Alterations in the cecal microbiome of New Zealand White rabbits due to the long-acting anticoagulant rodenticide brodifacoum

Introduction Long-acting anti-coagulant rodenticides (LAARs) are well characterized with respect to inhibition of vitamin K1 synthesis and effects on blood coagulation. However, effects of LAARs on the microbiome have not been explored.Methods We administered brodifacoum (BDF), one of the more poten...

Full description

Saved in:
Bibliographic Details
Main Authors: Ankur Naqib, Intakhar Ahmad, Zachary McDonald, Sergey Kalinin, Jackie Rocha, Ankit Tandon, Ramanjaneyulu Rayala, Leonid Feferman, George E. Chlipala, Hui Chen, Matthew Lindeblad, Israel Rubinstein, Stefan J. Green, Richard B. van Breemen, Douglas L. Feinstein
Format: Article
Language:English
Published: Taylor & Francis Group 2025-12-01
Series:Toxicology Communications
Subjects:
Online Access:https://www.tandfonline.com/doi/10.1080/24734306.2025.2500111
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1850273820635561984
author Ankur Naqib
Intakhar Ahmad
Zachary McDonald
Sergey Kalinin
Jackie Rocha
Ankit Tandon
Ramanjaneyulu Rayala
Leonid Feferman
George E. Chlipala
Hui Chen
Matthew Lindeblad
Israel Rubinstein
Stefan J. Green
Richard B. van Breemen
Douglas L. Feinstein
author_facet Ankur Naqib
Intakhar Ahmad
Zachary McDonald
Sergey Kalinin
Jackie Rocha
Ankit Tandon
Ramanjaneyulu Rayala
Leonid Feferman
George E. Chlipala
Hui Chen
Matthew Lindeblad
Israel Rubinstein
Stefan J. Green
Richard B. van Breemen
Douglas L. Feinstein
author_sort Ankur Naqib
collection DOAJ
description Introduction Long-acting anti-coagulant rodenticides (LAARs) are well characterized with respect to inhibition of vitamin K1 synthesis and effects on blood coagulation. However, effects of LAARs on the microbiome have not been explored.Methods We administered brodifacoum (BDF), one of the more potent LAARs, to adult male New Zealand White rabbits, and carried out 16S RNA sequencing on cecal samples collected after different times. Samples were also obtained from rabbits treated with the bile sequestrant cholestyramine (CSA) which accelerates BDF clearance from the body, and from CSA-only treated rabbits. We collected blood samples after different times and used mass spectroscopy to measure plasma levels of L-arginine and related molecules.Results Changes at both the phylum and genus levels in relative abundance were observed after 2 and 3 days exposure to BDF. The majority of those microbiota changes were prevented by co-treatment with CSA. Identification of metabolic pathways potentially altered by BDF using Picrust2 identified several L-arginine-related pathways. Exposure to BDF caused increases in plasma L-arginine concentration as well as nitrites, suggesting increased activity of nitric oxide synthase. We also observed increases due to BDF in plasma concentrations of L-arginine-related molecules including L-citrulline, L-ornithine, and methylated L-arginines ADMA and NMMA.Conclusion These results demonstrate that LAAR poisoning can induce microbiome dysbiosis and influence metabolic pathways and metabolites involved in inflammation and vasodilation.
format Article
id doaj-art-d428a930df3747909fc041f3559b7bbc
institution OA Journals
issn 2473-4306
language English
publishDate 2025-12-01
publisher Taylor & Francis Group
record_format Article
series Toxicology Communications
spelling doaj-art-d428a930df3747909fc041f3559b7bbc2025-08-20T01:51:20ZengTaylor & Francis GroupToxicology Communications2473-43062025-12-019110.1080/24734306.2025.2500111Alterations in the cecal microbiome of New Zealand White rabbits due to the long-acting anticoagulant rodenticide brodifacoumAnkur Naqib0Intakhar Ahmad1Zachary McDonald2Sergey Kalinin3Jackie Rocha4Ankit Tandon5Ramanjaneyulu Rayala6Leonid Feferman7George E. Chlipala8Hui Chen9Matthew Lindeblad10Israel Rubinstein11Stefan J. Green12Richard B. van Breemen13Douglas L. Feinstein14Genomics and Microbiome Core Facility, Rush University, Chicago, IL, USADepartment of Anesthesiology, University of Illinois, Chicago, IL, USADepartment of Anesthesiology, University of Illinois, Chicago, IL, USADepartment of Anesthesiology, University of Illinois, Chicago, IL, USADepartment of Anesthesiology, University of Illinois, Chicago, IL, USADepartment of Anesthesiology, University of Illinois, Chicago, IL, USAMass Spectrometry Core, University of Illinois, Chicago, IL, USAResearch Informatics Core, University of Illinois, Chicago, IL, USAResearch Informatics Core, University of Illinois, Chicago, IL, USAMass Spectrometry Core, University of Illinois, Chicago, IL, USAToxicology Research Laboratory, University of Illinois, Chicago, IL, USADepartment of Medicine, University of Illinois, Chicago, IL, USAGenomics and Microbiome Core Facility, Rush University, Chicago, IL, USADepartment of Pharmaceutical Sciences, Linus Pauling Institute, Oregon State University, Corvallis, OR, USADepartment of Anesthesiology, University of Illinois, Chicago, IL, USAIntroduction Long-acting