Ecofriendly synthesis of NiZnFe2O5 nanoparticle by papaya leaf extract for electrochemical detection of ascorbic acid in orange juice and pharmaceuticals
A green technique has been employed to synthesize the NiZnFe2O5 nanoparticles using papaya leaf extract. The X-ray diffraction investigated the structural characteristics and crystalline size. The morphology of the synthesised nanoparticle is analysed by scanning electron microscopy. The average di...
Saved in:
| Main Authors: | , , , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Association of Physical Chemists (IAPC)
2024-12-01
|
| Series: | Journal of Electrochemical Science and Engineering |
| Subjects: | |
| Online Access: | https://pub.iapchem.org/ojs/index.php/JESE/article/view/2479 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1850257294421393408 |
|---|---|
| author | Gubbihalli Nanjundappa Chandana Murudagalli Basavaraju Shivaswamy Mandya Shivananju Asha Shanthalingaiah Jeevitha Honnegowdanahalli Shivabasappa Nagendra Prasad Bendekere Shankarappa Hemanth Madanahalli Ankanathappa Sangamesha Beejaganahalli Sangameshwara Madhukar Lingappa Mallesha Jamballi G. Manjunatha |
| author_facet | Gubbihalli Nanjundappa Chandana Murudagalli Basavaraju Shivaswamy Mandya Shivananju Asha Shanthalingaiah Jeevitha Honnegowdanahalli Shivabasappa Nagendra Prasad Bendekere Shankarappa Hemanth Madanahalli Ankanathappa Sangamesha Beejaganahalli Sangameshwara Madhukar Lingappa Mallesha Jamballi G. Manjunatha |
| author_sort | Gubbihalli Nanjundappa Chandana |
| collection | DOAJ |
| description |
A green technique has been employed to synthesize the NiZnFe2O5 nanoparticles using papaya leaf extract. The X-ray diffraction investigated the structural characteristics and crystalline size. The morphology of the synthesised nanoparticle is analysed by scanning electron microscopy. The average diameter of the nanoparticle is 47.93 nm, which was determined using the dynamic light scattering method. UV/Vis diffuse reflectance spectrum results revealed that the NiZnFe2O5 NPs band gap is 1.8 eV. It was calculated using the Kubelka-Monk function and energy dispersion X-ray spectroscopy analysis was used to identify the synthesized nanoparticle's elements. The electrochemical behaviour of NiZnFe2O5 modified glassy carbon electrode (GCE) nd bare GCE was studied to detect ascorbic acid using cyclic voltammetry and differential pulse voltammetry. Compared to unmodified GCE, NiZnFe2O5 nanoparticles modified GCE exhibit excellent electrocatalytic activity towards the AA oxidation, which was proved by the increase in peak current and decrease in peak potential. Electrochemical impedance analysis suggests that the NiZnFe2O5 nanoparticles significantly enhance the charge transfer rate. The linear response of the peak current on the concentration of AA was obtained in the range of 0.2-50 µM. The detection limit was found to be 1.038 µM. The present work serves as a systematic benchmark to assess the electrochemical sensing potential of NiZnFe2O5 NPs towards AA in orange juice and pharmaceuticals.
