Formulation and Evaluation of Licorice-Extract-Enhanced Chitosan, PVA, and Gelatin-Derived Hydrogels for Wound Dressing

Wound infections remain a significant clinical challenge, impeding healing and causing deterioration. Recently, multifunctional hydrogel dressings have gained interest as an effective treatment to treat infections efficiently and enhance wound recovery. The present research is focused on the develop...

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Main Authors: Maria Mujahid, Muhammad Zubair, Asma Yaqoob, Sohail Shahzad, Aman Ullah
Format: Article
Language:English
Published: MDPI AG 2025-04-01
Series:Bioengineering
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Online Access:https://www.mdpi.com/2306-5354/12/5/439
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author Maria Mujahid
Muhammad Zubair
Asma Yaqoob
Sohail Shahzad
Aman Ullah
author_facet Maria Mujahid
Muhammad Zubair
Asma Yaqoob
Sohail Shahzad
Aman Ullah
author_sort Maria Mujahid
collection DOAJ
description Wound infections remain a significant clinical challenge, impeding healing and causing deterioration. Recently, multifunctional hydrogel dressings have gained interest as an effective treatment to treat infections efficiently and enhance wound recovery. The present research is focused on the development of composite hydrogels comprising chitosan (CS), polyvinyl alcohol (PVA), gelatin (GEL) and licorice extract (LE), using the freeze gelation technique. The resulting composite hydrogels of CS/PVA/GEL incorporating LE were characterized by FTIR, XRD and SEM. FTIR analysis confirmed the presence of specific functional groups within the molecules. XRD exhibited the amorphous nature of hydrogels. SEM analysis revealed that increasing the CS ratio in hydrogels created a more porous structure with a smaller pore size. All the hydrogels demonstrated oxygen permeability, which is crucial for the healing process. Among the synthesized hydrogels, MM-2 containing PVA (20 mL) and LE (4 mL) demonstrated superior performance with a water retention capacity of 440% and moisture content of 91%. This exceptional result can be attributed to the higher proportion of PVA and the material’s porous structure, which enhances its hydrophilic properties. The synthesized hydrogels showed good antibacterial potential against three selected strains of bacteria including <i>Bacillus subtilis</i> (<i>B. subtilis</i>), <i>Staphylococcus aureus</i> (<i>S. aureus</i>) and <i>Escherichia coli</i> (<i>E. coli</i>). The hydrogels’ cytotoxicity levels were assessed through hemolysis assay and the results demonstrated that all hydrogels were non-toxic. The hydrolytic breakdown revealed that the interconnected hydrogels with licorice components exhibited slow degradation, making them more appropriate for long-term wound treatment. Specifically, MM-4 demonstrated a 74% degradation rate and displayed 75% antioxidant activity, indicating its potential effectiveness for chronic wound applications. These characteristics of synthesized CS/PVA/GEL/LE-derived hydrogels suggest their potential use as a promising candidate for wound care applications.
