Recycling of Oily Sludge as a Roadbed Material Utilizing Phosphogypsum-Based Cementitious Materials

Oily sludge is a hazardous waste containing emulsified petroleum hydrocarbons, water, heavy metals, and solid particles. The objective of this work is to employ solidification/stabilization (S/S) techniques to utilize oily sludge as a roadbed material with ordinary Portland cement (OPC), fly ash (FA...

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Main Authors: Wei Xiao, Xiao Yao, Fuyang Zhang
Format: Article
Language:English
Published: Wiley 2019-01-01
Series:Advances in Civil Engineering
Online Access:http://dx.doi.org/10.1155/2019/6280715
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author Wei Xiao
Xiao Yao
Fuyang Zhang
author_facet Wei Xiao
Xiao Yao
Fuyang Zhang
author_sort Wei Xiao
collection DOAJ
description Oily sludge is a hazardous waste containing emulsified petroleum hydrocarbons, water, heavy metals, and solid particles. The objective of this work is to employ solidification/stabilization (S/S) techniques to utilize oily sludge as a roadbed material with ordinary Portland cement (OPC), fly ash (FA), and silica fume (SF) as binders and phosphogypsum (PG) as a stabilizer. The efficacy of the S/S process is assessed mainly through an unconfined compressive strength (UCS) test and a toxicity leaching test. Road performance, including water stability, freeze-thaw resistance, and volume stability, is also tested on the solidified samples. The mineralogical compositions, microstructures, and pore structure are characterized through X-ray diffractometry (XRD), scanning electron microscopy (SEM), and mercury intrusion porosimetry (MIP). The results show that the addition of 20% binders (OPC : FA : SF = 1 : 0.7 : 0.8) in combination with phosphogypsum to the oily sludge not only increases the 28-day compressive strength of the solidified samples and remarkably decreases the release of heavy metals but also refines the pore structure and compacts the microstructure. The solidified body had sufficient strength and good water stability performance, freeze-thaw resistance, and volumetric stability. This solidification/stabilization (S/S) process, which combines oily sludge treatment and phosphogypsum resource utilization, significantly enhances environmental protection and renders the solidified product economically profitable.
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spelling doaj-art-da8655c90ba44942b503cf3a18776e022025-02-03T05:51:23ZengWileyAdvances in Civil Engineering1687-80861687-80942019-01-01201910.1155/2019/62807156280715Recycling of Oily Sludge as a Roadbed Material Utilizing Phosphogypsum-Based Cementitious MaterialsWei Xiao0Xiao Yao1Fuyang Zhang2College of Materials Science and Engineering, Nanjing Tech University, Nanjing 210009, ChinaCollege of Materials Science and Engineering, Nanjing Tech University, Nanjing 210009, ChinaCollege of Materials Science and Engineering, Nanjing Tech University, Nanjing 210009, ChinaOily sludge is a hazardous waste containing emulsified petroleum hydrocarbons, water, heavy metals, and solid particles. The objective of this work is to employ solidification/stabilization (S/S) techniques to utilize oily sludge as a roadbed material with ordinary Portland cement (OPC), fly ash (FA), and silica fume (SF) as binders and phosphogypsum (PG) as a stabilizer. The efficacy of the S/S process is assessed mainly through an unconfined compressive strength (UCS) test and a toxicity leaching test. Road performance, including water stability, freeze-thaw resistance, and volume stability, is also tested on the solidified samples. The mineralogical compositions, microstructures, and pore structure are characterized through X-ray diffractometry (XRD), scanning electron microscopy (SEM), and mercury intrusion porosimetry (MIP). The results show that the addition of 20% binders (OPC : FA : SF = 1 : 0.7 : 0.8) in combination with phosphogypsum to the oily sludge not only increases the 28-day compressive strength of the solidified samples and remarkably decreases the release of heavy metals but also refines the pore structure and compacts the microstructure. The solidified body had sufficient strength and good water stability performance, freeze-thaw resistance, and volumetric stability. This solidification/stabilization (S/S) process, which combines oily sludge treatment and phosphogypsum resource utilization, significantly enhances environmental protection and renders the solidified product economically profitable.http://dx.doi.org/10.1155/2019/6280715
spellingShingle Wei Xiao
Xiao Yao
Fuyang Zhang
Recycling of Oily Sludge as a Roadbed Material Utilizing Phosphogypsum-Based Cementitious Materials
Advances in Civil Engineering
title Recycling of Oily Sludge as a Roadbed Material Utilizing Phosphogypsum-Based Cementitious Materials
title_full Recycling of Oily Sludge as a Roadbed Material Utilizing Phosphogypsum-Based Cementitious Materials
title_fullStr Recycling of Oily Sludge as a Roadbed Material Utilizing Phosphogypsum-Based Cementitious Materials
title_full_unstemmed Recycling of Oily Sludge as a Roadbed Material Utilizing Phosphogypsum-Based Cementitious Materials
title_short Recycling of Oily Sludge as a Roadbed Material Utilizing Phosphogypsum-Based Cementitious Materials
title_sort recycling of oily sludge as a roadbed material utilizing phosphogypsum based cementitious materials
url http://dx.doi.org/10.1155/2019/6280715
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AT xiaoyao recyclingofoilysludgeasaroadbedmaterialutilizingphosphogypsumbasedcementitiousmaterials
AT fuyangzhang recyclingofoilysludgeasaroadbedmaterialutilizingphosphogypsumbasedcementitiousmaterials