Effect of Nitrate Acid Treated Dolomite on the Tensile Properties of Ultra-High Molecular Weight Polyethylene (UHMWPE) Composites

Ultra-High Molecular Weight Polyethylene (UHMWPE) polymers have been used in biomedical applications due to its biocompatibility, durability, toughness and high wear resistance. To enhance the mechanical properties, various types of minerals are commonly utilized as fillers in UHMWPE. One of the min...

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Main Authors: S.F.A. Abdullah, S.S. Md Saleh, N.F Mohammad, S.N. Syed Mahamud, M.F. Omar, H.Md Akil, B.P Chang, H.R Saliu, N.H. Rostam, J. Gondro
Format: Article
Language:English
Published: Polish Academy of Sciences 2024-04-01
Series:Archives of Metallurgy and Materials
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Online Access:https://journals.pan.pl/Content/130948/PDF/AMM-2024-1-46-MD%20Saleh.pdf
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author S.F.A. Abdullah
S.S. Md Saleh
N.F Mohammad
S.N. Syed Mahamud
M.F. Omar
H.Md Akil
B.P Chang
H.R Saliu
N.H. Rostam
J. Gondro
author_facet S.F.A. Abdullah
S.S. Md Saleh
N.F Mohammad
S.N. Syed Mahamud
M.F. Omar
H.Md Akil
B.P Chang
H.R Saliu
N.H. Rostam
J. Gondro
author_sort S.F.A. Abdullah
collection DOAJ
description Ultra-High Molecular Weight Polyethylene (UHMWPE) polymers have been used in biomedical applications due to its biocompatibility, durability, toughness and high wear resistance. To enhance the mechanical properties, various types of minerals are commonly utilized as fillers in UHMWPE. One of the minerals is dolomite, which has been recognized as a valuable mineral with versatile applications, particularly in the field of biomedical applications. This paper presents the tensile properties of UHMWPE composites that filled with dolomite and treated-dolomite at various filler loading (i.e., 1-5 wt.%). Nitric acid and diammonium phosphate were used to treat the dolomite. From the results, the peaks of the FTIR spectrum displays carbonate (CO3–2), phosphate (PO4–3) and hydroxyl (OH–) groups in the ct-dolomite powder sample while the XRD pattern reveals that using dolomite treated with 1M nitric acid resulted in the presence of calcium hydroxide phosphate (Ca10(PO4)5(OH)) and MgO. For tensile strength, UHMWPE/ct-dolomite composites show better tensile strength than the pure UHMWPE composites. Treated improve the dolomite filler and resulted in significantly better matrix-filler interfacial interactions and improve the properties.
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spelling doaj-art-d9fbee7c065b420088a7d4f37fac4e0a2025-08-20T02:55:39ZengPolish Academy of SciencesArchives of Metallurgy and Materials2300-19092024-04-01vol. 69No 1281288https://doi.org/10.24425/amm.2024.147820Effect of Nitrate Acid Treated Dolomite on the Tensile Properties of Ultra-High Molecular Weight Polyethylene (UHMWPE) CompositesS.F.A. Abdullah0https://orcid.org/0009-0006-9327-5573S.S. Md Saleh1N.F Mohammadhttps://orcid.org/0000-0003-2188-4610S.N. Syed Mahamud2https://orcid.org/0000-0001-9919-2409M.F. Omar3https://orcid.org/0000-0002-6365-6272H.Md Akil4https://orcid.org/0000-0002-7422-4627B.P Changhttps://orcid.org/0000-0002-5765-9637H.R Saliuhttps://orcid.org/0000-0001-5151-0770N.H. Rostam5https://orcid.org/0009-0001-7991-5646J. Gondro6Universiti Malaysia Perlis, Faculty of Chemical Engineering & Technology, Kompleks Pusat Pengajian Jejawi 2, 02600 Arau, Perlis, Malaysia; University Malaysia Perlis, Biomedical and Nanotechnology Research Group, Center of Excellence Geopolymer and Green Technology (CEGeoTech), 01000 Kangar, Perlis, MalaysiaUniversiti Malaysia Perlis, Faculty of Chemical Engineering & Technology, Kompleks Pusat Pengajian Jejawi 2, 02600 Arau, Perlis, Malaysia; University Malaysia Perlis, Biomedical and Nanotechnology Research