Possible Superconductivity in Very Thin Magnesium Films

It is known that noble metals such as gold, silver and copper are not superconductors; this is also true for magnesium. This is due to the weakness of the electron–phonon interaction, which makes them excellent conductors but not superconductors. As has recently been shown for gold, silver and coppe...

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Main Authors: Giovanni Alberto Ummarino, Alessio Zaccone
Format: Article
Language:English
Published: MDPI AG 2025-03-01
Series:Condensed Matter
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Online Access:https://www.mdpi.com/2410-3896/10/1/17
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author Giovanni Alberto Ummarino
Alessio Zaccone
author_facet Giovanni Alberto Ummarino
Alessio Zaccone
author_sort Giovanni Alberto Ummarino
collection DOAJ
description It is known that noble metals such as gold, silver and copper are not superconductors; this is also true for magnesium. This is due to the weakness of the electron–phonon interaction, which makes them excellent conductors but not superconductors. As has recently been shown for gold, silver and copper, and even for magnesium, it is possible that in very particular situations, superconductivity may occur. Quantum confinement in thin films has been consistently shown to induce a significant enhancement of the superconducting critical temperature in several superconductors. It is therefore an important fundamental question whether ultra-thin film confinement may induce observable superconductivity in non-superconducting metals such as magnesium. We study this problem using a generalization, in the Eliashberg framework, of a BCS theory of superconductivity in good metals under thin-film confinement. By numerically solving these new Eliashberg-type equations, we find the dependence of the superconducting critical temperature on the film thickness, <i>L</i>. This parameter-free theory predicts superconductivity in very thin magnesium films. We demonstrate that this is a fine-tuning problem where the thickness must assume a very precise value, close to half a nanometer.
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spelling doaj-art-d49aa10015f04d66bc4d035353077c452025-08-20T02:11:18ZengMDPI AGCondensed Matter2410-38962025-03-011011710.3390/condmat10010017Possible Superconductivity in Very Thin Magnesium FilmsGiovanni Alberto Ummarino0Alessio Zaccone1Department of Applied Science and Technology, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino, ItalyDepartment of Physics “A. Pontremoli”, University of Milan, via Celoria 16, 20133 Milan, ItalyIt is known that noble metals such as gold, silver and copper are not superconductors; this is also true for magnesium. This is due to the weakness of the electron–phonon interaction, which makes them excellent conductors but not superconductors. As has recently been shown for gold, silver and copper, and even for magnesium, it is possible that in very particular situations, superconductivity may occur. Quantum confinement in thin films has been consistently shown to induce a significant enhancement of the superconducting critical temperature in several superconductors. It is therefore an important fundamental question whether ultra-thin film confinement may induce observable superconductivity in non-superconducting metals such as magnesium. We study this problem using a generalization, in the Eliashberg framework, of a BCS theory of superconductivity in good metals under thin-film confinement. By numerically solving these new Eliashberg-type equations, we find the dependence of the superconducting critical temperature on the film thickness, <i>L</i>. This parameter-free theory predicts superconductivity in very thin magnesium films. We demonstrate that this is a fine-tuning problem where the thickness must assume a very precise value, close to half a nanometer.https://www.mdpi.com/2410-3896/10/1/17quantum confinementthin filmsEliashberg theory
spellingShingle Giovanni Alberto Ummarino
Alessio Zaccone
Possible Superconductivity in Very Thin Magnesium Films
Condensed Matter
quantum confinement
thin films
Eliashberg theory
title Possible Superconductivity in Very Thin Magnesium Films
title_full Possible Superconductivity in Very Thin Magnesium Films
title_fullStr Possible Superconductivity in Very Thin Magnesium Films
title_full_unstemmed Possible Superconductivity in Very Thin Magnesium Films
title_short Possible Superconductivity in Very Thin Magnesium Films
title_sort possible superconductivity in very thin magnesium films
topic quantum confinement
thin films
Eliashberg theory
url https://www.mdpi.com/2410-3896/10/1/17
work_keys_str_mv AT giovannialbertoummarino possiblesuperconductivityinverythinmagnesiumfilms
AT alessiozaccone possiblesuperconductivityinverythinmagnesiumfilms