A Promising Strategy for Solvent-Regulated Selective Hydrogenation of 5-Hydroxymethylfurfural over Porous Carbon-Supported Ni-ZnO Nanoparticles
Highlights A porous carbon-supported Ni-ZnO nanoparticles catalyst (Ni-ZnO/AC) was synthesized by low-temperature coprecipitation, demonstrating exceptional catalytic activity and stability. Selective hydrogenation of 5-hydroxymethylfurfural (HMF) to 2,5-bis(hydroxymethyl)furan (97.5%) or 2,5-dimeth...
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| Format: | Article |
| Language: | English |
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SpringerOpen
2025-07-01
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| Series: | Nano-Micro Letters |
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| Online Access: | https://doi.org/10.1007/s40820-025-01847-5 |
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| author | Rulu Huang Chao Liu Kaili Zhang Jianchun Jiang Ziqi Tian Yongming Chai Kui Wang |
| author_facet | Rulu Huang Chao Liu Kaili Zhang Jianchun Jiang Ziqi Tian Yongming Chai Kui Wang |
| author_sort | Rulu Huang |
| collection | DOAJ |
| description | Highlights A porous carbon-supported Ni-ZnO nanoparticles catalyst (Ni-ZnO/AC) was synthesized by low-temperature coprecipitation, demonstrating exceptional catalytic activity and stability. Selective hydrogenation of 5-hydroxymethylfurfural (HMF) to 2,5-bis(hydroxymethyl)furan (97.5%) or 2,5-dimethylfuran (99.5%) is achieved over Ni-ZnO/AC catalyst by solvent-tuning. Solvent-catalyst interaction jointly regulates hydrodeoxygenation behavior in HMF hydrogenation by modulating rate and pathway via a hydrogen shuttle mechanism. |
| format | Article |
| id | doaj-art-d56d16715cb14380b4e0ad8b8420a3a6 |
| institution | Kabale University |
| issn | 2311-6706 2150-5551 |
| language | English |
| publishDate | 2025-07-01 |
| publisher | SpringerOpen |
| record_format | Article |
| series | Nano-Micro Letters |
| spelling | doaj-art-d56d16715cb14380b4e0ad8b8420a3a62025-08-20T03:46:27ZengSpringerOpenNano-Micro Letters2311-67062150-55512025-07-0118111410.1007/s40820-025-01847-5A Promising Strategy for Solvent-Regulated Selective Hydrogenation of 5-Hydroxymethylfurfural over Porous Carbon-Supported Ni-ZnO NanoparticlesRulu Huang0Chao Liu1Kaili Zhang2Jianchun Jiang3Ziqi Tian4Yongming Chai5Kui Wang6National Key Laboratory for Development and Utilization of Forest Food Resources, Biomass Energy and Material Key Laboratory of Jiangsu Province, Institute of Chemical Industry of Forest Products, Chinese Academy of ForestrySchool of Materials Science and Engineering, Central South University of Forestry and TechnologyCo-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry UniversityNational Key Laboratory for Development and Utilization of Forest Food Resources, Biomass Energy and Material Key Laboratory of Jiangsu Province, Institute of Chemical Industry of Forest Products, Chinese Academy of ForestryNingbo Institute of Materials Technology and Engineering, Chinese Academy of SciencesState Key Laboratory of Heavy Oil Processing, College of Chemistry and Chemical Engineering, China University of Petroleum (East China)National Key Laboratory for Development and Utilization of Forest Food Resources, Biomass Energy and Material Key Laboratory of Jiangsu Province, Institute of Chemical Industry of Forest Products, Chinese Academy of ForestryHighlights A porous carbon-supported Ni-ZnO nanoparticles catalyst (Ni-ZnO/AC) was synthesized by low-temperature coprecipitation, demonstrating exceptional catalytic activity and stability. Selective hydrogenation of 5-hydroxymethylfurfural (HMF) to 2,5-bis(hydroxymethyl)furan (97.5%) or 2,5-dimethylfuran (99.5%) is achieved over Ni-ZnO/AC catalyst by solvent-tuning. Solvent-catalyst interaction jointly regulates hydrodeoxygenation behavior in HMF hydrogenation by modulating rate and pathway via a hydrogen shuttle mechanism.https://doi.org/10.1007/s40820-025-01847-5Porous carbon-supported Ni-ZnO nanoparticles catalystSelective hydrogenation5-HydroxymethylfurfuralSolventProton-donating ability |
| spellingShingle | Rulu Huang Chao Liu Kaili Zhang Jianchun Jiang Ziqi Tian Yongming Chai Kui Wang A Promising Strategy for Solvent-Regulated Selective Hydrogenation of 5-Hydroxymethylfurfural over Porous Carbon-Supported Ni-ZnO Nanoparticles Nano-Micro Letters Porous carbon-supported Ni-ZnO nanoparticles catalyst Selective hydrogenation 5-Hydroxymethylfurfural Solvent Proton-donating ability |
| title | A Promising Strategy for Solvent-Regulated Selective Hydrogenation of 5-Hydroxymethylfurfural over Porous Carbon-Supported Ni-ZnO Nanoparticles |
| title_full | A Promising Strategy for Solvent-Regulated Selective Hydrogenation of 5-Hydroxymethylfurfural over Porous Carbon-Supported Ni-ZnO Nanoparticles |
| title_fullStr | A Promising Strategy for Solvent-Regulated Selective Hydrogenation of 5-Hydroxymethylfurfural over Porous Carbon-Supported Ni-ZnO Nanoparticles |
| title_full_unstemmed | A Promising Strategy for Solvent-Regulated Selective Hydrogenation of 5-Hydroxymethylfurfural over Porous Carbon-Supported Ni-ZnO Nanoparticles |
| title_short | A Promising Strategy for Solvent-Regulated Selective Hydrogenation of 5-Hydroxymethylfurfural over Porous Carbon-Supported Ni-ZnO Nanoparticles |
| title_sort | promising strategy for solvent regulated selective hydrogenation of 5 hydroxymethylfurfural over porous carbon supported ni zno nanoparticles |
| topic | Porous carbon-supported Ni-ZnO nanoparticles catalyst Selective hydrogenation 5-Hydroxymethylfurfural Solvent Proton-donating ability |
| url | https://doi.org/10.1007/s40820-025-01847-5 |
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