Effect of magnetic field on precipitation kinetics and shear strength of Sn58Bi-Ni solders

Magnetic-field-assisted soldering offered a promising approach for achieving high-reliability interconnects in space applications. In this study, Sn58Bi solder and its composites doped with 0.6 wt% Ni nanoparticles (NPs) or microparticles (MPs) were investigated to elucidate the effects of magnetic...

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Main Authors: Chuan-jiang Wu, Liang Zhang, Yu-hao Chen, Xin-quan Yu, Quan-Bin Lu, Wei-min Long
Format: Article
Language:English
Published: Elsevier 2025-07-01
Series:Materials & Design
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Online Access:http://www.sciencedirect.com/science/article/pii/S0264127525005787
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author Chuan-jiang Wu
Liang Zhang
Yu-hao Chen
Xin-quan Yu
Quan-Bin Lu
Wei-min Long
author_facet Chuan-jiang Wu
Liang Zhang
Yu-hao Chen
Xin-quan Yu
Quan-Bin Lu
Wei-min Long
author_sort Chuan-jiang Wu
collection DOAJ
description Magnetic-field-assisted soldering offered a promising approach for achieving high-reliability interconnects in space applications. In this study, Sn58Bi solder and its composites doped with 0.6 wt% Ni nanoparticles (NPs) or microparticles (MPs) were investigated to elucidate the effects of magnetic fields on the behavior of magnetic solders, with particular focus on microstructural evolution, grain orientation, and mechanical performance. The classical lamellar eutectic structure was transformed into a honeycomb-like morphology under the applied magnetic field, accompanied by an increased dislocation density. Meanwhile, the magnetic field suppressed Ni particle agglomeration and promoted the precipitation of fine (Cu, Ni)6Sn5 grains between the Sn and Bi phases, which produced a pinning effect. It also inhibited intermetallic compounds (IMC) layer growth, refined the IMC grains, and preserved their orientation. Consequently, the shear strength of joints soldered under the magnetic field increased by approximately 30 %. For the first time, first-principles calculations revealed how the synergistic effect of magnetic Ni doping and magnetic field application improved the mechanical and electronic properties of (Cu, Ni)6Sn5 IMC. These findings provided essential insights into the microstructural evolution of Sn-based magnetic solders under magnetic fields and contributed to the development of magnetic field-assisted soldering and the design of magnetic solder materials.
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series Materials & Design
spelling doaj-art-d78f75e3570a46d98e5802e04e9767012025-08-20T03:22:04ZengElsevierMaterials & Design0264-12752025-07-0125511415810.1016/j.matdes.2025.114158Effect of magnetic field on precipitation kinetics and shear strength of Sn58Bi-Ni soldersChuan-jiang Wu0Liang Zhang1Yu-hao Chen2Xin-quan Yu3Quan-Bin Lu4Wei-min Long5School of Materials Science and Engineering, Xiamen University of Technology, Xiamen 361000, ChinaSchool of Materials Science and Engineering, Xiamen University of Technology, Xiamen 361000, China; State Key Laboratory of Advanced Brazing Filler Metals & Technology, Zhengzhou Research Institute of Mechanical Engineering, Zhengzhou 450001, China; Corresponding authors.School of Materials Science and Engineering, Xiamen University of Technology, Xiamen 361000, ChinaState Key Laboratory of Advanced Brazing Filler Metals & Technology, Zhengzhou Research Institute of Mechanical Engineering, Zhengzhou 450001, ChinaState Key Laboratory of Advanced Brazing Filler Metals & Technology, Zhengzhou Research Institute of Mechanical Engineering, Zhengzhou 450001, ChinaState Key Laboratory of Advanced Brazing Filler Metals & Technology, Zhengzhou Research Institute of Mechanical Engineering, Zhengzhou 450001, China; Corresponding authors.Magnetic-field-assisted soldering offered a promising approach for achieving high-reliability interconnects in space applications. In this study, Sn58Bi solder and its composites doped with 0.6 wt% Ni nanoparticles (NPs) or microparticles (MPs) were investigated to elucidate the effects of magnetic fields on the behavior of magnetic solders, with particular focus on microstructural evolution, grain orientation, and mechanical performance. The classical lamellar eutectic structure was transformed into a honeycomb-like morphology under the applied magnetic field, accompanied by an increased dislocation density. Meanwhile, the magnetic field suppressed Ni particle agglomeration and promoted the precipitation of fine (Cu, Ni)6Sn5 grains between the Sn and Bi phases, which produced a pinning effect. It also inhibited intermetallic compounds (IMC) layer growth, refined the IMC grains, and preserved their orientation. Consequently, the shear strength of joints soldered under the magnetic field increased by approximately 30 %. For the first time, first-principles calculations revealed how the synergistic effect of magnetic Ni doping and magnetic field application improved the mechanical and electronic properties of (Cu, Ni)6Sn5 IMC. These findings provided essential insights into the microstructural evolution of Sn-based magnetic solders under magnetic fields and contributed to the development of magnetic field-assisted soldering and the design of magnetic solder materials.http://www.sciencedirect.com/science/article/pii/S0264127525005787Magnetic solderMagnetic fieldPrecipitationFirst-principles
spellingShingle Chuan-jiang Wu
Liang Zhang
Yu-hao Chen
Xin-quan Yu
Quan-Bin Lu
Wei-min Long
Effect of magnetic field on precipitation kinetics and shear strength of Sn58Bi-Ni solders
Materials & Design
Magnetic solder
Magnetic field
Precipitation
First-principles
title Effect of magnetic field on precipitation kinetics and shear strength of Sn58Bi-Ni solders
title_full Effect of magnetic field on precipitation kinetics and shear strength of Sn58Bi-Ni solders
title_fullStr Effect of magnetic field on precipitation kinetics and shear strength of Sn58Bi-Ni solders
title_full_unstemmed Effect of magnetic field on precipitation kinetics and shear strength of Sn58Bi-Ni solders
title_short Effect of magnetic field on precipitation kinetics and shear strength of Sn58Bi-Ni solders
title_sort effect of magnetic field on precipitation kinetics and shear strength of sn58bi ni solders
topic Magnetic solder
Magnetic field
Precipitation
First-principles
url http://www.sciencedirect.com/science/article/pii/S0264127525005787
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AT quanbinlu effectofmagneticfieldonprecipitationkineticsandshearstrengthofsn58binisolders
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