Innovative ceramic-matrix composite substrates with tunable electrical conductivity for high-power applications

A wide band gap semiconductor power module can operate at higher voltages as compared with its traditional silicon counterpart. However, its insulating system undergoes stronger electric fields at the triple point between the ceramic substrate, the metallic tracks and the encapsulating polymer, whic...

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Main Authors: Driss Kenfaui, Zarel Valdez-Nava, Lionel Laudebat, Marie-Laure Locatelli, Céline Combettes, Vincent Bley, Sorin Dinculescu, Christophe Tenailleau, Pascal Dufour, Sophie Guillemet-Fritsch
Format: Article
Language:English
Published: Taylor & Francis Group 2022-12-01
Series:Science and Technology of Advanced Materials
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Online Access:https://www.tandfonline.com/doi/10.1080/14686996.2022.2137695
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author Driss Kenfaui
Zarel Valdez-Nava
Lionel Laudebat
Marie-Laure Locatelli
Céline Combettes
Vincent Bley
Sorin Dinculescu
Christophe Tenailleau
Pascal Dufour
Sophie Guillemet-Fritsch
author_facet Driss Kenfaui
Zarel Valdez-Nava
Lionel Laudebat
Marie-Laure Locatelli
Céline Combettes
Vincent Bley
Sorin Dinculescu
Christophe Tenailleau
Pascal Dufour
Sophie Guillemet-Fritsch
author_sort Driss Kenfaui
collection DOAJ
description A wide band gap semiconductor power module can operate at higher voltages as compared with its traditional silicon counterpart. However, its insulating system undergoes stronger electric fields at the triple point between the ceramic substrate, the metallic tracks and the encapsulating polymer, which can dramatically reduce its lifespan. Here we report an original concept based on the local modification of the substrate properties to mitigate such electrical stress. Numerical simulations revealed its potential to reduce this constraint by up to 50%. This concept was realized by developing, through a practical approach, a novel substrate made of an AlN-based ceramic (material A) integrating a nanocomposite volume endowed with controlled properties and geometry. This approach implies first the spark plasma sintering of the AlN powder with additives (Y2O3, CaF2) to endow the material A with a very low electrical conductivity (σ) and high thermal conductivity (k). Graphene nanoplatelets (GNP) were incorporated within this material to fabricate a nanocomposite with a controlled σ anisotropy that otherwise reached a striking ratio of 106 at 20°C for 1.25 vol% GNP. Our approach secondly aimed at developing an effective process allowing to integrate this nanocomposite into the material A with a very high degree of reproducibility. It finally consisted in establishing the electrical contacts on the achieved substrate and encapsulating it for breakdown testing. The novel substrate enabled a mitigation of the electrical constraint by diminishing its intensity and shifting it from the triple point to a less constrained area. It already brought an improvement in breakdown voltage (VB) by 15% as compared to the traditional substrate, and revealed the potential for achieving higher VB as well. This work lays the foundation for the development of novel multifunctional ceramic-matrix composite substrates sought for power electronics as well as for other potential applications.
