Effect of K2O on the lubrication and heat transfer performance of continuous casting mold flux

To improve the lubrication performance and heat transfer control capability of continuous casting mold flux, the effects of K2O on its properties were systematically investigated by using a rotary viscometer, infrared emissivity technique (IET), infrared spectrometer, Raman spectrometer, and X-ray d...

Full description

Saved in:
Bibliographic Details
Main Authors: Liguang ZHU, Chaofei GUO, Zhihong GUO, Baochen HAN, Xianhui WANG, Tianwei XIE, Hairui ZHAO, Lin CHENG
Format: Article
Language:zho
Published: Hebei University of Science and Technology 2025-04-01
Series:Journal of Hebei University of Science and Technology
Subjects:
Online Access:https://xuebao.hebust.edu.cn/hbkjdx/article/pdf/b202502010?st=article_issue
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1849310765577666560
author Liguang ZHU
Chaofei GUO
Zhihong GUO
Baochen HAN
Xianhui WANG
Tianwei XIE
Hairui ZHAO
Lin CHENG
author_facet Liguang ZHU
Chaofei GUO
Zhihong GUO
Baochen HAN
Xianhui WANG
Tianwei XIE
Hairui ZHAO
Lin CHENG
author_sort Liguang ZHU
collection DOAJ
description To improve the lubrication performance and heat transfer control capability of continuous casting mold flux, the effects of K2O on its properties were systematically investigated by using a rotary viscometer, infrared emissivity technique (IET), infrared spectrometer, Raman spectrometer, and X-ray diffractometer (XRD). The results indicate that when the K2O content increases from 0 to 6 wt.%, the viscosity of the mold flux (at 1 300 ℃) initially decreases and then increases, and reaching its minimum value at 2 wt.% K2O, along with the lowest transition temperature. Microstructural analysis reveals that the proportions of simple structural units (Q0</sup> and Q1</sup>) in the molten slag firstly increase and then decrease, while complex structural units (Al-O-Al and Si-O-Al) exhibit the opposite trend. This leads to an initial reduction followed by an increase in the overall structural complexity and polymerization degree of the slag. Furthermore, increasing K2O content promotes the precipitation of the Bredigite phase (Ca7Mg(SiO4)4) while suppressing the formation of the Cuspidine phase (Ca4Si2F2O7), resulting in a gradual decline in the heat flux density of the mold flux. Comprehensive analysis demonstrates that the optimal K2O content of 2 wt.% significantly enhances both lubrication performance and heat transfer regulation of the mold flux, which provides theoretical reference for optimizing continuous casting processes.
format Article
id doaj-art-db7283813eef420fa199e987d05a5b4f
institution Kabale University
issn 1008-1542
language zho
publishDate 2025-04-01
publisher Hebei University of Science and Technology
record_format Article
series Journal of Hebei University of Science and Technology
spelling doaj-art-db7283813eef420fa199e987d05a5b4f2025-08-20T03:53:38ZzhoHebei University of Science and TechnologyJournal of Hebei University of Science and Technology1008-15422025-04-0146220721410.7535/hbkd.2025yx02010b202502010Effect of K2O on the lubrication and heat transfer performance of continuous casting mold fluxLiguang ZHU0Chaofei GUO1Zhihong GUO2Baochen HAN3Xianhui WANG4Tianwei XIE5Hairui ZHAO6Lin CHENG7School of Materials Science and Engineering, Hebei University of Science and Technology, Shijiazhuang, Hebei 050018, ChinaSchool of Materials Science and Engineering, Hebei University of Science and Technology, Shijiazhuang, Hebei 050018, ChinaSchool of Materials Science and Engineering, Hebei University of Science and Technology, Shijiazhuang, Hebei 050018, ChinaSchool of Materials Science and Engineering, Hebei University of Science and Technology, Shijiazhuang, Hebei 050018, ChinaZhi Xin Qian'an Electromagnetic Materials Beijing Shougang Company