Preparation and Characteristic of Polyurethane Powder Adhesives with Heating Resistance Modified by Nanosilica

Polyurethane powder adhesives (PPAs) have a great application prospect in various areas. However, the weakly adhesion property at high temperature greatly hindered its application. In this study, nanosilica as reinforcing agent and dispersing agent has been introduced during the preparation of PPAs....

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Main Authors: Xiue Ren, Zepeng Liao, Chenyang Fan, Haibo Lin
Format: Article
Language:English
Published: Wiley 2022-01-01
Series:Advances in Polymer Technology
Online Access:http://dx.doi.org/10.1155/2022/6384600
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author Xiue Ren
Zepeng Liao
Chenyang Fan
Haibo Lin
author_facet Xiue Ren
Zepeng Liao
Chenyang Fan
Haibo Lin
author_sort Xiue Ren
collection DOAJ
description Polyurethane powder adhesives (PPAs) have a great application prospect in various areas. However, the weakly adhesion property at high temperature greatly hindered its application. In this study, nanosilica as reinforcing agent and dispersing agent has been introduced during the preparation of PPAs. A series of the polyurethane powder adhesives modified by nanosilica were prepared and the influence of adding order of nanosilica on the heat resistance and adhesive strength properties of PPAs has been investigated. The results showed that the T-peel strength of most samples after second heat (heated at 70°C for 24 hours) decreased about 60-80% comparing with the original T-peel strength. However, PPSY only decreased 17.5%, which indicated the nanosilica added after the chain extension reaction, in the prepolymer synthesis could increase the heat resistance performance of polyurethane powder adhesives. It also means the nanosilica was doped between the PU chains keeping the original form as enhancement reagent adding the nanosilica after the chain extension reaction. The excellent heat resistance performance of PPSY could meet the requirements of the industrial gluing in the fields of footwear.
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spelling doaj-art-da933d33e3c9455fb893eab1a3f5a3ce2025-08-20T02:21:20ZengWileyAdvances in Polymer Technology1098-23292022-01-01202210.1155/2022/6384600Preparation and Characteristic of Polyurethane Powder Adhesives with Heating Resistance Modified by NanosilicaXiue Ren0Zepeng Liao1Chenyang Fan2Haibo Lin3School of Chemical Engineering and New Energy MaterialsSchool of Chemical Engineering and New Energy MaterialsSchool of Chemical Engineering and New Energy MaterialsSchool of Chemical Engineering and New Energy MaterialsPolyurethane powder adhesives (PPAs) have a great application prospect in various areas. However, the weakly adhesion property at high temperature greatly hindered its application. In this study, nanosilica as reinforcing agent and dispersing agent has been introduced during the preparation of PPAs. A series of the polyurethane powder adhesives modified by nanosilica were prepared and the influence of adding order of nanosilica on the heat resistance and adhesive strength properties of PPAs has been investigated. The results showed that the T-peel strength of most samples after second heat (heated at 70°C for 24 hours) decreased about 60-80% comparing with the original T-peel strength. However, PPSY only decreased 17.5%, which indicated the nanosilica added after the chain extension reaction, in the prepolymer synthesis could increase the heat resistance performance of polyurethane powder adhesives. It also means the nanosilica was doped between the PU chains keeping the original form as enhancement reagent adding the nanosilica after the chain extension reaction. The excellent heat resistance performance of PPSY could meet the requirements of the industrial gluing in the fields of footwear.http://dx.doi.org/10.1155/2022/6384600
spellingShingle Xiue Ren
Zepeng Liao
Chenyang Fan
Haibo Lin
Preparation and Characteristic of Polyurethane Powder Adhesives with Heating Resistance Modified by Nanosilica
Advances in Polymer Technology
title Preparation and Characteristic of Polyurethane Powder Adhesives with Heating Resistance Modified by Nanosilica
title_full Preparation and Characteristic of Polyurethane Powder Adhesives with Heating Resistance Modified by Nanosilica
title_fullStr Preparation and Characteristic of Polyurethane Powder Adhesives with Heating Resistance Modified by Nanosilica
title_full_unstemmed Preparation and Characteristic of Polyurethane Powder Adhesives with Heating Resistance Modified by Nanosilica
title_short Preparation and Characteristic of Polyurethane Powder Adhesives with Heating Resistance Modified by Nanosilica
title_sort preparation and characteristic of polyurethane powder adhesives with heating resistance modified by nanosilica
url http://dx.doi.org/10.1155/2022/6384600
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AT zepengliao preparationandcharacteristicofpolyurethanepowderadhesiveswithheatingresistancemodifiedbynanosilica
AT chenyangfan preparationandcharacteristicofpolyurethanepowderadhesiveswithheatingresistancemodifiedbynanosilica
AT haibolin preparationandcharacteristicofpolyurethanepowderadhesiveswithheatingresistancemodifiedbynanosilica