Assessment of Potential Toxicity of Hyaluronic Acid-Coated Magnetic Nanoparticles on Maize (<i>Zea mays</i>) at Early Development Stages

The effectiveness of iron oxide nanoparticles in enhancing crop plant development depends on their stabilization. In this study, the effect of hyaluronic acid (HA), used both as a stabilizer for iron oxide nanoparticles (HA-MNP) and independently, was evaluated in maize seedlings. Different concentr...

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Main Authors: Mihaela Răcuciu, Cristina-Nicoleta Precup, Maria Denisa Cocîrlea, Simona Oancea
Format: Article
Language:English
Published: MDPI AG 2025-03-01
Series:Molecules
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Online Access:https://www.mdpi.com/1420-3049/30/6/1316
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author Mihaela Răcuciu
Cristina-Nicoleta Precup
Maria Denisa Cocîrlea
Simona Oancea
author_facet Mihaela Răcuciu
Cristina-Nicoleta Precup
Maria Denisa Cocîrlea
Simona Oancea
author_sort Mihaela Răcuciu
collection DOAJ
description The effectiveness of iron oxide nanoparticles in enhancing crop plant development depends on their stabilization. In this study, the effect of hyaluronic acid (HA), used both as a stabilizer for iron oxide nanoparticles (HA-MNP) and independently, was evaluated in maize seedlings. Different concentrations of HA-MNP (0.625–7.5 mg/L) were tested alongside a 0.01% HA solution. Growth parameters, antioxidant enzyme activities (peroxidase and polyphenol oxidase), photosynthetic pigments (chlorophyll and carotenoids), phenolic content, and genotoxicity were analyzed. While HA alone led to slight decreases in seedling length, pigment content, and polyphenol levels compared to the control, it increased peroxidase activity and mitotic index. Lower concentrations of HA-MNP (below 2.5 mg/L) enhanced seedling growth, likely due to improved iron uptake, whereas higher concentrations reduced pigment and phenolic content. All HA-MNP concentrations induced genotoxic effects, which was proven by an increased mitotic index and chromosomal aberrations, indicating both positive and defensive plant responses to oxidative stress. These findings suggest a complex interaction between HA, HA-MNP, and maize seedlings, where HA concentrations play a significant role in modulating growth and stress response, while higher concentrations may induce toxicity.
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publisher MDPI AG
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series Molecules
spelling doaj-art-d4c131f60e404e8b82660b2d5bd563cc2025-08-20T01:48:48ZengMDPI AGMolecules1420-30492025-03-01306131610.3390/molecules30061316Assessment of Potential Toxicity of Hyaluronic Acid-Coated Magnetic Nanoparticles on Maize (<i>Zea mays</i>) at Early Development StagesMihaela Răcuciu0Cristina-Nicoleta Precup1Maria Denisa Cocîrlea2Simona Oancea3Environmental Sciences and Physics Department, Faculty of Sciences, Lucian Blaga University of Sibiu, 5-7 Dr. I. Ratiu Street, 550012 Sibiu, RomaniaEnvironmental Sciences and Physics Department, Faculty of Sciences, Lucian Blaga University of Sibiu, 5-7 Dr. I. Ratiu Street, 550012 Sibiu, RomaniaAgricultural Sciences and Food Engineering Department, Lucian Blaga University of Sibiu, 7-9 Dr. I. Ratiu Street, 550024 Sibiu, RomaniaAgricultural Sciences and Food Engineering Department, Lucian Blaga University of Sibiu, 7-9 Dr. I. Ratiu Street, 550024 Sibiu, RomaniaThe effectiveness of iron oxide nanoparticles in enhancing crop plant development depends on their stabilization. In this study, the effect of hyaluronic acid (HA), used both as a stabilizer for iron oxide nanoparticles (HA-MNP) and independently, was evaluated in maize seedlings. Different concentrations of HA-MNP (0.625–7.5 mg/L) were tested alongside a 0.01% HA solution. Growth parameters, antioxidant enzyme activities (peroxidase and polyphenol oxidase), photosynthetic pigments (chlorophyll and carotenoids), phenolic content, and genotoxicity were analyzed. While HA alone led to slight decreases in seedling length, pigment content, and polyphenol levels compared to the control, it increased peroxidase activity and mitotic index. Lower concentrations of HA-MNP (below 2.5 mg/L) enhanced seedling growth, likely due to improved iron uptake, whereas higher concentrations reduced pigment and phenolic content. All HA-MNP concentrations induced genotoxic effects, which was proven by an increased mitotic index and chromosomal aberrations, indicating both positive and defensive plant responses to oxidative stress. These findings suggest a complex interaction between HA, HA-MNP, and maize seedlings, where HA concentrations play a significant role in modulating growth and stress response, while higher concentrations may induce toxicity.https://www.mdpi.com/1420-3049/30/6/1316iron oxide nanoparticlehyaluronic acidmaizeplant growthenzymatic activitychromosomal aberrations
spellingShingle Mihaela Răcuciu
Cristina-Nicoleta Precup
Maria Denisa Cocîrlea
Simona Oancea
Assessment of Potential Toxicity of Hyaluronic Acid-Coated Magnetic Nanoparticles on Maize (<i>Zea mays</i>) at Early Development Stages
Molecules
iron oxide nanoparticle
hyaluronic acid
maize
plant growth
enzymatic activity
chromosomal aberrations
title Assessment of Potential Toxicity of Hyaluronic Acid-Coated Magnetic Nanoparticles on Maize (<i>Zea mays</i>) at Early Development Stages
title_full Assessment of Potential Toxicity of Hyaluronic Acid-Coated Magnetic Nanoparticles on Maize (<i>Zea mays</i>) at Early Development Stages
title_fullStr Assessment of Potential Toxicity of Hyaluronic Acid-Coated Magnetic Nanoparticles on Maize (<i>Zea mays</i>) at Early Development Stages
title_full_unstemmed Assessment of Potential Toxicity of Hyaluronic Acid-Coated Magnetic Nanoparticles on Maize (<i>Zea mays</i>) at Early Development Stages
title_short Assessment of Potential Toxicity of Hyaluronic Acid-Coated Magnetic Nanoparticles on Maize (<i>Zea mays</i>) at Early Development Stages
title_sort assessment of potential toxicity of hyaluronic acid coated magnetic nanoparticles on maize i zea mays i at early development stages
topic iron oxide nanoparticle
hyaluronic acid
maize
plant growth
enzymatic activity
chromosomal aberrations
url https://www.mdpi.com/1420-3049/30/6/1316
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