Investigating the Degradability of HDPE, LDPE, PE-BIO, and PE-OXO Films under UV-B Radiation

The changes in structural properties of high density polyethylene films (HDPE), low density polyethylene films (LDPE), biodegradable polyethylene (PE-BIO), and oxodegradable polyethylene (PE-OXO) films exposed to UV-B radiation were studied. The carbonyl (ICO) and vinyl (IV) index, the crystalline p...

Full description

Saved in:
Bibliographic Details
Main Authors: A. Martínez-Romo, R. González-Mota, J. J. Soto-Bernal, I. Rosales-Candelas
Format: Article
Language:English
Published: Wiley 2015-01-01
Series:Journal of Spectroscopy
Online Access:http://dx.doi.org/10.1155/2015/586514
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1849683418751696896
author A. Martínez-Romo
R. González-Mota
J. J. Soto-Bernal
I. Rosales-Candelas
author_facet A. Martínez-Romo
R. González-Mota
J. J. Soto-Bernal
I. Rosales-Candelas
author_sort A. Martínez-Romo
collection DOAJ
description The changes in structural properties of high density polyethylene films (HDPE), low density polyethylene films (LDPE), biodegradable polyethylene (PE-BIO), and oxodegradable polyethylene (PE-OXO) films exposed to UV-B radiation were studied. The carbonyl (ICO) and vinyl (IV) index, the crystalline phase fraction, and the dichroic ratio were used to evaluate the photooxidation of these polymers. The results obtained show that LDPE and HDPE undergo a major degree of oxidation and an increase in the crystalline phase fraction comparing to PE-BIO and PE-OXO. If the LDPE and HDPE are pretreated by an accurate radiation UV-B dosage before its different commercial uses or in its final disposition, they can become an option for biodegradable material without the necessity of adding organic agents or photosensitizers.
format Article
id doaj-art-d7d4eb93265a4fc1856a79ce1ec4b3d4
institution DOAJ
issn 2314-4920
2314-4939
language English
publishDate 2015-01-01
publisher Wiley
record_format Article
series Journal of Spectroscopy
spelling doaj-art-d7d4eb93265a4fc1856a79ce1ec4b3d42025-08-20T03:23:52ZengWileyJournal of Spectroscopy2314-49202314-49392015-01-01201510.1155/2015/586514586514Investigating the Degradability of HDPE, LDPE, PE-BIO, and PE-OXO Films under UV-B RadiationA. Martínez-Romo0R. González-Mota1J. J. Soto-Bernal2I. Rosales-Candelas3Instituto Tecnológico de Aguascalientes, Avenida Adolfo López Mateos No. 1801 Ote, Fraccionamiento Bona Gens, 20256 Aguascalientes, AGS, MexicoInstituto Tecnológico de Aguascalientes, Avenida Adolfo López Mateos No. 1801 Ote, Fraccionamiento Bona Gens, 20256 Aguascalientes, AGS, MexicoInstituto Tecnológico de Aguascalientes, Avenida Adolfo López Mateos No. 1801 Ote, Fraccionamiento Bona Gens, 20256 Aguascalientes, AGS, MexicoInstituto Tecnológico de Aguascalientes, Avenida Adolfo López Mateos No. 1801 Ote, Fraccionamiento Bona Gens, 20256 Aguascalientes, AGS, MexicoThe changes in structural properties of high density polyethylene films (HDPE), low density polyethylene films (LDPE), biodegradable polyethylene (PE-BIO), and oxodegradable polyethylene (PE-OXO) films exposed to UV-B radiation were studied. The carbonyl (ICO) and vinyl (IV) index, the crystalline phase fraction, and the dichroic ratio were used to evaluate the photooxidation of these polymers. The results obtained show that LDPE and HDPE undergo a major degree of oxidation and an increase in the crystalline phase fraction comparing to PE-BIO and PE-OXO. If the LDPE and HDPE are pretreated by an accurate radiation UV-B dosage before its different commercial uses or in its final disposition, they can become an option for biodegradable material without the necessity of adding organic agents or photosensitizers.http://dx.doi.org/10.1155/2015/586514
spellingShingle A. Martínez-Romo
R. González-Mota
J. J. Soto-Bernal
I. Rosales-Candelas
Investigating the Degradability of HDPE, LDPE, PE-BIO, and PE-OXO Films under UV-B Radiation
Journal of Spectroscopy
title Investigating the Degradability of HDPE, LDPE, PE-BIO, and PE-OXO Films under UV-B Radiation
title_full Investigating the Degradability of HDPE, LDPE, PE-BIO, and PE-OXO Films under UV-B Radiation
title_fullStr Investigating the Degradability of HDPE, LDPE, PE-BIO, and PE-OXO Films under UV-B Radiation
title_full_unstemmed Investigating the Degradability of HDPE, LDPE, PE-BIO, and PE-OXO Films under UV-B Radiation
title_short Investigating the Degradability of HDPE, LDPE, PE-BIO, and PE-OXO Films under UV-B Radiation
title_sort investigating the degradability of hdpe ldpe pe bio and pe oxo films under uv b radiation
url http://dx.doi.org/10.1155/2015/586514
work_keys_str_mv AT amartinezromo investigatingthedegradabilityofhdpeldpepebioandpeoxofilmsunderuvbradiation
AT rgonzalezmota investigatingthedegradabilityofhdpeldpepebioandpeoxofilmsunderuvbradiation
AT jjsotobernal investigatingthedegradabilityofhdpeldpepebioandpeoxofilmsunderuvbradiation
AT irosalescandelas investigatingthedegradabilityofhdpeldpepebioandpeoxofilmsunderuvbradiation