Synthesis and properties of a novel waterborne photosensitive resin for 3D printing
A series of novel waterborne photosensitive resins were prepared successfully with poly(propylene oxide) bis(2-aminopropyl ether), tricyclodecane dimethanol diacrylate, 2-isocyanatoethyl acrylate, and hydrochloric acid by Michael addition reaction. The results show that with the increasing double bo...
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| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
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Budapest University of Technology and Economics
2023-01-01
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| Series: | eXPRESS Polymer Letters |
| Subjects: | |
| Online Access: | http://www.expresspolymlett.com/letolt.php?file=EPL-0012057&mi=cd |
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| _version_ | 1850058152771321856 |
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| author | Qinghong Luo Ting Zhang Ruijie Xu Hongping Xiang Yanyan Cui Zhiquan Li Xiaoxuan Liu |
| author_facet | Qinghong Luo Ting Zhang Ruijie Xu Hongping Xiang Yanyan Cui Zhiquan Li Xiaoxuan Liu |
| author_sort | Qinghong Luo |
| collection | DOAJ |
| description | A series of novel waterborne photosensitive resins were prepared successfully with poly(propylene oxide) bis(2-aminopropyl ether), tricyclodecane dimethanol diacrylate, 2-isocyanatoethyl acrylate, and hydrochloric acid by Michael addition reaction. The results show that with the increasing double bonds content, the double bonds conversion increases from 78.7, 85.6 to 92.8% in the photopolymerization, respectively, and the gel content of the UV-cured film increases from 48.05, 69.10 to 83.28%. In addition, the glass transition temperature and tensile strength of the UV-cured film follow the same increasing trend. Moreover, the content of hydrochloride has a great influence on the hydrophilicity of the waterborne photosensitive resins. The studies indicated that as the hydrochloride content decreases, the surface water contact angle of the UV-cured film increases from 10.8, 22.9 to 51.5°, and water absorption decreases from 26.55, 16.20 to 11.06%, respectively. Moreover, the waterborne photosensitive resins exhibited a high printing accuracy together with a good effect of washing and are promising for 3D printing. |
| format | Article |
| id | doaj-art-d7b8c694014a41e8b280436dbe2f886e |
| institution | DOAJ |
| issn | 1788-618X |
| language | English |
| publishDate | 2023-01-01 |
| publisher | Budapest University of Technology and Economics |
| record_format | Article |
| series | eXPRESS Polymer Letters |
| spelling | doaj-art-d7b8c694014a41e8b280436dbe2f886e2025-08-20T02:51:14ZengBudapest University of Technology and EconomicseXPRESS Polymer Letters1788-618X2023-01-01171405310.3144/expresspolymlett.2023.4Synthesis and properties of a novel waterborne photosensitive resin for 3D printingQinghong LuoTing ZhangRuijie XuHongping XiangYanyan CuiZhiquan LiXiaoxuan LiuA series of novel waterborne photosensitive resins were prepared successfully with poly(propylene oxide) bis(2-aminopropyl ether), tricyclodecane dimethanol diacrylate, 2-isocyanatoethyl acrylate, and hydrochloric acid by Michael addition reaction. The results show that with the increasing double bonds content, the double bonds conversion increases from 78.7, 85.6 to 92.8% in the photopolymerization, respectively, and the gel content of the UV-cured film increases from 48.05, 69.10 to 83.28%. In addition, the glass transition temperature and tensile strength of the UV-cured film follow the same increasing trend. Moreover, the content of hydrochloride has a great influence on the hydrophilicity of the waterborne photosensitive resins. The studies indicated that as the hydrochloride content decreases, the surface water contact angle of the UV-cured film increases from 10.8, 22.9 to 51.5°, and water absorption decreases from 26.55, 16.20 to 11.06%, respectively. Moreover, the waterborne photosensitive resins exhibited a high printing accuracy together with a good effect of washing and are promising for 3D printing.http://www.expresspolymlett.com/letolt.php?file=EPL-0012057&mi=cdpolymer synthesis, molecular engineeringwaterborne photosensitive resins3d printing |
| spellingShingle | Qinghong Luo Ting Zhang Ruijie Xu Hongping Xiang Yanyan Cui Zhiquan Li Xiaoxuan Liu Synthesis and properties of a novel waterborne photosensitive resin for 3D printing eXPRESS Polymer Letters polymer synthesis, molecular engineering waterborne photosensitive resins 3d printing |
| title | Synthesis and properties of a novel waterborne photosensitive resin for 3D printing |
| title_full | Synthesis and properties of a novel waterborne photosensitive resin for 3D printing |
| title_fullStr | Synthesis and properties of a novel waterborne photosensitive resin for 3D printing |
| title_full_unstemmed | Synthesis and properties of a novel waterborne photosensitive resin for 3D printing |
| title_short | Synthesis and properties of a novel waterborne photosensitive resin for 3D printing |
| title_sort | synthesis and properties of a novel waterborne photosensitive resin for 3d printing |
| topic | polymer synthesis, molecular engineering waterborne photosensitive resins 3d printing |
| url | http://www.expresspolymlett.com/letolt.php?file=EPL-0012057&mi=cd |
| work_keys_str_mv | AT qinghongluo synthesisandpropertiesofanovelwaterbornephotosensitiveresinfor3dprinting AT tingzhang synthesisandpropertiesofanovelwaterbornephotosensitiveresinfor3dprinting AT ruijiexu synthesisandpropertiesofanovelwaterbornephotosensitiveresinfor3dprinting AT hongpingxiang synthesisandpropertiesofanovelwaterbornephotosensitiveresinfor3dprinting AT yanyancui synthesisandpropertiesofanovelwaterbornephotosensitiveresinfor3dprinting AT zhiquanli synthesisandpropertiesofanovelwaterbornephotosensitiveresinfor3dprinting AT xiaoxuanliu synthesisandpropertiesofanovelwaterbornephotosensitiveresinfor3dprinting |