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spelling doaj-art-dac2ff76caa24450b15e6bc5a3b880f12025-08-20T01:52:31ZengTaylor & Francis GroupScience and Technology of Advanced Materials1468-69961878-55142022-12-0123173575110.1080/14686996.2022.2137695Innovative ceramic-matrix composite substrates with tunable electrical conductivity for high-power applicationsDriss Kenfaui0Zarel Valdez-Nava1Lionel Laudebat2Marie-Laure Locatelli3Céline Combettes4Vincent Bley5Sorin Dinculescu6Christophe Tenailleau7Pascal Dufour8Sophie Guillemet-Fritsch9LAPLACE, Université de Toulouse, CNRS, INPT, UPS, Toulouse, FranceLAPLACE, Université de Toulouse, CNRS, INPT, UPS, Toulouse, FranceLAPLACE, Université de Toulouse, CNRS, INPT, UPS, Toulouse, FranceLAPLACE, Université de Toulouse, CNRS, INPT, UPS, Toulouse, FranceLAPLACE, Université de Toulouse, CNRS, INPT, UPS, Toulouse, FranceLAPLACE, Université de Toulouse, CNRS, INPT, UPS, Toulouse, FranceLAPLACE, Université de Toulouse, CNRS, INPT, UPS, Toulouse, FranceCIRIMAT (Centre Inter-universitaire de Recherche et d’Ingénierie des Matériaux), Université́ de Toulouse, CNRS, INPT, UPS, Toulouse, FranceCIRIMAT (Centre Inter-universitaire de Recherche et d’Ingénierie des Matériaux), Université́ de Toulouse, CNRS, INPT, UPS, Toulouse, FranceCIRIMAT (Centre Inter-universitaire de Recherche et d’Ingénierie des Matériaux), Université́ de Toulouse, CNRS, INPT, UPS, Toulouse, FranceA wide band gap semiconductor power module can operate at higher voltages as compared with its traditional silicon counterpart. However, its insulating system undergoes stronger electric fields at the triple point between the ceramic substrate, the metallic tracks and the encapsulating polymer, which can dramatically reduce its lifespan. Here we report an original concept based on the local modification of the substrate properties to mitigate such electrical stress. Numerical simulations revealed its potential to reduce this constraint by up to 50%. This concept was realized by developing, through a practical approach, a novel substrate made of an AlN-based ceramic (material A) integrating a nanocomposite volume endowed with controlled properties and geometry. This approach implies first the spark plasma sintering of the AlN powder with additives (Y2O3, CaF2) to endow the material A with a very low electrical conductivity (σ) and high thermal conductivity (k). Graphene nanoplatelets (GNP) were incorporated within this material to fabricate a nanocomposite with a controlled σ anisotropy that otherwise reached a striking ratio of 106 at 20°C for 1.25 vol% GNP. Our approach secondly aimed at developing an effective process allowing to integrate this nanocomposite into the material A with a very high degree of reproducibility. It finally consisted in establishing the electrical contacts on the achieved substrate and encapsulating it for breakdown testing. The novel substrate enabled a mitigation of the electrical constraint by diminishing its intensity and shifting it from the triple point to a less constrained area. It already brought an improvement in breakdown voltage (VB) by 15% as compared to the traditional substrate, and revealed the potential for achieving higher VB as well. This work lays the foundation for the development of novel multifunctional ceramic-matrix composite substrates sought for power electronics as well as for other potential applications.https://www.tandfonline.com/doi/10.1080/14686996.2022.2137695Power moduleceramic-matrix composite substrategraphenespark plasma sinteringelectrical conductivity anisotropybreakdown voltage
spellingShingle Driss Kenfaui
Zarel Valdez-Nava
Lionel Laudebat
Marie-Laure Locatelli
Céline Combettes
Vincent Bley
Sorin Dinculescu
Christophe Tenailleau
Pascal Dufour
Sophie Guillemet-Fritsch
Innovative ceramic-matrix composite substrates with tunable electrical conductivity for high-power applications
Science and Technology of Advanced Materials
Power module
ceramic-matrix composite substrate
graphene
spark plasma sintering
electrical conductivity anisotropy
breakdown voltage
title Innovative ceramic-matrix composite substrates with tunable electrical conductivity for high-power applications
title_full Innovative ceramic-matrix composite substrates with tunable electrical conductivity for high-power applications
title_fullStr Innovative ceramic-matrix composite substrates with tunable electrical conductivity for high-power applications
title_full_unstemmed Innovative ceramic-matrix composite substrates with tunable electrical conductivity for high-power applications
title_short Innovative ceramic-matrix composite substrates with tunable electrical conductivity for high-power applications
title_sort innovative ceramic matrix composite substrates with tunable electrical conductivity for high power applications
topic Power module
ceramic-matrix composite substrate
graphene
spark plasma sintering
electrical conductivity anisotropy
breakdown voltage
url https://www.tandfonline.com/doi/10.1080/14686996.2022.2137695
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