Group, Center of Excellence Geopolymer and Green Technology (CEGeoTech), 01000 Kangar, Perlis, MalaysiaUniversiti Malaysia Perlis, Faculty of Chemical Engineering & Technology, Kompleks Pusat Pengajian Jejawi 2, 02600 Arau, Perlis, Malaysia; University Malaysia Perlis, Biomedical and Nanotechnology Research Group, Center of Excellence Geopolymer and Green Technology (CEGeoTech), 01000 Kangar, Perlis, MalaysiaUniversiti Malaysia Perlis, Faculty of Chemical Engineering & Technology, Kompleks Pusat Pengajian Jejawi 2, 02600 Arau, Perlis, MalaysiaUniversiti Sains Malaysia, School of Materials and Mineral Resources Engineering, Engineering Campus, 14300 Nibong Tebal, Pulau Pinang, MalaysiaUniversiti Malaysia Perlis, Faculty of Chemical Engineering & Technology, Kompleks Pusat Pengajian Jejawi 2, 02600 Arau, Perlis, MalaysiaCzestochowa University of Technology, Faculty of Production Engineering and Materials Technology, Depa rtment of Physics, 19 Armii Krajowej Av., 42-200 Częstochowa, PolandompositesUltra-High Molecular Weight Polyethylene (UHMWPE) polymers have been used in biomedical applications due to its biocompatibility, durability, toughness and high wear resistance. To enhance the mechanical properties, various types of minerals are commonly utilized as fillers in UHMWPE. One of the minerals is dolomite, which has been recognized as a valuable mineral with versatile applications, particularly in the field of biomedical applications. This paper presents the tensile properties of UHMWPE composites that filled with dolomite and treated-dolomite at various filler loading (i.e., 1-5 wt.%). Nitric acid and diammonium phosphate were used to treat the dolomite. From the results, the peaks of the FTIR spectrum displays carbonate (CO3–2), phosphate (PO4–3) and hydroxyl (OH–) groups in the ct-dolomite powder sample while the XRD pattern reveals that using dolomite treated with 1M nitric acid resulted in the presence of calcium hydroxide phosphate (Ca10(PO4)5(OH)) and MgO. For tensile strength, UHMWPE/ct-dolomite composites show better tensile strength than the pure UHMWPE composites. Treated improve the dolomite filler and resulted in significantly better matrix-filler interfacial interactions and improve the properties.https://journals.pan.pl/Content/130948/PDF/AMM-2024-1-46-MD%20Saleh.pdfuhmwpechemical treatments of bamboodolomitepolymer compositesbiomedical
spellingShingle S.F.A. Abdullah
S.S. Md Saleh
N.F Mohammad
S.N. Syed Mahamud
M.F. Omar
H.Md Akil
B.P Chang
H.R Saliu
N.H. Rostam
J. Gondro
Effect of Nitrate Acid Treated Dolomite on the Tensile Properties of Ultra-High Molecular Weight Polyethylene (UHMWPE) Composites
Archives of Metallurgy and Materials
uhmwpe
chemical treatments of bamboo
dolomite
polymer composites
biomedical
title Effect of Nitrate Acid Treated Dolomite on the Tensile Properties of Ultra-High Molecular Weight Polyethylene (UHMWPE) Composites
title_full Effect of Nitrate Acid Treated Dolomite on the Tensile Properties of Ultra-High Molecular Weight Polyethylene (UHMWPE) Composites
title_fullStr Effect of Nitrate Acid Treated Dolomite on the Tensile Properties of Ultra-High Molecular Weight Polyethylene (UHMWPE) Composites
title_full_unstemmed Effect of Nitrate Acid Treated Dolomite on the Tensile Properties of Ultra-High Molecular Weight Polyethylene (UHMWPE) Composites
title_short Effect of Nitrate Acid Treated Dolomite on the Tensile Properties of Ultra-High Molecular Weight Polyethylene (UHMWPE) Composites
title_sort effect of nitrate acid treated dolomite on the tensile properties of ultra high molecular weight polyethylene uhmwpe composites
topic uhmwpe
chemical treatments of bamboo
dolomite
polymer composites
biomedical
url https://journals.pan.pl/Content/130948/PDF/AMM-2024-1-46-MD%20Saleh.pdf
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