A Promising Strategy for Solvent-Regulated Selective Hydrogenation of 5-Hydroxymethylfurfural over Porous Carbon-Supported Ni-ZnO Nanoparticles

A Promising Strategy for Solvent-Regulated Selective Hydrogenation of 5-Hydroxymethylfurfural over Porous Carbon-Supported Ni-ZnO Nanoparticles

Highlights A porous carbon-supported Ni-ZnO nanoparticles catalyst (Ni-ZnO/AC) was synthesized by low-temperature coprecipitation, demonstrating exceptional catalytic activity and stability. Selective hydrogenation of 5-hydroxymethylfurfural (HMF) to 2,5-bis(hydroxymethyl)furan (97.5%) or 2,5-dimeth...

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Bibliographic Details
Main Authors: Rulu Huang, Chao Liu, Kaili Zhang, Jianchun Jiang, Ziqi Tian, Yongming Chai, Kui Wang
Format: Article
Language:English
Published: SpringerOpen 2025-07-01
Series:Nano-Micro Letters
Subjects:
Porous carbon-supported Ni-ZnO nanoparticles catalyst
Selective hydrogenation
5-Hydroxymethylfurfural
Solvent
Proton-donating ability
Online Access:https://doi.org/10.1007/s40820-025-01847-5
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Summary:Highlights A porous carbon-supported Ni-ZnO nanoparticles catalyst (Ni-ZnO/AC) was synthesized by low-temperature coprecipitation, demonstrating exceptional catalytic activity and stability. Selective hydrogenation of 5-hydroxymethylfurfural (HMF) to 2,5-bis(hydroxymethyl)furan (97.5%) or 2,5-dimethylfuran (99.5%) is achieved over Ni-ZnO/AC catalyst by solvent-tuning. Solvent-catalyst interaction jointly regulates hydrodeoxygenation behavior in HMF hydrogenation by modulating rate and pathway via a hydrogen shuttle mechanism.
ISSN:2311-6706
2150-5551

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