Synthesis of self-aggregative zinc chlorophylls possessing polymerizable esters as a atable model compound for main light-harvesting antennas of green photosynthetic bacteria
Zinc bacteriochlorophyll-d derivatives possessing a polymerizable moiety at the 17-propionate were prepared as model compounds of natural occurring chlorophylls in the main peripheral antennas of green photosynthetic bacteria (chlorosomes). The synthetic compounds self-aggregated in n...
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| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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Wiley
2006-01-01
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| Series: | International Journal of Photoenergy |
| Online Access: | http://dx.doi.org/10.1155/IJP/2006/90989 |
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| _version_ | 1832567267992272896 |
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| author | Hitoshi Tamiaki Kazuya Nishihara Reiko Shibata |
| author_facet | Hitoshi Tamiaki Kazuya Nishihara Reiko Shibata |
| author_sort | Hitoshi Tamiaki |
| collection | DOAJ |
| description | Zinc bacteriochlorophyll-d derivatives possessing a polymerizable moiety at the
17-propionate were prepared as model compounds of natural occurring chlorophylls
in the main peripheral antennas of green photosynthetic bacteria (chlorosomes).
The synthetic compounds self-aggregated in nonpolar organic solvents as well as
in the solid state to give large oligomers similar to chlorosomal J-aggregates.
Such introduction of the polymerizable groups in the ester did not suppress the ability of
self-aggregation. |
| format | Article |
| id | doaj-art-d4016025279c4c41bd59eddb0108c7ec |
| institution | Kabale University |
| issn | 1110-662X 1687-529X |
| language | English |
| publishDate | 2006-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Photoenergy |
| spelling | doaj-art-d4016025279c4c41bd59eddb0108c7ec2025-02-03T01:01:59ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2006-01-01200610.1155/IJP/2006/9098990989Synthesis of self-aggregative zinc chlorophylls possessing polymerizable esters as a atable model compound for main light-harvesting antennas of green photosynthetic bacteriaHitoshi Tamiaki0Kazuya Nishihara1Reiko Shibata2Department of Bioscience and Biotechnology, Faculty of Science and Engineering, Ritsumeikan University, Shiga, Kusatsu 525 8577, JapanDepartment of Bioscience and Biotechnology, Faculty of Science and Engineering, Ritsumeikan University, Shiga, Kusatsu 525 8577, JapanDepartment of Bioscience and Biotechnology, Faculty of Science and Engineering, Ritsumeikan University, Shiga, Kusatsu 525 8577, JapanZinc bacteriochlorophyll-d derivatives possessing a polymerizable moiety at the 17-propionate were prepared as model compounds of natural occurring chlorophylls in the main peripheral antennas of green photosynthetic bacteria (chlorosomes). The synthetic compounds self-aggregated in nonpolar organic solvents as well as in the solid state to give large oligomers similar to chlorosomal J-aggregates. Such introduction of the polymerizable groups in the ester did not suppress the ability of self-aggregation.http://dx.doi.org/10.1155/IJP/2006/90989 |
| spellingShingle | Hitoshi Tamiaki Kazuya Nishihara Reiko Shibata Synthesis of self-aggregative zinc chlorophylls possessing polymerizable esters as a atable model compound for main light-harvesting antennas of green photosynthetic bacteria International Journal of Photoenergy |
| title | Synthesis of self-aggregative zinc chlorophylls possessing polymerizable esters as a atable model compound for main light-harvesting antennas of green photosynthetic bacteria |
| title_full | Synthesis of self-aggregative zinc chlorophylls possessing polymerizable esters as a atable model compound for main light-harvesting antennas of green photosynthetic bacteria |
| title_fullStr | Synthesis of self-aggregative zinc chlorophylls possessing polymerizable esters as a atable model compound for main light-harvesting antennas of green photosynthetic bacteria |
| title_full_unstemmed | Synthesis of self-aggregative zinc chlorophylls possessing polymerizable esters as a atable model compound for main light-harvesting antennas of green photosynthetic bacteria |
| title_short | Synthesis of self-aggregative zinc chlorophylls possessing polymerizable esters as a atable model compound for main light-harvesting antennas of green photosynthetic bacteria |
| title_sort | synthesis of self aggregative zinc chlorophylls possessing polymerizable esters as a atable model compound for main light harvesting antennas of green photosynthetic bacteria |
| url | http://dx.doi.org/10.1155/IJP/2006/90989 |
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