Atmospheric Brown Carbon: Sources, Optical Properties, and Chromophore Composition

Abstract Brown carbon (BrC) constitutes a significant portion of organic carbon (OC) and exerts a substantial influence on air quality, atmospheric chemical processes, and the impact on climate dynamics. The intricate chemistry of BrC arises from multiple mechanisms and source types, yielding a wide...

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Main Authors: Ashmeet Kaur Alang, Shankar G. Aggarwal
Format: Article
Language:English
Published: Springer 2024-05-01
Series:Aerosol and Air Quality Research
Subjects:
Online Access:https://doi.org/10.4209/aaqr.240035
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author Ashmeet Kaur Alang
Shankar G. Aggarwal
author_facet Ashmeet Kaur Alang
Shankar G. Aggarwal
author_sort Ashmeet Kaur Alang
collection DOAJ
description Abstract Brown carbon (BrC) constitutes a significant portion of organic carbon (OC) and exerts a substantial influence on air quality, atmospheric chemical processes, and the impact on climate dynamics. The intricate chemistry of BrC arises from multiple mechanisms and source types, yielding a wide spectrum of spectral properties. Consequently, identifying representative chromophore species to develop reference material is crucial to capture the full diversity of BrC found in the atmosphere and to ensure its precise determination. This also emphasizes the need for a more comprehensive measurement method to link BrC’s optical traits with its chemical composition. One of the objectives of this review is to evaluate the existing level of understanding concerning the molecular compositions of BrC compounds by analyzing recent field and laboratory data. This paper revises and expands a part of the prior database containing critical assessments of the primary and secondary sources, photochemistry of multi-phase chemical reactions involving BrC, potential candidate BrC chromophores, and recent studies on optical properties of BrC in the cryosphere, to draw lessons from recent advances that lead to improved BrC representation in the atmosphere.
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institution Kabale University
issn 1680-8584
2071-1409
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publishDate 2024-05-01
publisher Springer
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series Aerosol and Air Quality Research
spelling doaj-art-d80526ab33144df39399a0fce101c7602025-02-09T12:24:36ZengSpringerAerosol and Air Quality Research1680-85842071-14092024-05-0124912310.4209/aaqr.240035Atmospheric Brown Carbon: Sources, Optical Properties, and Chromophore CompositionAshmeet Kaur Alang0Shankar G. Aggarwal1Academy of Scientific and Innovative Research (AcSIR)Academy of Scientific and Innovative Research (AcSIR)Abstract Brown carbon (BrC) constitutes a significant portion of organic carbon (OC) and exerts a substantial influence on air quality, atmospheric chemical processes, and the impact on climate dynamics. The intricate chemistry of BrC arises from multiple mechanisms and source types, yielding a wide spectrum of spectral properties. Consequently, identifying representative chromophore species to develop reference material is crucial to capture the full diversity of BrC found in the atmosphere and to ensure its precise determination. This also emphasizes the need for a more comprehensive measurement method to link BrC’s optical traits with its chemical composition. One of the objectives of this review is to evaluate the existing level of understanding concerning the molecular compositions of BrC compounds by analyzing recent field and laboratory data. This paper revises and expands a part of the prior database containing critical assessments of the primary and secondary sources, photochemistry of multi-phase chemical reactions involving BrC, potential candidate BrC chromophores, and recent studies on optical properties of BrC in the cryosphere, to draw lessons from recent advances that lead to improved BrC representation in the atmosphere.https://doi.org/10.4209/aaqr.240035Brown carbon (BrC)Secondary formation processesOptical propertiesSourcesReference material
spellingShingle Ashmeet Kaur Alang
Shankar G. Aggarwal
Atmospheric Brown Carbon: Sources, Optical Properties, and Chromophore Composition
Aerosol and Air Quality Research
Brown carbon (BrC)
Secondary formation processes
Optical properties
Sources
Reference material
title Atmospheric Brown Carbon: Sources, Optical Properties, and Chromophore Composition
title_full Atmospheric Brown Carbon: Sources, Optical Properties, and Chromophore Composition
title_fullStr Atmospheric Brown Carbon: Sources, Optical Properties, and Chromophore Composition
title_full_unstemmed Atmospheric Brown Carbon: Sources, Optical Properties, and Chromophore Composition
title_short Atmospheric Brown Carbon: Sources, Optical Properties, and Chromophore Composition
title_sort atmospheric brown carbon sources optical properties and chromophore composition
topic Brown carbon (BrC)
Secondary formation processes
Optical properties
Sources
Reference material
url https://doi.org/10.4209/aaqr.240035
work_keys_str_mv AT ashmeetkauralang atmosphericbrowncarbonsourcesopticalpropertiesandchromophorecomposition
AT shankargaggarwal atmosphericbrowncarbonsourcesopticalpropertiesandchromophorecomposition