|
| format | Article |
| id | doaj-art-d5a48d98c2f04334973b6a21595eb5e4 |
| institution | OA Journals |
| issn | 1847-9286 |
| language | English |
| publishDate | 2024-12-01 |
| publisher | International Association of Physical Chemists (IAPC) |
| record_format | Article |
| series | Journal of Electrochemical Science and Engineering |
| spelling | doaj-art-d5a48d98c2f04334973b6a21595eb5e42025-08-20T01:56:28ZengInternational Association of Physical Chemists (IAPC)Journal of Electrochemical Science and Engineering1847-92862024-12-0110.5599/jese.2479Ecofriendly synthesis of NiZnFe2O5 nanoparticle by papaya leaf extract for electrochemical detection of ascorbic acid in orange juice and pharmaceuticalsGubbihalli Nanjundappa Chandana0Murudagalli Basavaraju Shivaswamy1Mandya Shivananju Asha2Shanthalingaiah Jeevitha3Honnegowdanahalli Shivabasappa Nagendra Prasad4Bendekere Shankarappa Hemanth5Madanahalli Ankanathappa Sangamesha6Beejaganahalli Sangameshwara Madhukar7Lingappa Mallesha8Jamballi G. Manjunatha9Department of Chemistry, Sri Jayachamarajendra College of Engineering, JSS Science and Technology University, Mysuru-570 006, Karnataka, IndiaDepartment of Chemistry, Sri Jayachamarajendra College of Engineering, JSS Science and Technology University, Mysuru-570 006, Karnataka, IndiaDepartment of Studies and Research Centre in Chemistry (A Recognized Research Centre of University of Mysore), St. Philomena’s College Bannimantapa, Mysuru 570015, Karnataka, IndiaDepartment of Chemistry, Sri Jayachamarajendra College of Engineering, JSS Science and Technology University, Mysuru-570 006, Karnataka, IndiaDepartment of Chemistry,Sri Jayachamarajendra College of Engineering, JSS Science and Technology University, Mysuru-570006Centre for Nano and Material Sciences, JAIN (Deemed-to-be University), Jain Global Campus, Kanakapura, Bangalore, Karnataka-562112, IndiaDepartment of Chemistry, The National Institute of Engineering, Mysuru-570008, Karnataka, India.Department of Chemistry, Sri Jayachamarajendra College of Engineering, JSS Science and Technology University, Mysuru-570 006, Karnataka, IndiaJSS College of Arts, Commerce and Science, Ooty road, Mysuru, Karnataka-570008, IndiaDepartment of Chemistry, FMKMC College, Constituent College of Mangalore University, Madikeri, Karnataka-571201, India A green technique has been employed to synthesize the NiZnFe2O5 nanoparticles using papaya leaf extract. The X-ray diffraction investigated the structural characteristics and crystalline size. The morphology of the synthesised nanoparticle is analysed by scanning electron microscopy. The average diameter of the nanoparticle is 47.93 nm, which was determined using the dynamic light scattering method. UV/Vis diffuse reflectance spectrum results revealed that the NiZnFe2O5 NPs band gap is 1.8 eV. It was calculated using the Kubelka-Monk function and energy dispersion X-ray spectroscopy analysis was used to identify the synthesized nanoparticle's elements. The electrochemical behaviour of NiZnFe2O5 modified glassy carbon electrode (GCE) nd bare GCE was studied to detect ascorbic acid using cyclic voltammetry and differential pulse voltammetry. Compared to unmodified GCE, NiZnFe2O5 nanoparticles modified GCE exhibit excellent electrocatalytic activity towards the AA oxidation, which was proved by the increase in peak current and decrease in peak potential. Electrochemical impedance analysis suggests that the NiZnFe2O5 nanoparticles significantly enhance the charge transfer rate. The linear response of the peak current on the concentration of AA was obtained in the range of 0.2-50 µM. The detection limit was found to be 1.038 µM. The present work serves as a systematic benchmark to assess the electrochemical sensing potential of NiZnFe2O5 NPs towards AA in orange juice and pharmaceuticals. https://pub.iapchem.org/ojs/index.php/JESE/article/view/2479Green synthesisglassy carbon electrodecyclic voltammetrydifferential pulse voltammetryvitamin-C tablets |
