02:21:37ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422012-01-01201210.1155/2012/385178385178Polystyrene Backbone Polymers Consisting of Alkyl-Substituted Triazine Side Groups for Phosphorescent OLEDsBeatrice Ch. D. Salert0Armin Wedel1Lutz Grubert2Thomas Eberle3Rémi Anémian4Hartmut Krueger5Department of Polymers and Electronics, Fraunhofer Institute for Applied Polymer Research, Geiselbergstraße 69, 14476 Potsdam, GermanyDepartment of Polymers and Electronics, Fraunhofer Institute for Applied Polymer Research, Geiselbergstraße 69, 14476 Potsdam, GermanyDepartment of Chemistry, Humboldt University, Brook-Taylor-Straße 2, 12489 Berlin, GermanyMerck KGaA, Frankfurter Straße 250, 64293 Darmstadt, GermanyMerck KGaA, Frankfurter Straße 250, 64293 Darmstadt, GermanyDepartment of Polymers and Electronics, Fraunhofer Institute for Applied Polymer Research, Geiselbergstraße 69, 14476 Potsdam, GermanyThis paper describes the synthesis of new electron-transporting styrene monomers and their corresponding polystyrenes all with a 2,4,6-triphenyl-1,3,5-triazine basic structure in the side group. The monomers differ in the alkyl substitution and in the meta-/paralinkage of the triazine to the polymer backbone. The thermal and spectroscopic properties of the new electron-transporting polymers are discussed in regard to their chemical structures. Phosphorescent OLEDs were prepared using the obtained electron-transporting polymers as the emissive layer material in blend systems together with a green iridium-based emitter 13 and a small molecule as an additional cohost with wideband gap characteristics (CoH-001). The performance of the OLEDs was characterized and discussed in regard to the chemical structure of the new electron-transporting polymers.http://dx.doi.org/10.1155/2012/385178
spellingShingle Beatrice Ch. D. Salert
Armin Wedel
Lutz Grubert
Thomas Eberle
Rémi Anémian
Hartmut Krueger
Polystyrene Backbone Polymers Consisting of Alkyl-Substituted Triazine Side Groups for Phosphorescent OLEDs
Advances in Materials Science and Engineering
title Polystyrene Backbone Polymers Consisting of Alkyl-Substituted Triazine Side Groups for Phosphorescent OLEDs
title_full Polystyrene Backbone Polymers Consisting of Alkyl-Substituted Triazine Side Groups for Phosphorescent OLEDs
title_fullStr Polystyrene Backbone Polymers Consisting of Alkyl-Substituted Triazine Side Groups for Phosphorescent OLEDs
title_full_unstemmed Polystyrene Backbone Polymers Consisting of Alkyl-Substituted Triazine Side Groups for Phosphorescent OLEDs
title_short Polystyrene Backbone Polymers Consisting of Alkyl-Substituted Triazine Side Groups for Phosphorescent OLEDs
title_sort polystyrene backbone polymers consisting of alkyl substituted triazine side groups for phosphorescent oleds
url http://dx.doi.org/10.1155/2012/385178
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