Research progress in high-temperature corrosion of Ni-base alloys in coal ash/flue gas

To meet the requirements of green, efficient, and low-carbon development, the next generation of 700 ℃ level advanced ultra-supercritical (A-USC) coal-fired power plants with increased steam temperature and pressure has received great attention worldwide. However, the increased steam parameters and...

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Main Authors: DU Lingxiao, DING Hang, XIE Yun
Format: Article
Language:zho
Published: Journal of Materials Engineering 2025-02-01
Series:Cailiao gongcheng
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Online Access:https://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2024.000114
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author DU Lingxiao
DING Hang
XIE Yun
author_facet DU Lingxiao
DING Hang
XIE Yun
author_sort DU Lingxiao
collection DOAJ
description To meet the requirements of green, efficient, and low-carbon development, the next generation of 700 ℃ level advanced ultra-supercritical (A-USC) coal-fired power plants with increased steam temperature and pressure has received great attention worldwide. However, the increased steam parameters and harsh service environment corresponding to the A-USC boiler seriously threaten the safe operation of heat-exchanging components. The traditional ferritic/martensitic heat-resistant steels and austenitic stainless steels cannot survive due to their inadequate creep strength and corrosion resistance at temperatures above 700 ℃, and Ni-base alloys are required. Based on the coal ash/flue gas environment related to A-USC boiler adopting oxy-fuel combustion, the research progress in high-temperature corrosion of Ni-base alloys exposed to flue gas and coal ash was summarized, especially focusing on the effect of corrosive CO2, H2O(g), SO2 gases and sulfate salts on the thermal growth of CrO3 protective film on Ni-base alloys. Finally, the effect of oxide particulates in coal ash, Cl-containing gases, and molten KCl salts resulting from biomass combustion on the high-temperature corrosion behavior of Ni-base alloys is the key direction for future research.
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spelling doaj-art-dbda3e803e7b46bda73a504150e1a2162025-08-20T03:06:06ZzhoJournal of Materials EngineeringCailiao gongcheng1001-43812025-02-0153210611410.11868/j.issn.1001-4381.2024.0001141001-4381(2025)02-0106-09Research progress in high-temperature corrosion of Ni-base alloys in coal ash/flue gasDU Lingxiao0DING Hang1XIE Yun2School of Materials Science and Engineering,Nanchang Hangkong University,Nanchang 330063,ChinaSchool of Materials Science and Engineering,Nanchang Hangkong University,Nanchang 330063,ChinaSchool of Materials Science and Engineering,Nanchang Hangkong University,Nanchang 330063,ChinaTo meet the requirements of green, efficient, and low-carbon development, the next generation of 700 ℃ level advanced ultra-supercritical (A-USC) coal-fired power plants with increased steam temperature and pressure has received great attention worldwide. However, the increased steam parameters and harsh service environment corresponding to the A-USC boiler seriously threaten the safe operation of heat-exchanging components. The traditional ferritic/martensitic heat-resistant steels and austenitic stainless steels cannot survive due to their inadequate creep strength and corrosion resistance at temperatures above 700 ℃, and Ni-base alloys are required. Based on the coal ash/flue gas environment related to A-USC boiler adopting oxy-fuel combustion, the research progress in high-temperature corrosion of Ni-base alloys exposed to flue gas and coal ash was summarized, especially focusing on the effect of corrosive CO2, H2O(g), SO2 gases and sulfate salts on the thermal growth of CrO3 protective film on Ni-base alloys. Finally, the effect of oxide particulates in coal ash, Cl-containing gases, and molten KCl salts resulting from biomass combustion on the high-temperature corrosion behavior of Ni-base alloys is the key direction for future research.https://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2024.000114ni-base alloycoal ash/flue gas corrosionhigh-temperature corrosionadvanced ultra-supercritical boiler
spellingShingle DU Lingxiao
DING Hang
XIE Yun
Research progress in high-temperature corrosion of Ni-base alloys in coal ash/flue gas
Cailiao gongcheng
ni-base alloy
coal ash/flue gas corrosion
high-temperature corrosion
advanced ultra-supercritical boiler
title Research progress in high-temperature corrosion of Ni-base alloys in coal ash/flue gas
title_full Research progress in high-temperature corrosion of Ni-base alloys in coal ash/flue gas
title_fullStr Research progress in high-temperature corrosion of Ni-base alloys in coal ash/flue gas
title_full_unstemmed Research progress in high-temperature corrosion of Ni-base alloys in coal ash/flue gas
title_short Research progress in high-temperature corrosion of Ni-base alloys in coal ash/flue gas
title_sort research progress in high temperature corrosion of ni base alloys in coal ash flue gas
topic ni-base alloy
coal ash/flue gas corrosion
high-temperature corrosion
advanced ultra-supercritical boiler
url https://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2024.000114
work_keys_str_mv AT dulingxiao researchprogressinhightemperaturecorrosionofnibasealloysincoalashfluegas
AT dinghang researchprogressinhightemperaturecorrosionofnibasealloysincoalashfluegas
AT xieyun researchprogressinhightemperaturecorrosionofnibasealloysincoalashfluegas