Universal Expressions for the Polarization and the Depolarization Factor in Homogeneous Dielectric and Magnetic Spheres Subjected to an External Field of <i>Any</i> Form

Spherical structures of dielectric and magnetic materials are studied intensively in basic research and employed widely in applications. The polarization, (<b>P</b> for dielectric and <b>M</b> for magnetic materials), is the parent physical vector of all relevant entities (e....

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Main Author: Dimosthenis Stamopoulos
Format: Article
Language:English
Published: MDPI AG 2025-03-01
Series:Crystals
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Online Access:https://www.mdpi.com/2073-4352/15/4/331
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author Dimosthenis Stamopoulos
author_facet Dimosthenis Stamopoulos
author_sort Dimosthenis Stamopoulos
collection DOAJ
description Spherical structures of dielectric and magnetic materials are studied intensively in basic research and employed widely in applications. The polarization, (<b>P</b> for dielectric and <b>M</b> for magnetic materials), is the parent physical vector of all relevant entities (e.g., moment, , and force, <b>F</b>), which determine the signals recorded by an experimental setup or diagnostic equipment and configure the motion in real space. Here, we use classical electromagnetism to study the polarization, , of spherical structures of linear and isotropic—however, not necessarily homogeneous—materials subjected to an external vector field, (<b>E</b><sub>ext</sub> for dielectric and <b>H</b><sub>ext</sub> for magnetic materials), dc (static), or even ac of low frequency (quasistatic limit). We tackle an integro-differential equation on the polarization, , able to provide closed-form solutions, determined solely from , on the basis of spherical harmonics, <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msubsup><mrow><mi mathvariant="normal">Y</mi></mrow><mrow><mi>l</mi></mrow><mrow><mi>m</mi></mrow></msubsup></mrow></semantics></math></inline-formula>. These generic equations can be used to calculate analytically the polarization, , directly from an external field, , of any form. The proof of concept is studied in homogeneous dielectric and magnetic spheres. Indeed, the polarization, , can be obtained by universal expressions, directly applicable for <i>any</i> form of the external field, . Notably, we obtain the relation between the extrinsic, , and intrinsic, , susceptibilities (<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msubsup><mrow><mo>χ</mo></mrow><mrow><mi mathvariant="normal">e</mi></mrow><mrow><mi mathvariant="normal">e</mi><mi mathvariant="normal">x</mi><mi mathvariant="normal">t</mi></mrow></msubsup></mrow></semantics></math></inline-formula> and <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msubsup><mrow><mo>χ</mo></mrow><mrow><mi mathvariant="normal">e</mi></mrow><mrow><mi mathvariant="normal">i</mi><mi mathvariant="normal">n</mi><mi mathvariant="normal">t</mi></mrow></msubsup></mrow></semantics></math></inline-formula> for dielectric and <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msubsup><mrow><mo>χ</mo></mrow><mrow><mi mathvariant="normal">m</mi></mrow><mrow><mi mathvariant="normal">e</mi><mi mathvariant="normal">x</mi><mi mathvariant="normal">t</mi></mrow></msubsup></mrow></semantics></math></inline-formula> and <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msubsup><mrow><mo>χ</mo></mrow><mrow><mi mathvariant="normal">m</mi></mrow><mrow><mi mathvariant="normal">i</mi><mi mathvariant="normal">n</mi><mi mathvariant="normal">t</mi></mrow></msubsup></mrow></semantics></math></inline-formula> for magnetic materials) and clarify the nature of the depolarization factor, , which depends on the degree <i>l</i>—however, not on the order <i>m</i> of the mode <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><mo>(</mo><mi>l</mi><mo>,</mo><mi>m</mi><mo>)</mo></mrow></semantics></math></inline-formula> of the applied . Our universal approach can be useful to understand the physics and to facilitate applications of such spherical structures.
