Preparation of Soft Magnetic Fe-Ni-Pb-B Alloy Nanoparticles by Room Temperature Solid-Solid Reaction

The Fe-Ni-Pb-B alloy nanoparticles was prepared by a solid-solid chemical reaction of ferric trichloride, nickel chloride, lead acetate, and potassium borohydride powders at room temperature. The research results of the ICP and thermal analysis indicate that the resultants are composed of iron, nick...

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Main Authors: Guo-Qing Zhong, Qin Zhong
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:The Scientific World Journal
Online Access:http://dx.doi.org/10.1155/2013/946897
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author Guo-Qing Zhong
Qin Zhong
author_facet Guo-Qing Zhong
Qin Zhong
author_sort Guo-Qing Zhong
collection DOAJ
description The Fe-Ni-Pb-B alloy nanoparticles was prepared by a solid-solid chemical reaction of ferric trichloride, nickel chloride, lead acetate, and potassium borohydride powders at room temperature. The research results of the ICP and thermal analysis indicate that the resultants are composed of iron, nickel, lead, boron, and PVP, and the component of the alloy is connected with the mole ratio of potassium borohydride and the metal salts. The TEM images show that the resultants are ultrafine and spherical particles, and the particle size is about a diameter of 25 nm. The largest saturation magnetization value of the 21.18 emu g−1 is obtained in the Fe-Ni-Pb-B alloy. The mechanism of the preparation reaction for the Fe-Ni-Pb-B multicomponent alloys is discussed.
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publishDate 2013-01-01
publisher Wiley
record_format Article
series The Scientific World Journal
spelling doaj-art-d3bdeaa3b22a4f6aa1a8311ca18b1cb52025-08-20T03:24:12ZengWileyThe Scientific World Journal1537-744X2013-01-01201310.1155/2013/946897946897Preparation of Soft Magnetic Fe-Ni-Pb-B Alloy Nanoparticles by Room Temperature Solid-Solid ReactionGuo-Qing Zhong0Qin Zhong1State Key Laboratory Cultivation Base for Nonmetal Composite and Functional Materials, School of Material Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, ChinaState Key Laboratory Cultivation Base for Nonmetal Composite and Functional Materials, School of Material Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, ChinaThe Fe-Ni-Pb-B alloy nanoparticles was prepared by a solid-solid chemical reaction of ferric trichloride, nickel chloride, lead acetate, and potassium borohydride powders at room temperature. The research results of the ICP and thermal analysis indicate that the resultants are composed of iron, nickel, lead, boron, and PVP, and the component of the alloy is connected with the mole ratio of potassium borohydride and the metal salts. The TEM images show that the resultants are ultrafine and spherical particles, and the particle size is about a diameter of 25 nm. The largest saturation magnetization value of the 21.18 emu g−1 is obtained in the Fe-Ni-Pb-B alloy. The mechanism of the preparation reaction for the Fe-Ni-Pb-B multicomponent alloys is discussed.http://dx.doi.org/10.1155/2013/946897
spellingShingle Guo-Qing Zhong
Qin Zhong
Preparation of Soft Magnetic Fe-Ni-Pb-B Alloy Nanoparticles by Room Temperature Solid-Solid Reaction
The Scientific World Journal
title Preparation of Soft Magnetic Fe-Ni-Pb-B Alloy Nanoparticles by Room Temperature Solid-Solid Reaction
title_full Preparation of Soft Magnetic Fe-Ni-Pb-B Alloy Nanoparticles by Room Temperature Solid-Solid Reaction
title_fullStr Preparation of Soft Magnetic Fe-Ni-Pb-B Alloy Nanoparticles by Room Temperature Solid-Solid Reaction
title_full_unstemmed Preparation of Soft Magnetic Fe-Ni-Pb-B Alloy Nanoparticles by Room Temperature Solid-Solid Reaction
title_short Preparation of Soft Magnetic Fe-Ni-Pb-B Alloy Nanoparticles by Room Temperature Solid-Solid Reaction
title_sort preparation of soft magnetic fe ni pb b alloy nanoparticles by room temperature solid solid reaction
url http://dx.doi.org/10.1155/2013/946897
work_keys_str_mv AT guoqingzhong preparationofsoftmagneticfenipbballoynanoparticlesbyroomtemperaturesolidsolidreaction
AT qinzhong preparationofsoftmagneticfenipbballoynanoparticlesbyroomtemperaturesolidsolidreaction