Iron complexes: green and sustainable synthesis and evaluation of their potency as antioxidants and inhibitors of DNA damage in rats

Three iron complexes were synthesized through green and sustainable procedures via chelation with salicylic acid, 3-methyl-1-phenyl-pyrazol-5-one, and ethylacetoactate under solvent-free conditions at room temperature. The synthesis assured the concept of both the twelve principles of Green Chemist...

Full description

Saved in:
Bibliographic Details
Main Authors: Fayze Mohamed Eissa, Heba Abdelaziz, Abdelsalam Arfein, Zeinab Mohamed
Format: Article
Language:English
Published: Universidade Estadual de Maringá 2024-12-01
Series:Acta Scientiarum: Biological Sciences
Subjects:
Online Access:https://periodicos.uem.br/ojs/index.php/ActaSciBiolSci/article/view/71230
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1849220343578755072
author Fayze Mohamed Eissa
Heba Abdelaziz
Abdelsalam Arfein
Zeinab Mohamed
author_facet Fayze Mohamed Eissa
Heba Abdelaziz
Abdelsalam Arfein
Zeinab Mohamed
author_sort Fayze Mohamed Eissa
collection DOAJ
description Three iron complexes were synthesized through green and sustainable procedures via chelation with salicylic acid, 3-methyl-1-phenyl-pyrazol-5-one, and ethylacetoactate under solvent-free conditions at room temperature. The synthesis assured the concept of both the twelve principles of Green Chemistry and Sustainability Commands. 48 male Wistar albino rats were administered gentamicin (GM) at a dose of 80 mg kg-1 day-1, with or without (I-SA), (I-MPP), (I-EAA) (120 mg kg-1 day-1) to evaluate the complexes' potential protective effects against GM-induced hepatotoxicity and nephrotoxicity. Oxidative stress markers and DNA fragmentation increased significantly, while the activity of the antioxidant enzymes SOD and CAT notably decreased. The study findings suggest that the three complexes serve as novel natural antioxidants, mitigating oxygen free radicals, lipid peroxidation, and DNA damage in gentamicin-treated rats. These compounds hold promise as potential natural drugs in future applications.
format Article
id doaj-art-dc1c8186bfca48cfa0f9cc071a1d2928
institution Kabale University
issn 1679-9283
1807-863X
language English
publishDate 2024-12-01
publisher Universidade Estadual de Maringá
record_format Article
series Acta Scientiarum: Biological Sciences
spelling doaj-art-dc1c8186bfca48cfa0f9cc071a1d29282024-12-13T18:54:54ZengUniversidade Estadual de MaringáActa Scientiarum: Biological Sciences1679-92831807-863X2024-12-0146110.4025/actascibiolsci.v46i1.71230Iron complexes: green and sustainable synthesis and evaluation of their potency as antioxidants and inhibitors of DNA damage in ratsFayze Mohamed Eissa0Heba Abdelaziz1Abdelsalam Arfein2Zeinab Mohamed3Aswan UniversityAswan UniversityAswan UniversityAswan University Three iron complexes were synthesized through green and sustainable procedures via chelation with salicylic acid, 3-methyl-1-phenyl-pyrazol-5-one, and ethylacetoactate under solvent-free conditions at room temperature. The synthesis assured the concept of both the twelve principles of Green Chemistry and Sustainability Commands. 48 male Wistar albino rats were administered gentamicin (GM) at a dose of 80 mg kg-1 day-1, with or without (I-SA), (I-MPP), (I-EAA) (120 mg kg-1 day-1) to evaluate the complexes' potential protective effects against GM-induced hepatotoxicity and nephrotoxicity. Oxidative stress markers and DNA fragmentation increased significantly, while the activity of the antioxidant enzymes SOD and CAT notably decreased. The study findings suggest that the three complexes serve as novel natural antioxidants, mitigating oxygen free radicals, lipid peroxidation, and DNA damage in gentamicin-treated rats. These compounds hold promise as potential natural drugs in future applications. https://periodicos.uem.br/ojs/index.php/ActaSciBiolSci/article/view/71230green synthesis; sustainability; antioxidants markers; DNA damage; iron complexes
spellingShingle Fayze Mohamed Eissa
Heba Abdelaziz
Abdelsalam Arfein
Zeinab Mohamed
Iron complexes: green and sustainable synthesis and evaluation of their potency as antioxidants and inhibitors of DNA damage in rats
Acta Scientiarum: Biological Sciences
green synthesis; sustainability; antioxidants markers; DNA damage; iron complexes
title Iron complexes: green and sustainable synthesis and evaluation of their potency as antioxidants and inhibitors of DNA damage in rats
title_full Iron complexes: green and sustainable synthesis and evaluation of their potency as antioxidants and inhibitors of DNA damage in rats
title_fullStr Iron complexes: green and sustainable synthesis and evaluation of their potency as antioxidants and inhibitors of DNA damage in rats
title_full_unstemmed Iron complexes: green and sustainable synthesis and evaluation of their potency as antioxidants and inhibitors of DNA damage in rats
title_short Iron complexes: green and sustainable synthesis and evaluation of their potency as antioxidants and inhibitors of DNA damage in rats
title_sort iron complexes green and sustainable synthesis and evaluation of their potency as antioxidants and inhibitors of dna damage in rats
topic green synthesis; sustainability; antioxidants markers; DNA damage; iron complexes
url https://periodicos.uem.br/ojs/index.php/ActaSciBiolSci/article/view/71230
work_keys_str_mv AT fayzemohamedeissa ironcomplexesgreenandsustainablesynthesisandevaluationoftheirpotencyasantioxidantsandinhibitorsofdnadamageinrats
AT hebaabdelaziz ironcomplexesgreenandsustainablesynthesisandevaluationoftheirpotencyasantioxidantsandinhibitorsofdnadamageinrats
AT abdelsalamarfein ironcomplexesgreenandsustainablesynthesisandevaluationoftheirpotencyasantioxidantsandinhibitorsofdnadamageinrats
AT zeinabmohamed ironcomplexesgreenandsustainablesynthesisandevaluationoftheirpotencyasantioxidantsandinhibitorsofdnadamageinrats