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spelling doaj-art-d8371f6409f94fbf894486e3678fb2a32025-08-20T03:13:54ZengMDPI AGCrystals2073-43522025-03-0115433110.3390/cryst15040331Universal Expressions for the Polarization and the Depolarization Factor in Homogeneous Dielectric and Magnetic Spheres Subjected to an External Field of <i>Any</i> FormDimosthenis Stamopoulos0Department of Physics, School of Science, National and Kapodistrian University of Athens, Zografou Panepistimioupolis, 15784 Athens, GreeceSpherical structures of dielectric and magnetic materials are studied intensively in basic research and employed widely in applications. The polarization, (<b>P</b> for dielectric and <b>M</b> for magnetic materials), is the parent physical vector of all relevant entities (e.g., moment, , and force, <b>F</b>), which determine the signals recorded by an experimental setup or diagnostic equipment and configure the motion in real space. Here, we use classical electromagnetism to study the polarization, , of spherical structures of linear and isotropic—however, not necessarily homogeneous—materials subjected to an external vector field, (<b>E</b><sub>ext</sub> for dielectric and <b>H</b><sub>ext</sub> for magnetic materials), dc (static), or even ac of low frequency (quasistatic limit). We tackle an integro-differential equation on the polarization, , able to provide closed-form solutions, determined solely from , on the basis of spherical harmonics, <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msubsup><mrow><mi mathvariant="normal">Y</mi></mrow><mrow><mi>l</mi></mrow><mrow><mi>m</mi></mrow></msubsup></mrow></semantics></math></inline-formula>. These generic equations can be used to calculate analytically the polarization, , directly from an external field, , of any form. The proof of concept is studied in homogeneous dielectric and magnetic spheres. Indeed, the polarization, , can be obtained by universal expressions, directly applicable for <i>any</i> form of the external field, . Notably, we obtain the relation between the extrinsic, , and intrinsic, , susceptibilities (<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msubsup><mrow><mo>χ</mo></mrow><mrow><mi mathvariant="normal">e</mi></mrow><mrow><mi mathvariant="normal">e</mi><mi mathvariant="normal">x</mi><mi mathvariant="normal">t</mi></mrow></msubsup></mrow></semantics></math></inline-formula> and <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msubsup><mrow><mo>χ</mo></mrow><mrow><mi mathvariant="normal">e</mi></mrow><mrow><mi mathvariant="normal">i</mi><mi mathvariant="normal">n</mi><mi mathvariant="normal">t</mi></mrow></msubsup></mrow></semantics></math></inline-formula> for dielectric and <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msubsup><mrow><mo>χ</mo></mrow><mrow><mi mathvariant="normal">m</mi></mrow><mrow><mi mathvariant="normal">e</mi><mi mathvariant="normal">x</mi><mi mathvariant="normal">t</mi></mrow></msubsup></mrow></semantics></math></inline-formula> and <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msubsup><mrow><mo>χ</mo></mrow><mrow><mi mathvariant="normal">m</mi></mrow><mrow><mi mathvariant="normal">i</mi><mi mathvariant="normal">n</mi><mi mathvariant="normal">t</mi></mrow></msubsup></mrow></semantics></math></inline-formula> for magnetic materials) and clarify the nature of the depolarization factor, , which depends on the degree <i>l</i>—however, not on the order <i>m</i> of the mode <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><mo>(</mo><mi>l</mi><mo>,</mo><mi>m</mi><mo>)</mo></mrow></semantics></math></inline-formula> of the applied . Our universal approach can be useful to understand the physics and to facilitate applications of such spherical structures.https://www.mdpi.com/2073-4352/15/4/331electric polarizationmagnetic polarizationdepolarization factordielectric spheresmagnetic spheresdepolarizing factor
spellingShingle Dimosthenis Stamopoulos
Universal Expressions for the Polarization and the Depolarization Factor in Homogeneous Dielectric and Magnetic Spheres Subjected to an External Field of <i>Any</i> Form
Crystals
electric polarization
magnetic polarization
depolarization factor
dielectric spheres
magnetic spheres
depolarizing factor
title Universal Expressions for the Polarization and the Depolarization Factor in Homogeneous Dielectric and Magnetic Spheres Subjected to an External Field of <i>Any</i> Form
title_full Universal Expressions for the Polarization and the Depolarization Factor in Homogeneous Dielectric and Magnetic Spheres Subjected to an External Field of <i>Any</i> Form
title_fullStr Universal Expressions for the Polarization and the Depolarization Factor in Homogeneous Dielectric and Magnetic Spheres Subjected to an External Field of <i>Any</i> Form
title_full_unstemmed Universal Expressions for the Polarization and the Depolarization Factor in Homogeneous Dielectric and Magnetic Spheres Subjected to an External Field of <i>Any</i> Form
title_short Universal Expressions for the Polarization and the Depolarization Factor in Homogeneous Dielectric and Magnetic Spheres Subjected to an External Field of <i>Any</i> Form
title_sort universal expressions for the polarization and the depolarization factor in homogeneous dielectric and magnetic spheres subjected to an external field of i any i form
topic electric polarization
magnetic polarization
depolarization factor
dielectric spheres
magnetic spheres
depolarizing factor
url https://www.mdpi.com/2073-4352/15/4/331
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