Design, Synthesis and Structural Study of a <i>Bis</i>thiosemicarbazone Ligand Precursor of Metallosupramolecular Architectures
The increase in the investigation of different self-assembled architectures derived from thiosemicarbazone ligands can be attributed to the numerous functional metallosupramolecular architectures with practical applications that can be obtained. The potentially tetradentate organic <i>bis</...
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MDPI AG
2023-11-01
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| Series: | Chemistry Proceedings |
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| author | Uxía Barreiro-Sisto Isabel Velo-Heleno Miguel Martínez-Calvo Marcelino Maneiro Sandra Fernández-Fariña |
| author_facet | Uxía Barreiro-Sisto Isabel Velo-Heleno Miguel Martínez-Calvo Marcelino Maneiro Sandra Fernández-Fariña |
| author_sort | Uxía Barreiro-Sisto |
| collection | DOAJ |
| description | The increase in the investigation of different self-assembled architectures derived from thiosemicarbazone ligands can be attributed to the numerous functional metallosupramolecular architectures with practical applications that can be obtained. The potentially tetradentate organic <i>bis</i>thiosemicarbazone ligand H<sub>2</sub>L possesses two flexible bidentate [NS] domains separated by a short and rigid spacer, which could stabilize several metal ions and thus different metallosupramolecular architectures. H<sub>2</sub>L was prepared by the reaction between two equivalents of N-ethylhydrazinecarbothioamide and one equivalent of 1,1′,1″-(benzene-1,3,5-triyl)tris(ethan-1-one) and was fully studied using several techniques, including X-ray diffraction. |
| format | Article |
| id | doaj-art-d8a8cb8a23964cdd9f61382b952ad82e |
| institution | OA Journals |
| issn | 2673-4583 |
| language | English |
| publishDate | 2023-11-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Chemistry Proceedings |
| spelling | doaj-art-d8a8cb8a23964cdd9f61382b952ad82e2025-08-20T02:00:29ZengMDPI AGChemistry Proceedings2673-45832023-11-01141310.3390/ecsoc-27-16087Design, Synthesis and Structural Study of a <i>Bis</i>thiosemicarbazone Ligand Precursor of Metallosupramolecular ArchitecturesUxía Barreiro-Sisto0Isabel Velo-Heleno1Miguel Martínez-Calvo2Marcelino Maneiro3Sandra Fernández-Fariña4Suprabioin Lab, Departamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, Campus Vida, 15782 Santiago de Compostela, SpainSuprabioin Lab, Departamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, Campus Vida, 15782 Santiago de Compostela, SpainSuprabioin Lab, Departamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, Campus Vida, 15782 Santiago de Compostela, SpainSuprabioin Lab, Departamento de Química Inorgánica, Facultade de Ciencias, Universidade de Santiago de Compostela, Campus Terra, 27002 Lugo, SpainSuprabioin Lab, Departamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, Campus Vida, 15782 Santiago de Compostela, SpainThe increase in the investigation of different self-assembled architectures derived from thiosemicarbazone ligands can be attributed to the numerous functional metallosupramolecular architectures with practical applications that can be obtained. The potentially tetradentate organic <i>bis</i>thiosemicarbazone ligand H<sub>2</sub>L possesses two flexible bidentate [NS] domains separated by a short and rigid spacer, which could stabilize several metal ions and thus different metallosupramolecular architectures. H<sub>2</sub>L was prepared by the reaction between two equivalents of N-ethylhydrazinecarbothioamide and one equivalent of 1,1′,1″-(benzene-1,3,5-triyl)tris(ethan-1-one) and was fully studied using several techniques, including X-ray diffraction.https://www.mdpi.com/2673-4583/14/1/3<i>bis</i>thiosemicarbazoneligandmetallosupramolecular architectures |
| spellingShingle | Uxía Barreiro-Sisto Isabel Velo-Heleno Miguel Martínez-Calvo Marcelino Maneiro Sandra Fernández-Fariña Design, Synthesis and Structural Study of a <i>Bis</i>thiosemicarbazone Ligand Precursor of Metallosupramolecular Architectures Chemistry Proceedings <i>bis</i>thiosemicarbazone ligand metallosupramolecular architectures |
| title | Design, Synthesis and Structural Study of a <i>Bis</i>thiosemicarbazone Ligand Precursor of Metallosupramolecular Architectures |
| title_full | Design, Synthesis and Structural Study of a <i>Bis</i>thiosemicarbazone Ligand Precursor of Metallosupramolecular Architectures |
| title_fullStr | Design, Synthesis and Structural Study of a <i>Bis</i>thiosemicarbazone Ligand Precursor of Metallosupramolecular Architectures |
| title_full_unstemmed | Design, Synthesis and Structural Study of a <i>Bis</i>thiosemicarbazone Ligand Precursor of Metallosupramolecular Architectures |
| title_short | Design, Synthesis and Structural Study of a <i>Bis</i>thiosemicarbazone Ligand Precursor of Metallosupramolecular Architectures |
| title_sort | design synthesis and structural study of a i bis i thiosemicarbazone ligand precursor of metallosupramolecular architectures |
| topic | <i>bis</i>thiosemicarbazone ligand metallosupramolecular architectures |
| url | https://www.mdpi.com/2673-4583/14/1/3 |
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