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spelling doaj-art-d9460bea5e8747dd970fa5fe4a507bb72025-08-20T03:47:48ZengMDPI AGBioengineering2306-53542025-04-0112543910.3390/bioengineering12050439Formulation and Evaluation of Licorice-Extract-Enhanced Chitosan, PVA, and Gelatin-Derived Hydrogels for Wound DressingMaria Mujahid0Muhammad Zubair1Asma Yaqoob2Sohail Shahzad3Aman Ullah4Department of Chemistry, University of Sahiwal, Sahiwal 57000, PakistanLipid Chemistry Utilization Lab, Department of Agricultural, Food & Nutritional Science, University of Albert, Edmonton, AB T6G 2P5, CanadaInstitute of Biochemistry, Biotechnology and Bioinformatics, The Islamia University of Bahawalpur, Rabia Hall Rd, Bahawalpur 63100, PakistanDepartment of Chemistry, University of Sahiwal, Sahiwal 57000, PakistanLipid Chemistry Utilization Lab, Department of Agricultural, Food & Nutritional Science, University of Albert, Edmonton, AB T6G 2P5, CanadaWound infections remain a significant clinical challenge, impeding healing and causing deterioration. Recently, multifunctional hydrogel dressings have gained interest as an effective treatment to treat infections efficiently and enhance wound recovery. The present research is focused on the development of composite hydrogels comprising chitosan (CS), polyvinyl alcohol (PVA), gelatin (GEL) and licorice extract (LE), using the freeze gelation technique. The resulting composite hydrogels of CS/PVA/GEL incorporating LE were characterized by FTIR, XRD and SEM. FTIR analysis confirmed the presence of specific functional groups within the molecules. XRD exhibited the amorphous nature of hydrogels. SEM analysis revealed that increasing the CS ratio in hydrogels created a more porous structure with a smaller pore size. All the hydrogels demonstrated oxygen permeability, which is crucial for the healing process. Among the synthesized hydrogels, MM-2 containing PVA (20 mL) and LE (4 mL) demonstrated superior performance with a water retention capacity of 440% and moisture content of 91%. This exceptional result can be attributed to the higher proportion of PVA and the material’s porous structure, which enhances its hydrophilic properties. The synthesized hydrogels showed good antibacterial potential against three selected strains of bacteria including <i>Bacillus subtilis</i> (<i>B. subtilis</i>), <i>Staphylococcus aureus</i> (<i>S. aureus</i>) and <i>Escherichia coli</i> (<i>E. coli</i>). The hydrogels’ cytotoxicity levels were assessed through hemolysis assay and the results demonstrated that all hydrogels were non-toxic. The hydrolytic breakdown revealed that the interconnected hydrogels with licorice components exhibited slow degradation, making them more appropriate for long-term wound treatment. Specifically, MM-4 demonstrated a 74% degradation rate and displayed 75% antioxidant activity, indicating its potential effectiveness for chronic wound applications. These characteristics of synthesized CS/PVA/GEL/LE-derived hydrogels suggest their potential use as a promising candidate for wound care applications.https://www.mdpi.com/2306-5354/12/5/439chitosanPVAfreeze gelationgelatinwound dressingantibacterial
spellingShingle Maria Mujahid
Muhammad Zubair
Asma Yaqoob
Sohail Shahzad
Aman Ullah
Formulation and Evaluation of Licorice-Extract-Enhanced Chitosan, PVA, and Gelatin-Derived Hydrogels for Wound Dressing
Bioengineering
chitosan
PVA
freeze gelation
gelatin
wound dressing
antibacterial
title Formulation and Evaluation of Licorice-Extract-Enhanced Chitosan, PVA, and Gelatin-Derived Hydrogels for Wound Dressing
title_full Formulation and Evaluation of Licorice-Extract-Enhanced Chitosan, PVA, and Gelatin-Derived Hydrogels for Wound Dressing
title_fullStr Formulation and Evaluation of Licorice-Extract-Enhanced Chitosan, PVA, and Gelatin-Derived Hydrogels for Wound Dressing
title_full_unstemmed Formulation and Evaluation of Licorice-Extract-Enhanced Chitosan, PVA, and Gelatin-Derived Hydrogels for Wound Dressing
title_short Formulation and Evaluation of Licorice-Extract-Enhanced Chitosan, PVA, and Gelatin-Derived Hydrogels for Wound Dressing
title_sort formulation and evaluation of licorice extract enhanced chitosan pva and gelatin derived hydrogels for wound dressing
topic chitosan
PVA
freeze gelation
gelatin
wound dressing
antibacterial
url https://www.mdpi.com/2306-5354/12/5/439
work_keys_str_mv AT mariamujahid formulationandevaluationoflicoriceextractenhancedchitosanpvaandgelatinderivedhydrogelsforwounddressing
AT muhammadzubair formulationandevaluationoflicoriceextractenhancedchitosanpvaandgelatinderivedhydrogelsforwounddressing
AT asmayaqoob formulationandevaluationoflicoriceextractenhancedchitosanpvaandgelatinderivedhydrogelsforwounddressing
AT sohailshahzad formulationandevaluationoflicoriceextractenhancedchitosanpvaandgelatinderivedhydrogelsforwounddressing
AT amanullah formulationandevaluationoflicoriceextractenhancedchitosanpvaandgelatinderivedhydrogelsforwounddressing