Nitrogen-vacancy centers in epitaxial laterally overgrown diamond: towards up-scaling of color center-based quantum technologies

Providing high-quality, single-crystal diamond (SCD) with a large area is desirable for up-scaling quantum technology applications that rely on color centers in diamond. Growth methods aiming to increase the area of SCD are an active research area. Native color centers offer a sensitive probe for lo...

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Main Authors: Nimba Oshnik, Sebastian Westrich, Nina Burmeister, Oliver Roman Opaluch, Lahcene Mehmel, Riadh Issaoui, Alexandre Tallaire, Ovidiu Brinza, Jocelyn Achard, Elke Neu
Format: Article
Language:English
Published: IOP Publishing 2025-01-01
Series:Materials for Quantum Technology
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Online Access:https://doi.org/10.1088/2633-4356/adce50
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author Nimba Oshnik
Sebastian Westrich
Nina Burmeister
Oliver Roman Opaluch
Lahcene Mehmel
Riadh Issaoui
Alexandre Tallaire
Ovidiu Brinza
Jocelyn Achard
Elke Neu
author_facet Nimba Oshnik
Sebastian Westrich
Nina Burmeister
Oliver Roman Opaluch
Lahcene Mehmel
Riadh Issaoui
Alexandre Tallaire
Ovidiu Brinza
Jocelyn Achard
Elke Neu
author_sort Nimba Oshnik
collection DOAJ
description Providing high-quality, single-crystal diamond (SCD) with a large area is desirable for up-scaling quantum technology applications that rely on color centers in diamond. Growth methods aiming to increase the area of SCD are an active research area. Native color centers offer a sensitive probe for local crystal quality in such novel materials e.g. via their reaction to stress. In this work, we investigate individual native nitrogen-vacancy (NV) centers in SCD layers manufactured via laterally overgrowing hole arrays in a heteroepitaxially grown large-scale substrate. Heteroepitaxy has become a common tool for growing large SCDs; however, achieving the high crystal quality needed for quantum applications remains a challenge. In the overgrown layer, we identify NV centers with spin-decoherence times in the order of hundreds of µ s, comparable to high-purity homoepitaxial SCD. We quantify the effective crystal stress in different regions of the overgrown layer, indicating a low stress overall and a stress reduction in the diamond layer above the holes.
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series Materials for Quantum Technology
spelling doaj-art-d6eb8b64b08e40fc83ea51c42a81d9312025-08-20T02:18:28ZengIOP PublishingMaterials for Quantum Technology2633-43562025-01-015202520110.1088/2633-4356/adce50Nitrogen-vacancy centers in epitaxial laterally overgrown diamond: towards up-scaling of color center-based quantum technologiesNimba Oshnik0https://orcid.org/0009-0008-6495-8951Sebastian Westrich1Nina Burmeister2https://orcid.org/0009-0007-8638-8649Oliver Roman Opaluch3Lahcene Mehmel4https://orcid.org/0000-0001-5791-168XRiadh Issaoui5Alexandre Tallaire6Ovidiu Brinza7Jocelyn Achard8https://orcid.org/0000-0001-7000-7230Elke Neu9https://orcid.org/0000-0003-1904-3206Department of Physics and Research Center OPTIMAS , Rheinland-Pfälzische Technische Universität Kaiserslautern-Landau, 67663 Kaiserslautern, Germany; Institute for Quantum Control (PGI-8) , Forschungszentrum Jülich, 52428 Jülich, Germany; Institute for Quantum Computation and Analytics (PGI-12) , Forschungszentrum Jülich, 52428 Jülich, GermanyDepartment of Physics and Research Center OPTIMAS , Rheinland-Pfälzische Technische Universität Kaiserslautern-Landau, 67663 Kaiserslautern, GermanyDepartment of Physics and Research Center OPTIMAS , Rheinland-Pfälzische Technische Universität Kaiserslautern-Landau, 67663 Kaiserslautern, Germany; Current address: Universität des