Inadequate Models of Stereochemistry Based on Kimball’s Spheres and Pauli’s Exclusion Principle

The confinement of two electrons in each of several non-overlapping spheres is not intended as “Ansatz” for Schrödinger’s equation, and the concomitant kinetic energy is studied. The “ coexistence integral ” of two atomic angular functions is introduced, and the Gillespie description and Pauli excl...

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Main Author: Christian K. Jørgensen
Format: Article
Language:deu
Published: Swiss Chemical Society 1977-11-01
Series:CHIMIA
Online Access:https://www.chimia.ch/chimia/article/view/9386
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author Christian K. Jørgensen
author_facet Christian K. Jørgensen
author_sort Christian K. Jørgensen
collection DOAJ
description The confinement of two electrons in each of several non-overlapping spheres is not intended as “Ansatz” for Schrödinger’s equation, and the concomitant kinetic energy is studied. The “ coexistence integral ” of two atomic angular functions is introduced, and the Gillespie description and Pauli exclusion principle are discussed.
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2673-2424
language deu
publishDate 1977-11-01
publisher Swiss Chemical Society
record_format Article
series CHIMIA
spelling doaj-art-d6cc3e6c36234ffe9dbb7718823fab862025-08-20T02:29:54ZdeuSwiss Chemical SocietyCHIMIA0009-42932673-24241977-11-01311110.2533/chimia.1977.445Inadequate Models of Stereochemistry Based on Kimball’s Spheres and Pauli’s Exclusion PrincipleChristian K. Jørgensen0Département de Chimie minérale, analytique et appliquée, Université de Genève The confinement of two electrons in each of several non-overlapping spheres is not intended as “Ansatz” for Schrödinger’s equation, and the concomitant kinetic energy is studied. The “ coexistence integral ” of two atomic angular functions is introduced, and the Gillespie description and Pauli exclusion principle are discussed. https://www.chimia.ch/chimia/article/view/9386
spellingShingle Christian K. Jørgensen
Inadequate Models of Stereochemistry Based on Kimball’s Spheres and Pauli’s Exclusion Principle
CHIMIA
title Inadequate Models of Stereochemistry Based on Kimball’s Spheres and Pauli’s Exclusion Principle
title_full Inadequate Models of Stereochemistry Based on Kimball’s Spheres and Pauli’s Exclusion Principle
title_fullStr Inadequate Models of Stereochemistry Based on Kimball’s Spheres and Pauli’s Exclusion Principle
title_full_unstemmed Inadequate Models of Stereochemistry Based on Kimball’s Spheres and Pauli’s Exclusion Principle
title_short Inadequate Models of Stereochemistry Based on Kimball’s Spheres and Pauli’s Exclusion Principle
title_sort inadequate models of stereochemistry based on kimball s spheres and pauli s exclusion principle
url https://www.chimia.ch/chimia/article/view/9386
work_keys_str_mv AT christiankjørgensen inadequatemodelsofstereochemistrybasedonkimballsspheresandpaulisexclusionprinciple