Crystal structure and Hirshfeld surface analysis of (E)-2-cyano-N′-(3,4,5-trimethoxybenzylidene)acetohydrazide
In the title compound, C13H15N3O4, the 2-cyano-N′-methylideneacetohydrazide moiety and the trimethoxy phenol ring form a dihedral angle of 13.8 (1)°. Intermolecular N—H...O and C—H...O hydrogen bonds are observed. The intermolecular interactions were quantified and analysed using Hirshfeld surface a...
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International Union of Crystallography
2025-06-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
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| Online Access: | https://journals.iucr.org/paper?S2056989025003913 |
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| author | Subramani Uma Maheswari Srinivasan Senthilkumar Sivashanmugam Selvanayagam |
| author_facet | Subramani Uma Maheswari Srinivasan Senthilkumar Sivashanmugam Selvanayagam |
| author_sort | Subramani Uma Maheswari |
| collection | DOAJ |
| description | In the title compound, C13H15N3O4, the 2-cyano-N′-methylideneacetohydrazide moiety and the trimethoxy phenol ring form a dihedral angle of 13.8 (1)°. Intermolecular N—H...O and C—H...O hydrogen bonds are observed. The intermolecular interactions were quantified and analysed using Hirshfeld surface analysis, revealing that H...H interactions contribute most to the crystal packing (38.3%). |
| format | Article |
| id | doaj-art-d41fd033cee54616b06383c7d599c5df |
| institution | OA Journals |
| issn | 2056-9890 |
| language | English |
| publishDate | 2025-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj-art-d41fd033cee54616b06383c7d599c5df2025-08-20T02:32:12ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902025-06-0181647347510.1107/S2056989025003913tx2097Crystal structure and Hirshfeld surface analysis of (E)-2-cyano-N′-(3,4,5-trimethoxybenzylidene)acetohydrazideSubramani Uma Maheswari0Srinivasan Senthilkumar1Sivashanmugam Selvanayagam2Department of Chemistry, Annamalai University, Annamalainagar, Chidambaram 608 002, IndiaDepartment of Chemistry, Annamalai University, Annamalainagar, Chidambaram 608 002, IndiaPG & Research Department of Physics, Government Arts College, Melur 625 106, IndiaIn the title compound, C13H15N3O4, the 2-cyano-N′-methylideneacetohydrazide moiety and the trimethoxy phenol ring form a dihedral angle of 13.8 (1)°. Intermolecular N—H...O and C—H...O hydrogen bonds are observed. The intermolecular interactions were quantified and analysed using Hirshfeld surface analysis, revealing that H...H interactions contribute most to the crystal packing (38.3%).https://journals.iucr.org/paper?S2056989025003913benzohydrazineintermolecular hydrogen bondshirshfeld surface analysiscrystal structure |
| spellingShingle | Subramani Uma Maheswari Srinivasan Senthilkumar Sivashanmugam Selvanayagam Crystal structure and Hirshfeld surface analysis of (E)-2-cyano-N′-(3,4,5-trimethoxybenzylidene)acetohydrazide Acta Crystallographica Section E: Crystallographic Communications benzohydrazine intermolecular hydrogen bonds hirshfeld surface analysis crystal structure |
| title | Crystal structure and Hirshfeld surface analysis of (E)-2-cyano-N′-(3,4,5-trimethoxybenzylidene)acetohydrazide |
| title_full | Crystal structure and Hirshfeld surface analysis of (E)-2-cyano-N′-(3,4,5-trimethoxybenzylidene)acetohydrazide |
| title_fullStr | Crystal structure and Hirshfeld surface analysis of (E)-2-cyano-N′-(3,4,5-trimethoxybenzylidene)acetohydrazide |
| title_full_unstemmed | Crystal structure and Hirshfeld surface analysis of (E)-2-cyano-N′-(3,4,5-trimethoxybenzylidene)acetohydrazide |
| title_short | Crystal structure and Hirshfeld surface analysis of (E)-2-cyano-N′-(3,4,5-trimethoxybenzylidene)acetohydrazide |
| title_sort | crystal structure and hirshfeld surface analysis of e 2 cyano n 3 4 5 trimethoxybenzylidene acetohydrazide |
| topic | benzohydrazine intermolecular hydrogen bonds hirshfeld surface analysis crystal structure |
| url | https://journals.iucr.org/paper?S2056989025003913 |
| work_keys_str_mv | AT subramaniumamaheswari crystalstructureandhirshfeldsurfaceanalysisofe2cyanon345trimethoxybenzylideneacetohydrazide AT srinivasansenthilkumar crystalstructureandhirshfeldsurfaceanalysisofe2cyanon345trimethoxybenzylideneacetohydrazide AT sivashanmugamselvanayagam crystalstructureandhirshfeldsurfaceanalysisofe2cyanon345trimethoxybenzylideneacetohydrazide |