Influence of Si Content on Microstructure and Mechanical Properties of CoCrFeNi High-Entropy Alloys

CoCrFeNiSi<i><sub>x</sub></i> (where x = 0, 0.5, 1.0, 1.5, 2.0 mol, named as H4, Si<sub>0.5</sub>, Si<sub>1.0</sub>, Si<sub>1.5</sub>, and Si<sub>2.0</sub>, respectively) high-entropy alloys (HEAs) were fabricated via hot-press...

Full description

Saved in:
Bibliographic Details
Main Authors: Yajun Zhou, Ruifeng Zhao, Bo Ren, Aiyun Jiang, Zhongxia Liu, Jianxiu Liu
Format: Article
Language:English
Published: MDPI AG 2025-05-01
Series:Metals
Subjects:
Online Access:https://www.mdpi.com/2075-4701/15/5/538
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:CoCrFeNiSi<i><sub>x</sub></i> (where x = 0, 0.5, 1.0, 1.5, 2.0 mol, named as H4, Si<sub>0.5</sub>, Si<sub>1.0</sub>, Si<sub>1.5</sub>, and Si<sub>2.0</sub>, respectively) high-entropy alloys (HEAs) were fabricated via hot-press sintering. The effects of Si content on the phase structure, microstructure, and mechanical properties of HEAs were investigated. The results show that the H4 alloy consists of a single FCC phase. As the Si content increases, the phases of CoCrFeNiSi<i><sub>x</sub></i> HEAs transform from the FCC phase to the BCC and silicide phases. An increase in Si content can significantly enhance the hardness and yield strength of the alloys, yet at the expense of their plasticity. When the Si content increases from 0 to 2.0 mol, the hardness of the alloy increases from 280 HV to 1060 HV, the yield strength rises from 760 MPa to 1640 MPa, and the fracture strain drops to 6%. The strengthening mechanism of this HEA system mainly stems from the synergistic effect of solid solution strengthening and precipitation strengthening of silicide phases.
ISSN:2075-4701