Saarlandes, Campus Homburg , 66421 Homburg, GermanyDepartment of Physics and Research Center OPTIMAS , Rheinland-Pfälzische Technische Universität Kaiserslautern-Landau, 67663 Kaiserslautern, GermanyDepartment of Physics and Research Center OPTIMAS , Rheinland-Pfälzische Technische Universität Kaiserslautern-Landau, 67663 Kaiserslautern, Germany; Laboratoire des Sciences des Procédés et des Matériaux—LSPM—Villetaneuse , 93430 Villetaneuse, FranceLaboratoire des Sciences des Procédés et des Matériaux—LSPM—CNRS, Université Sorbonne Paris Nord , 93430 Villetaneuse, FranceLaboratoire des Sciences des Procédés et des Matériaux—LSPM—CNRS, Université Sorbonne Paris Nord , 93430 Villetaneuse, France; Ecole Nationale Supérieure de Chimie de Paris—Chimie Paristech, Université Paris Sciences et Lettres (PSL) , 75231 Paris, FranceLaboratoire des Sciences des Procédés et des Matériaux—LSPM—CNRS, Université Sorbonne Paris Nord , 93430 Villetaneuse, FranceLaboratoire des Sciences des Procédés et des Matériaux—LSPM—CNRS, Université Sorbonne Paris Nord , 93430 Villetaneuse, FranceDepartment of Physics and Research Center OPTIMAS , Rheinland-Pfälzische Technische Universität Kaiserslautern-Landau, 67663 Kaiserslautern, GermanyProviding high-quality, single-crystal diamond (SCD) with a large area is desirable for up-scaling quantum technology applications that rely on color centers in diamond. Growth methods aiming to increase the area of SCD are an active research area. Native color centers offer a sensitive probe for local crystal quality in such novel materials e.g. via their reaction to stress. In this work, we investigate individual native nitrogen-vacancy (NV) centers in SCD layers manufactured via laterally overgrowing hole arrays in a heteroepitaxially grown large-scale substrate. Heteroepitaxy has become a common tool for growing large SCDs; however, achieving the high crystal quality needed for quantum applications remains a challenge. In the overgrown layer, we identify NV centers with spin-decoherence times in the order of hundreds of µ s, comparable to high-purity homoepitaxial SCD. We quantify the effective crystal stress in different regions of the overgrown layer, indicating a low stress overall and a stress reduction in the diamond layer above the holes.https://doi.org/10.1088/2633-4356/adce50diamondnitrogen vacancy centerepitaxyspin coherencestrain
spellingShingle Nimba Oshnik
Sebastian Westrich
Nina Burmeister
Oliver Roman Opaluch
Lahcene Mehmel
Riadh Issaoui
Alexandre Tallaire
Ovidiu Brinza
Jocelyn Achard
Elke Neu
Nitrogen-vacancy centers in epitaxial laterally overgrown diamond: towards up-scaling of color center-based quantum technologies
Materials for Quantum Technology
diamond
nitrogen vacancy center
epitaxy
spin coherence
strain
title Nitrogen-vacancy centers in epitaxial laterally overgrown diamond: towards up-scaling of color center-based quantum technologies
title_full Nitrogen-vacancy centers in epitaxial laterally overgrown diamond: towards up-scaling of color center-based quantum technologies
title_fullStr Nitrogen-vacancy centers in epitaxial laterally overgrown diamond: towards up-scaling of color center-based quantum technologies
title_full_unstemmed Nitrogen-vacancy centers in epitaxial laterally overgrown diamond: towards up-scaling of color center-based quantum technologies
title_short Nitrogen-vacancy centers in epitaxial laterally overgrown diamond: towards up-scaling of color center-based quantum technologies
title_sort nitrogen vacancy centers in epitaxial laterally overgrown diamond towards up scaling of color center based quantum technologies
topic diamond
nitrogen vacancy center
epitaxy
spin coherence
strain
url https://doi.org/10.1088/2633-4356/adce50
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