anti-coagulant rodenticides (LAARs) are well characterized with respect to inhibition of vitamin K1 synthesis and effects on blood coagulation. However, effects of LAARs on the microbiome have not been explored.Methods We administered brodifacoum (BDF), one of the more potent LAARs, to adult male New Zealand White rabbits, and carried out 16S RNA sequencing on cecal samples collected after different times. Samples were also obtained from rabbits treated with the bile sequestrant cholestyramine (CSA) which accelerates BDF clearance from the body, and from CSA-only treated rabbits. We collected blood samples after different times and used mass spectroscopy to measure plasma levels of L-arginine and related molecules.Results Changes at both the phylum and genus levels in relative abundance were observed after 2 and 3 days exposure to BDF. The majority of those microbiota changes were prevented by co-treatment with CSA. Identification of metabolic pathways potentially altered by BDF using Picrust2 identified several L-arginine-related pathways. Exposure to BDF caused increases in plasma L-arginine concentration as well as nitrites, suggesting increased activity of nitric oxide synthase. We also observed increases due to BDF in plasma concentrations of L-arginine-related molecules including L-citrulline, L-ornithine, and methylated L-arginines ADMA and NMMA.Conclusion These results demonstrate that LAAR poisoning can induce microbiome dysbiosis and influence metabolic pathways and metabolites involved in inflammation and vasodilation.https://www.tandfonline.com/doi/10.1080/24734306.2025.2500111Rodenticidemicrobiomerabbitcecalargininebile sequestrant
spellingShingle Ankur Naqib
Intakhar Ahmad
Zachary McDonald
Sergey Kalinin
Jackie Rocha
Ankit Tandon
Ramanjaneyulu Rayala
Leonid Feferman
George E. Chlipala
Hui Chen
Matthew Lindeblad
Israel Rubinstein
Stefan J. Green
Richard B. van Breemen
Douglas L. Feinstein
Alterations in the cecal microbiome of New Zealand White rabbits due to the long-acting anticoagulant rodenticide brodifacoum
Toxicology Communications
Rodenticide
microbiome
rabbit
cecal
arginine
bile sequestrant
title Alterations in the cecal microbiome of New Zealand White rabbits due to the long-acting anticoagulant rodenticide brodifacoum
title_full Alterations in the cecal microbiome of New Zealand White rabbits due to the long-acting anticoagulant rodenticide brodifacoum
title_fullStr Alterations in the cecal microbiome of New Zealand White rabbits due to the long-acting anticoagulant rodenticide brodifacoum
title_full_unstemmed Alterations in the cecal microbiome of New Zealand White rabbits due to the long-acting anticoagulant rodenticide brodifacoum
title_short Alterations in the cecal microbiome of New Zealand White rabbits due to the long-acting anticoagulant rodenticide brodifacoum
title_sort alterations in the cecal microbiome of new zealand white rabbits due to the long acting anticoagulant rodenticide brodifacoum
topic Rodenticide
microbiome
rabbit
cecal
arginine
bile sequestrant
url https://www.tandfonline.com/doi/10.1080/24734306.2025.2500111
work_keys_str_mv AT ankurnaqib alterationsinthececalmicrobiomeofnewzealandwhiterabbitsduetothelongactinganticoagulantrodenticidebrodifacoum
AT intakharahmad alterationsinthececalmicrobiomeofnewzealandwhiterabbitsduetothelongactinganticoagulantrodenticidebrodifacoum
AT zacharymcdonald alterationsinthececalmicrobiomeofnewzealandwhiterabbitsduetothelongactinganticoagulantrodenticidebrodifacoum
AT sergeykalinin alterationsinthececalmicrobiomeofnewzealandwhiterabbitsduetothelongactinganticoagulantrodenticidebrodifacoum
AT jackierocha alterationsinthececalmicrobiomeofnewzealandwhiterabbitsduetothelongactinganticoagulantrodenticidebrodifacoum
AT ankittandon alterationsinthececalmicrobiomeofnewzealandwhiterabbitsduetothelongactinganticoagulantrodenticidebrodifacoum
AT ramanjaneyulurayala alterationsinthececalmicrobiomeofnewzealandwhiterabbitsduetothelongactinganticoagulantrodenticidebrodifacoum
AT leonidfeferman alterationsinthececalmicrobiomeofnewzealandwhiterabbitsduetothelongactinganticoagulantrodenticidebrodifacoum
AT georgeechlipala alterationsinthececalmicrobiomeofnewzealandwhiterabbitsduetothelongactinganticoagulantrodenticidebrodifacoum
AT huichen alterationsinthececalmicrobiomeofnewzealandwhiterabbitsduetothelongactinganticoagulantrodenticidebrodifacoum
AT matthewlindeblad alterationsinthececalmicrobiomeofnewzealandwhiterabbitsduetothelongactinganticoagulantrodenticidebrodifacoum
AT israelrubinstein alterationsinthececalmicrobiomeofnewzealandwhiterabbitsduetothelongactinganticoagulantrodenticidebrodifacoum
AT stefanjgreen alterationsinthececalmicrobiomeofnewzealandwhiterabbitsduetothelongactinganticoagulantrodenticidebrodifacoum
AT richardbvanbreemen alterationsinthececalmicrobiomeofnewzealandwhiterabbitsduetothelongactinganticoagulantrodenticidebrodifacoum
AT douglaslfeinstein alterationsinthececalmicrobiomeofnewzealandwhiterabbitsduetothelongactinganticoagulantrodenticidebrodifacoum