Influence of annealing temperature on the photocatalytic efficiency of sol-gel dip-coated ZnO thin films in methyl orange degradation

ZnO thin films on glass substrates and silicon wafers were prepared by the sol-gel dipcoating technique and annealed at temperatures ranging from 300 - 550 °C. X-ray diffraction (XRD) and Raman analysis confirm the hexagonal wurtzite structure of ZnO. Scanning electron microscopy (SEM) examination c...

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Main Authors: A.H. Haritha, M.E. Cruz, O. Sisman, A. Duran, D. Galusek, J.J. Velázquez, Y. Castro
Format: Article
Language:English
Published: Elsevier 2025-03-01
Series:Open Ceramics
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Online Access:http://www.sciencedirect.com/science/article/pii/S2666539524001913
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author A.H. Haritha
M.E. Cruz
O. Sisman
A. Duran
D. Galusek
J.J. Velázquez
Y. Castro
author_facet A.H. Haritha
M.E. Cruz
O. Sisman
A. Duran
D. Galusek
J.J. Velázquez
Y. Castro
author_sort A.H. Haritha
collection DOAJ
description ZnO thin films on glass substrates and silicon wafers were prepared by the sol-gel dipcoating technique and annealed at temperatures ranging from 300 - 550 °C. X-ray diffraction (XRD) and Raman analysis confirm the hexagonal wurtzite structure of ZnO. Scanning electron microscopy (SEM) examination confirmed that the films were homogeneous, crack-free and with a uniform distribution of nano-sized spherical grains. The decomposition of methyl orange (MO) using a solar simulator was used to determine the photocatalytic activity of the thin films. The annealing temperature was found to have a significant influence on the structure, morphology, and photocatalytic performance of ZnO thin films. The best photocatalytic activity under solar irradiation was shown by the ZnO thin film annealed at 450 °C. The enhanced photocatalytic performance of the films can be attributed to their optimized crystallinity, surface roughness and morphology, which provide more active sites for the photocatalytic reactions.
format Article
id doaj-art-d7d2ce3d4da74ac893e2cdd64a6a9545
institution OA Journals
issn 2666-5395
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publishDate 2025-03-01
publisher Elsevier
record_format Article
series Open Ceramics
spelling doaj-art-d7d2ce3d4da74ac893e2cdd64a6a95452025-08-20T02:07:20ZengElsevierOpen Ceramics2666-53952025-03-012110072710.1016/j.oceram.2024.100727Influence of annealing temperature on the photocatalytic efficiency of sol-gel dip-coated ZnO thin films in methyl orange degradationA.H. Haritha0M.E. Cruz1O. Sisman2A. Duran3D. Galusek4J.J. Velázquez5Y. Castro6FunGlass, Alexander Dubček University of Trenčín, Trenčín, Slovakia; Instituto de Cerámica y Vidrio (CSIC), Madrid, SpainInstituto de Cerámica y Vidrio (CSIC), Madrid, SpainFunGlass, Alexander Dubček University of Trenčín, Trenčín, SlovakiaInstituto de Cerámica y Vidrio (CSIC), Madrid, SpainFunGlass, Alexander Dubček University of Trenčín, Trenčín, Slovakia; Joint Glass Centre of the IIC SAS, TnUAD,nd FChPT STU, Trenčín, SlovakiaFunGlass, Alexander Dubček University of Trenčín, Trenčín, SlovakiaInstituto de Cerámica y Vidrio (CSIC), Madrid, Spain; Corresponding author.ZnO thin films on glass substrates and silicon wafers were prepared by the sol-gel dipcoating technique and annealed at temperatures ranging from 300 - 550 °C. X-ray diffraction (XRD) and Raman analysis confirm the hexagonal wurtzite structure of ZnO. Scanning electron microscopy (SEM) examination confirmed that the films were homogeneous, crack-free and with a uniform distribution of nano-sized spherical grains. The decomposition of methyl orange (MO) using a solar simulator was used to determine the photocatalytic activity of the thin films. The annealing temperature was found to have a significant influence on the structure, morphology, and photocatalytic performance of ZnO thin films. The best photocatalytic activity under solar irradiation was shown by the ZnO thin film annealed at 450 °C. The enhanced photocatalytic performance of the films can be attributed to their optimized crystallinity, surface roughness and morphology, which provide more active sites for the photocatalytic reactions.http://www.sciencedirect.com/science/article/pii/S2666539524001913Sol-gelZnOThin filmsPhotocatalyticMethyl orange
spellingShingle A.H. Haritha
M.E. Cruz
O. Sisman
A. Duran
D. Galusek
J.J. Velázquez
Y. Castro
Influence of annealing temperature on the photocatalytic efficiency of sol-gel dip-coated ZnO thin films in methyl orange degradation
Open Ceramics
Sol-gel
ZnO
Thin films
Photocatalytic
Methyl orange
title Influence of annealing temperature on the photocatalytic efficiency of sol-gel dip-coated ZnO thin films in methyl orange degradation
title_full Influence of annealing temperature on the photocatalytic efficiency of sol-gel dip-coated ZnO thin films in methyl orange degradation
title_fullStr Influence of annealing temperature on the photocatalytic efficiency of sol-gel dip-coated ZnO thin films in methyl orange degradation
title_full_unstemmed Influence of annealing temperature on the photocatalytic efficiency of sol-gel dip-coated ZnO thin films in methyl orange degradation
title_short Influence of annealing temperature on the photocatalytic efficiency of sol-gel dip-coated ZnO thin films in methyl orange degradation
title_sort influence of annealing temperature on the photocatalytic efficiency of sol gel dip coated zno thin films in methyl orange degradation
topic Sol-gel
ZnO
Thin films
Photocatalytic
Methyl orange
url http://www.sciencedirect.com/science/article/pii/S2666539524001913
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