Study on Stress Corrosion Sensitivity of 304 and 304L in the Ethylene Oxide/Ethylene Glycol Unit of a Certain Refinery

Ethylene oxide (EO) is a crucial organic synthesis raw material,ranking just behind polyethylene and polyvinyl chloride,and is primarily used in the production of ethylene glycol (EG).The SD process for EO/EG units(a patented EO/EG technology from SD Company in the United States) suffers from typica...

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Main Author: TANG Zhenhua, LIU Xiwu, LI Hui, LIU Xuxia, ZHANG Ruoxi
Format: Article
Language:zho
Published: Editorial Department of Materials Protection 2024-11-01
Series:Cailiao Baohu
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Online Access:http://www.mat-pro.com/fileup/1001-1560/PDF/20241120.pdf
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author TANG Zhenhua, LIU Xiwu, LI Hui, LIU Xuxia, ZHANG Ruoxi
author_facet TANG Zhenhua, LIU Xiwu, LI Hui, LIU Xuxia, ZHANG Ruoxi
author_sort TANG Zhenhua, LIU Xiwu, LI Hui, LIU Xuxia, ZHANG Ruoxi
collection DOAJ
description Ethylene oxide (EO) is a crucial organic synthesis raw material,ranking just behind polyethylene and polyvinyl chloride,and is primarily used in the production of ethylene glycol (EG).The SD process for EO/EG units(a patented EO/EG technology from SD Company in the United States) suffers from typical stress corrosion problems.To address this,the corrosion behavior and mechanisms of refinery-grade 304 and 304L materials in typical environments such as EO purification towers were simulated.Stress corrosion cracking susceptibility of the two materials was evaluated through slow strain rate testing.Results showed that the stress corrosion in EO/EG units was associated with the sensitization of stainless steel,with sensitized 304 and 304L stainless steel exhibiting susceptibility to stress corrosion cracking.Corresponding measures for material and process optimization were proposed,providing technical support to enhance the safe and stable operation of EO/EG units.
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id doaj-art-d5517e7bb65c43d1bb1f22fdaa0ae5e0
institution OA Journals
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publishDate 2024-11-01
publisher Editorial Department of Materials Protection
record_format Article
series Cailiao Baohu
spelling doaj-art-d5517e7bb65c43d1bb1f22fdaa0ae5e02025-08-20T02:31:52ZzhoEditorial Department of Materials ProtectionCailiao Baohu1001-15602024-11-01571117217710.16577/j.issn.1001-1560.2024.0262Study on Stress Corrosion Sensitivity of 304 and 304L in the Ethylene Oxide/Ethylene Glycol Unit of a Certain RefineryTANG Zhenhua, LIU Xiwu, LI Hui, LIU Xuxia, ZHANG Ruoxi0(SINOPEC Engineering Group Luoyang R&D Center of Technology,Luoyang 471003,China)Ethylene oxide (EO) is a crucial organic synthesis raw material,ranking just behind polyethylene and polyvinyl chloride,and is primarily used in the production of ethylene glycol (EG).The SD process for EO/EG units(a patented EO/EG technology from SD Company in the United States) suffers from typical stress corrosion problems.To address this,the corrosion behavior and mechanisms of refinery-grade 304 and 304L materials in typical environments such as EO purification towers were simulated.Stress corrosion cracking susceptibility of the two materials was evaluated through slow strain rate testing.Results showed that the stress corrosion in EO/EG units was associated with the sensitization of stainless steel,with sensitized 304 and 304L stainless steel exhibiting susceptibility to stress corrosion cracking.Corresponding measures for material and process optimization were proposed,providing technical support to enhance the safe and stable operation of EO/EG units.http://www.mat-pro.com/fileup/1001-1560/PDF/20241120.pdfethylene oxide refining tower;slow stretching;sensitization;304 and 304l;sensitivity to stress corrosion cracking
spellingShingle TANG Zhenhua, LIU Xiwu, LI Hui, LIU Xuxia, ZHANG Ruoxi
Study on Stress Corrosion Sensitivity of 304 and 304L in the Ethylene Oxide/Ethylene Glycol Unit of a Certain Refinery
Cailiao Baohu
ethylene oxide refining tower;slow stretching;sensitization;304 and 304l;sensitivity to stress corrosion cracking
title Study on Stress Corrosion Sensitivity of 304 and 304L in the Ethylene Oxide/Ethylene Glycol Unit of a Certain Refinery
title_full Study on Stress Corrosion Sensitivity of 304 and 304L in the Ethylene Oxide/Ethylene Glycol Unit of a Certain Refinery
title_fullStr Study on Stress Corrosion Sensitivity of 304 and 304L in the Ethylene Oxide/Ethylene Glycol Unit of a Certain Refinery
title_full_unstemmed Study on Stress Corrosion Sensitivity of 304 and 304L in the Ethylene Oxide/Ethylene Glycol Unit of a Certain Refinery
title_short Study on Stress Corrosion Sensitivity of 304 and 304L in the Ethylene Oxide/Ethylene Glycol Unit of a Certain Refinery
title_sort study on stress corrosion sensitivity of 304 and 304l in the ethylene oxide ethylene glycol unit of a certain refinery
topic ethylene oxide refining tower;slow stretching;sensitization;304 and 304l;sensitivity to stress corrosion cracking
url http://www.mat-pro.com/fileup/1001-1560/PDF/20241120.pdf
work_keys_str_mv AT tangzhenhualiuxiwulihuiliuxuxiazhangruoxi studyonstresscorrosionsensitivityof304and304lintheethyleneoxideethyleneglycolunitofacertainrefinery