DEMONSTRATION OF HETEROARYLMETHANE OXIDATION IN A BENZIMIDAZOLE DERIVATIVE WITH THE USE OF UV SPECTROPHOTOMETRY AND X-RAY DIFFRACTION
In this work, we present the synthesis of a copper complex of 1-benzyl-2-[(5-methyl-isoxazol-3-yl)methyl]-benzimidazole, by using simultaneously UV spectrophotometry and X-ray diffraction. It has been possible for us to highlight an original oxidation of benzylbenzimidazole group in such complex lea...
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| Format: | Article |
| Language: | English |
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2012-03-01
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| Series: | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
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| Online Access: | http://pubs.ub.ro/dwnl.php?id=CSCC6201201V01S01A0002 |
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| author | Amal Haoudi Mohamed Benchidmi Youssef Kandri Rodi Khalid Attar Frédéric Capet Christian Rolando El Mokhtar Essassi |
| author_facet | Amal Haoudi Mohamed Benchidmi Youssef Kandri Rodi Khalid Attar Frédéric Capet Christian Rolando El Mokhtar Essassi |
| author_sort | Amal Haoudi |
| collection | DOAJ |
| description | In this work, we present the synthesis of a copper complex of 1-benzyl-2-[(5-methyl-isoxazol-3-yl)methyl]-benzimidazole, by using simultaneously UV spectrophotometry and X-ray diffraction. It has been possible for us to highlight an original oxidation of benzylbenzimidazole group in such complex leading to ketone. A kinetic study carried out by UV spectrophotometry shows well that the oxidation reaction proceeds according to the first-order kinetic law: K = 9.4×10-4 s-1 and t½ = 12.4 min. |
| format | Article |
| id | doaj-art-dc1ef5d917ab486bad3dd8bb06175eac |
| institution | OA Journals |
| issn | 1582-540X |
| language | English |
| publishDate | 2012-03-01 |
| publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
| record_format | Article |
| series | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
| spelling | doaj-art-dc1ef5d917ab486bad3dd8bb06175eac2025-08-20T02:00:39ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry1582-540X2012-03-011311926DEMONSTRATION OF HETEROARYLMETHANE OXIDATION IN A BENZIMIDAZOLE DERIVATIVE WITH THE USE OF UV SPECTROPHOTOMETRY AND X-RAY DIFFRACTIONAmal HaoudiMohamed BenchidmiYoussef Kandri RodiKhalid AttarFrédéric CapetChristian RolandoEl Mokhtar EssassiIn this work, we present the synthesis of a copper complex of 1-benzyl-2-[(5-methyl-isoxazol-3-yl)methyl]-benzimidazole, by using simultaneously UV spectrophotometry and X-ray diffraction. It has been possible for us to highlight an original oxidation of benzylbenzimidazole group in such complex leading to ketone. A kinetic study carried out by UV spectrophotometry shows well that the oxidation reaction proceeds according to the first-order kinetic law: K = 9.4×10-4 s-1 and t½ = 12.4 min.http://pubs.ub.ro/dwnl.php?id=CSCC6201201V01S01A0002complexationfunctionalised benzimidazolekineticUV spectrophotometryX-ray study |
| spellingShingle | Amal Haoudi Mohamed Benchidmi Youssef Kandri Rodi Khalid Attar Frédéric Capet Christian Rolando El Mokhtar Essassi DEMONSTRATION OF HETEROARYLMETHANE OXIDATION IN A BENZIMIDAZOLE DERIVATIVE WITH THE USE OF UV SPECTROPHOTOMETRY AND X-RAY DIFFRACTION Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry complexation functionalised benzimidazole kinetic UV spectrophotometry X-ray study |
| title | DEMONSTRATION OF HETEROARYLMETHANE OXIDATION IN A BENZIMIDAZOLE DERIVATIVE WITH THE USE OF UV SPECTROPHOTOMETRY AND X-RAY DIFFRACTION |
| title_full | DEMONSTRATION OF HETEROARYLMETHANE OXIDATION IN A BENZIMIDAZOLE DERIVATIVE WITH THE USE OF UV SPECTROPHOTOMETRY AND X-RAY DIFFRACTION |
| title_fullStr | DEMONSTRATION OF HETEROARYLMETHANE OXIDATION IN A BENZIMIDAZOLE DERIVATIVE WITH THE USE OF UV SPECTROPHOTOMETRY AND X-RAY DIFFRACTION |
| title_full_unstemmed | DEMONSTRATION OF HETEROARYLMETHANE OXIDATION IN A BENZIMIDAZOLE DERIVATIVE WITH THE USE OF UV SPECTROPHOTOMETRY AND X-RAY DIFFRACTION |
| title_short | DEMONSTRATION OF HETEROARYLMETHANE OXIDATION IN A BENZIMIDAZOLE DERIVATIVE WITH THE USE OF UV SPECTROPHOTOMETRY AND X-RAY DIFFRACTION |
| title_sort | demonstration of heteroarylmethane oxidation in a benzimidazole derivative with the use of uv spectrophotometry and x ray diffraction |
| topic | complexation functionalised benzimidazole kinetic UV spectrophotometry X-ray study |
| url | http://pubs.ub.ro/dwnl.php?id=CSCC6201201V01S01A0002 |
| work_keys_str_mv | AT amalhaoudi demonstrationofheteroarylmethaneoxidationinabenzimidazolederivativewiththeuseofuvspectrophotometryandxraydiffraction AT mohamedbenchidmi demonstrationofheteroarylmethaneoxidationinabenzimidazolederivativewiththeuseofuvspectrophotometryandxraydiffraction AT youssefkandrirodi demonstrationofheteroarylmethaneoxidationinabenzimidazolederivativewiththeuseofuvspectrophotometryandxraydiffraction AT khalidattar demonstrationofheteroarylmethaneoxidationinabenzimidazolederivativewiththeuseofuvspectrophotometryandxraydiffraction AT fredericcapet demonstrationofheteroarylmethaneoxidationinabenzimidazolederivativewiththeuseofuvspectrophotometryandxraydiffraction AT christianrolando demonstrationofheteroarylmethaneoxidationinabenzimidazolederivativewiththeuseofuvspectrophotometryandxraydiffraction AT elmokhtaressassi demonstrationofheteroarylmethaneoxidationinabenzimidazolederivativewiththeuseofuvspectrophotometryandxraydiffraction |