| spellingShingle | Gubbihalli Nanjundappa Chandana Murudagalli Basavaraju Shivaswamy Mandya Shivananju Asha Shanthalingaiah Jeevitha Honnegowdanahalli Shivabasappa Nagendra Prasad Bendekere Shankarappa Hemanth Madanahalli Ankanathappa Sangamesha Beejaganahalli Sangameshwara Madhukar Lingappa Mallesha Jamballi G. Manjunatha Ecofriendly synthesis of NiZnFe2O5 nanoparticle by papaya leaf extract for electrochemical detection of ascorbic acid in orange juice and pharmaceuticals Journal of Electrochemical Science and Engineering Green synthesis glassy carbon electrode cyclic voltammetry differential pulse voltammetry vitamin-C tablets |
| title | Ecofriendly synthesis of NiZnFe2O5 nanoparticle by papaya leaf extract for electrochemical detection of ascorbic acid in orange juice and pharmaceuticals |
| title_full | Ecofriendly synthesis of NiZnFe2O5 nanoparticle by papaya leaf extract for electrochemical detection of ascorbic acid in orange juice and pharmaceuticals |
| title_fullStr | Ecofriendly synthesis of NiZnFe2O5 nanoparticle by papaya leaf extract for electrochemical detection of ascorbic acid in orange juice and pharmaceuticals |
| title_full_unstemmed | Ecofriendly synthesis of NiZnFe2O5 nanoparticle by papaya leaf extract for electrochemical detection of ascorbic acid in orange juice and pharmaceuticals |
| title_short | Ecofriendly synthesis of NiZnFe2O5 nanoparticle by papaya leaf extract for electrochemical detection of ascorbic acid in orange juice and pharmaceuticals |
| title_sort | ecofriendly synthesis of niznfe2o5 nanoparticle by papaya leaf extract for electrochemical detection of ascorbic acid in orange juice and pharmaceuticals |
| topic | Green synthesis glassy carbon electrode cyclic voltammetry differential pulse voltammetry vitamin-C tablets |
| url | https://pub.iapchem.org/ojs/index.php/JESE/article/view/2479 |
| work_keys_str_mv | AT gubbihallinanjundappachandana ecofriendlysynthesisofniznfe2o5nanoparticlebypapayaleafextractforelectrochemicaldetectionofascorbicacidinorangejuiceandpharmaceuticals AT murudagallibasavarajushivaswamy ecofriendlysynthesisofniznfe2o5nanoparticlebypapayaleafextractforelectrochemicaldetectionofascorbicacidinorangejuiceandpharmaceuticals AT mandyashivananjuasha ecofriendlysynthesisofniznfe2o5nanoparticlebypapayaleafextractforelectrochemicaldetectionofascorbicacidinorangejuiceandpharmaceuticals AT shanthalingaiahjeevitha ecofriendlysynthesisofniznfe2o5nanoparticlebypapayaleafextractforelectrochemicaldetectionofascorbicacidinorangejuiceandpharmaceuticals AT honnegowdanahallishivabasappanagendraprasad ecofriendlysynthesisofniznfe2o5nanoparticlebypapayaleafextractforelectrochemicaldetectionofascorbicacidinorangejuiceandpharmaceuticals AT bendekereshankarappahemanth ecofriendlysynthesisofniznfe2o5nanoparticlebypapayaleafextractforelectrochemicaldetectionofascorbicacidinorangejuiceandpharmaceuticals AT madanahalliankanathappasangamesha ecofriendlysynthesisofniznfe2o5nanoparticlebypapayaleafextractforelectrochemicaldetectionofascorbicacidinorangejuiceandpharmaceuticals AT beejaganahallisangameshwaramadhukar ecofriendlysynthesisofniznfe2o5nanoparticlebypapayaleafextractforelectrochemicaldetectionofascorbicacidinorangejuiceandpharmaceuticals AT lingappamallesha ecofriendlysynthesisofniznfe2o5nanoparticlebypapayaleafextractforelectrochemicaldetectionofascorbicacidinorangejuiceandpharmaceuticals AT jamballigmanjunatha ecofriendlysynthesisofniznfe2o5nanoparticlebypapayaleafextractforelectrochemicaldetectionofascorbicacidinorangejuiceandpharmaceuticals |