Limited, Tangshan, Hebei 064404, ChinaZhi Xin Qian'an Electromagnetic Materials Beijing Shougang Company Limited, Tangshan, Hebei 064404, ChinaZhi Xin Qian'an Electromagnetic Materials Beijing Shougang Company Limited, Tangshan, Hebei 064404, ChinaZhi Xin Qian'an Electromagnetic Materials Beijing Shougang Company Limited, Tangshan, Hebei 064404, ChinaTo improve the lubrication performance and heat transfer control capability of continuous casting mold flux, the effects of K2O on its properties were systematically investigated by using a rotary viscometer, infrared emissivity technique (IET), infrared spectrometer, Raman spectrometer, and X-ray diffractometer (XRD). The results indicate that when the K2O content increases from 0 to 6 wt.%, the viscosity of the mold flux (at 1 300 ℃) initially decreases and then increases, and reaching its minimum value at 2 wt.% K2O, along with the lowest transition temperature. Microstructural analysis reveals that the proportions of simple structural units (Q0</sup> and Q1</sup>) in the molten slag firstly increase and then decrease, while complex structural units (Al-O-Al and Si-O-Al) exhibit the opposite trend. This leads to an initial reduction followed by an increase in the overall structural complexity and polymerization degree of the slag. Furthermore, increasing K2O content promotes the precipitation of the Bredigite phase (Ca7Mg(SiO4)4) while suppressing the formation of the Cuspidine phase (Ca4Si2F2O7), resulting in a gradual decline in the heat flux density of the mold flux. Comprehensive analysis demonstrates that the optimal K2O content of 2 wt.% significantly enhances both lubrication performance and heat transfer regulation of the mold flux, which provides theoretical reference for optimizing continuous casting processes.https://xuebao.hebust.edu.cn/hbkjdx/article/pdf/b202502010?st=article_issuesteelmaking; continuous casting; mold flux; lubrication; heat transfer
spellingShingle Liguang ZHU
Chaofei GUO
Zhihong GUO
Baochen HAN
Xianhui WANG
Tianwei XIE
Hairui ZHAO
Lin CHENG
Effect of K2O on the lubrication and heat transfer performance of continuous casting mold flux
Journal of Hebei University of Science and Technology
steelmaking; continuous casting; mold flux; lubrication; heat transfer
title Effect of K2O on the lubrication and heat transfer performance of continuous casting mold flux
title_full Effect of K2O on the lubrication and heat transfer performance of continuous casting mold flux
title_fullStr Effect of K2O on the lubrication and heat transfer performance of continuous casting mold flux
title_full_unstemmed Effect of K2O on the lubrication and heat transfer performance of continuous casting mold flux
title_short Effect of K2O on the lubrication and heat transfer performance of continuous casting mold flux
title_sort effect of k2o on the lubrication and heat transfer performance of continuous casting mold flux
topic steelmaking; continuous casting; mold flux; lubrication; heat transfer
url https://xuebao.hebust.edu.cn/hbkjdx/article/pdf/b202502010?st=article_issue
work_keys_str_mv AT liguangzhu effectofk2oonthelubricationandheattransferperformanceofcontinuouscastingmoldflux
AT chaofeiguo effectofk2oonthelubricationandheattransferperformanceofcontinuouscastingmoldflux
AT zhihongguo effectofk2oonthelubricationandheattransferperformanceofcontinuouscastingmoldflux
AT baochenhan effectofk2oonthelubricationandheattransferperformanceofcontinuouscastingmoldflux
AT xianhuiwang effectofk2oonthelubricationandheattransferperformanceofcontinuouscastingmoldflux
AT tianweixie effectofk2oonthelubricationandheattransferperformanceofcontinuouscastingmoldflux
AT hairuizhao effectofk2oonthelubricationandheattransferperformanceofcontinuouscastingmoldflux
AT lincheng effectofk2oonthelubricationandheattransferperformanceofcontinuouscastingmoldflux