Attrition behavior analysis of four oxygen carriers in the in-situ redox jet attrition reactor

The anti-attrition properties of oxygen carriers (OCs) significantly impact the operation cost in chemical looping processes. A custom jet attrition reactor evaluates the attrition resistance of four OCs: ilmenite (Ilm-NO), CuFe bi-ore OC via hydroforming (CuFe-Hy), and two perovskites via spray dry...

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Main Authors: Xianyu Liu, Xin Wu, Daofeng Mei, Jinchen Ma, Haibo Zhao
Format: Article
Language:English
Published: Elsevier 2025-10-01
Series:Fuel Processing Technology
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Online Access:http://www.sciencedirect.com/science/article/pii/S0378382025001237
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author Xianyu Liu
Xin Wu
Daofeng Mei
Jinchen Ma
Haibo Zhao
author_facet Xianyu Liu
Xin Wu
Daofeng Mei
Jinchen Ma
Haibo Zhao
author_sort Xianyu Liu
collection DOAJ
description The anti-attrition properties of oxygen carriers (OCs) significantly impact the operation cost in chemical looping processes. A custom jet attrition reactor evaluates the attrition resistance of four OCs: ilmenite (Ilm-NO), CuFe bi-ore OC via hydroforming (CuFe-Hy), and two perovskites via spray drying and hydroforming (Per-SD and Per-Hy), through cold, hot, and redox attrition tests. The anti-attrition performance order across all tests is Ilm-NO > Per-Hy > CuFe-Hy > Per-SD. Post-testing characterizations are conducted, including particle size distributions of consumed particles and captured powders, structure properties, and compositional evolution. Oxygen carrier lifetimes are quantified based on the particle size distributions. Multiple stresses affecting oxygen carrier attrition exhibit antagonistic interactions rather than linear superposition. Element migration, particle expansion, and strength evolution of the tested oxygen carriers are observed. Particle density and crushing strength are highly related to the anti-attrition properties of oxygen carriers. This study develops an efficient method for evaluating OCs under the in-situ redox condition with a high-velocity jet, offering guidance for designing OCs with high attrition resistance and advancing the study of attrition mechanisms.
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publishDate 2025-10-01
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series Fuel Processing Technology
spelling doaj-art-da1c43ed502840afb7bb48eae1cc77912025-08-20T03:58:17ZengElsevierFuel Processing Technology0378-38202025-10-0127610829910.1016/j.fuproc.2025.108299Attrition behavior analysis of four oxygen carriers in the in-situ redox jet attrition reactorXianyu Liu0Xin Wu1Daofeng Mei2Jinchen Ma3Haibo Zhao4State Key Laboratory of Coal Combustion, School of Energy and Power Engineering, Huazhong University of Science & Technology, Wuhan 430074, ChinaState Key Laboratory of Coal Combustion, School of Energy and Power Engineering, Huazhong University of Science & Technology, Wuhan 430074, ChinaInstituto de Carboquímica (ICB-CSIC), Miguel Luesma Castán, 4, 50018 Zaragoza, SpainState Key Laboratory of Coal Combustion, School of Energy and Power Engineering, Huazhong University of Science & Technology, Wuhan 430074, ChinaState Key Laboratory of Coal Combustion, School of Energy and Power Engineering, Huazhong University of Science & Technology, Wuhan 430074, China; Corresponding author.The anti-attrition properties of oxygen carriers (OCs) significantly impact the operation cost in chemical looping processes. A custom jet attrition reactor evaluates the attrition resistance of four OCs: ilmenite (Ilm-NO), CuFe bi-ore OC via hydroforming (CuFe-Hy), and two perovskites via spray drying and hydroforming (Per-SD and Per-Hy), through cold, hot, and redox attrition tests. The anti-attrition performance order across all tests is Ilm-NO > Per-Hy > CuFe-Hy > Per-SD. Post-testing characterizations are conducted, including particle size distributions of consumed particles and captured powders, structure properties, and compositional evolution. Oxygen carrier lifetimes are quantified based on the particle size distributions. Multiple stresses affecting oxygen carrier attrition exhibit antagonistic interactions rather than linear superposition. Element migration, particle expansion, and strength evolution of the tested oxygen carriers are observed. Particle density and crushing strength are highly related to the anti-attrition properties of oxygen carriers. This study develops an efficient method for evaluating OCs under the in-situ redox condition with a high-velocity jet, offering guidance for designing OCs with high attrition resistance and advancing the study of attrition mechanisms.http://www.sciencedirect.com/science/article/pii/S0378382025001237Chemical loopingJet attrition reactorOxygen carrierHydroformingSpray drying
spellingShingle Xianyu Liu
Xin Wu
Daofeng Mei
Jinchen Ma
Haibo Zhao
Attrition behavior analysis of four oxygen carriers in the in-situ redox jet attrition reactor
Fuel Processing Technology
Chemical looping
Jet attrition reactor
Oxygen carrier
Hydroforming
Spray drying
title Attrition behavior analysis of four oxygen carriers in the in-situ redox jet attrition reactor
title_full Attrition behavior analysis of four oxygen carriers in the in-situ redox jet attrition reactor
title_fullStr Attrition behavior analysis of four oxygen carriers in the in-situ redox jet attrition reactor
title_full_unstemmed Attrition behavior analysis of four oxygen carriers in the in-situ redox jet attrition reactor
title_short Attrition behavior analysis of four oxygen carriers in the in-situ redox jet attrition reactor
title_sort attrition behavior analysis of four oxygen carriers in the in situ redox jet attrition reactor
topic Chemical looping
Jet attrition reactor
Oxygen carrier
Hydroforming
Spray drying
url http://www.sciencedirect.com/science/article/pii/S0378382025001237
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AT xinwu attritionbehavioranalysisoffouroxygencarriersintheinsituredoxjetattritionreactor
AT daofengmei attritionbehavioranalysisoffouroxygencarriersintheinsituredoxjetattritionreactor
AT jinchenma attritionbehavioranalysisoffouroxygencarriersintheinsituredoxjetattritionreactor
AT haibozhao attritionbehavioranalysisoffouroxygencarriersintheinsituredoxjetattritionreactor