Advancing NASICON-type materials through high-entropy strategy: Synthesis and applications
High-entropy materials (HEMs) have emerged as promising frontiers in electrochemical energy storage systems because of their unique compositional versatility and tunable physicochemical properties. By incorporating multiple principal elements with distinct chemical functionalities, HEMs exhibit tail...
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| Format: | Article |
| Language: | English |
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Tsinghua University Press
2025-05-01
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| Series: | Journal of Advanced Ceramics |
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| Online Access: | https://www.sciopen.com/article/10.26599/JAC.2025.9221079 |
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| author | Youmei Li Ming Zhang Jintian Wu Zixuan Fang Ziqiang Xu Mengqiang Wu |
| author_facet | Youmei Li Ming Zhang Jintian Wu Zixuan Fang Ziqiang Xu Mengqiang Wu |
| author_sort | Youmei Li |
| collection | DOAJ |
| description | High-entropy materials (HEMs) have emerged as promising frontiers in electrochemical energy storage systems because of their unique compositional versatility and tunable physicochemical properties. By incorporating multiple principal elements with distinct chemical functionalities, HEMs exhibit tailored electronic/ionic configurations, enabling unprecedented structural adaptability and application potential. This review systematically analyzes the fundamental principles underpinning the entropy-driven optimization of the electrochemical performance of battery materials, with a focus on the interplay between compositional disorder and functional enhancements. For the first time, we comprehensively review recent advances in Na superionic conductor (NASICON)-type HEMs spanning cathodes, solid-state electrolytes, and anodes. Through investigations, the profound impacts of high-entropy strategies on critical material parameters, including lattice strain modulation, interfacial stability reinforcement, charge-transfer kinetics optimization, and ion transport pathway regulation, were elucidated. Furthermore, we evaluate the current challenges in high-entropy NASICON-type battery design and propose actionable strategies for advancing next-generation high-entropy battery systems, emphasizing rational compositional screening, entropy-stabilized interface design, and machine learning-assisted property prediction. |
| format | Article |
| id | doaj-art-d94e0253797a47398e342ef49ba5429c |
| institution | Kabale University |
| issn | 2226-4108 2227-8508 |
| language | English |
| publishDate | 2025-05-01 |
| publisher | Tsinghua University Press |
| record_format | Article |
| series | Journal of Advanced Ceramics |
| spelling | doaj-art-d94e0253797a47398e342ef49ba5429c2025-08-20T03:29:31ZengTsinghua University PressJournal of Advanced Ceramics2226-41082227-85082025-05-01145922107910.26599/JAC.2025.9221079Advancing NASICON-type materials through high-entropy strategy: Synthesis and applicationsYoumei Li0Ming Zhang1Jintian Wu2Zixuan Fang3Ziqiang Xu4Mengqiang Wu5School of Materials and Energy, University of Electronic Science and Technology of China, Chengdu 611731, ChinaSchool of Materials and Energy, University of Electronic Science and Technology of China, Chengdu 611731, ChinaSchool of Chemistry and Engineering, Sichuan University of Science and Engineering, Zigong 643000, ChinaSchool of Materials and Energy, University of Electronic Science and Technology of China, Chengdu 611731, ChinaSchool of Materials and Energy, University of Electronic Science and Technology of China, Chengdu 611731, ChinaSchool of Materials and Energy, University of Electronic Science and Technology of China, Chengdu 611731, ChinaHigh-entropy materials (HEMs) have emerged as promising frontiers in electrochemical energy storage systems because of their unique compositional versatility and tunable physicochemical properties. By incorporating multiple principal elements with distinct chemical functionalities, HEMs exhibit tailored electronic/ionic configurations, enabling unprecedented structural adaptability and application potential. This review systematically analyzes the fundamental principles underpinning the entropy-driven optimization of the electrochemical performance of battery materials, with a focus on the interplay between compositional disorder and functional enhancements. For the first time, we comprehensively review recent advances in Na superionic conductor (NASICON)-type HEMs spanning cathodes, solid-state electrolytes, and anodes. Through investigations, the profound impacts of high-entropy strategies on critical material parameters, including lattice strain modulation, interfacial stability reinforcement, charge-transfer kinetics optimization, and ion transport pathway regulation, were elucidated. Furthermore, we evaluate the current challenges in high-entropy NASICON-type battery design and propose actionable strategies for advancing next-generation high-entropy battery systems, emphasizing rational compositional screening, entropy-stabilized interface design, and machine learning-assisted property prediction.https://www.sciopen.com/article/10.26599/JAC.2025.9221079na superionic conductor (nasicon) materialshigh-entropybattery designelectrochemical propertyinterface |
| spellingShingle | Youmei Li Ming Zhang Jintian Wu Zixuan Fang Ziqiang Xu Mengqiang Wu Advancing NASICON-type materials through high-entropy strategy: Synthesis and applications Journal of Advanced Ceramics na superionic conductor (nasicon) materials high-entropy battery design electrochemical property interface |
| title | Advancing NASICON-type materials through high-entropy strategy: Synthesis and applications |
| title_full | Advancing NASICON-type materials through high-entropy strategy: Synthesis and applications |
| title_fullStr | Advancing NASICON-type materials through high-entropy strategy: Synthesis and applications |
| title_full_unstemmed | Advancing NASICON-type materials through high-entropy strategy: Synthesis and applications |
| title_short | Advancing NASICON-type materials through high-entropy strategy: Synthesis and applications |
| title_sort | advancing nasicon type materials through high entropy strategy synthesis and applications |
| topic | na superionic conductor (nasicon) materials high-entropy battery design electrochemical property interface |
| url | https://www.sciopen.com/article/10.26599/JAC.2025.9221079 |
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