Petrochemical Wastewater Treatment by Eggshell Modified Biochar as Adsorbent: Atechno-Economic and Sustainable Approach

Petrochemical industrial wastewater (PIW)contains toluene and xylene (TX), and various organic and inorganic pollutants, causing severe risks to human health if improperly released into the environmental matrices. For the long-term reliability of environmental conservation, this study illustrates th...

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Main Authors: Andy G. Kumi, Mona G. Ibrahim, Manabu Fujii, Mahmoud Nasr
Format: Article
Language:English
Published: SAGE Publishing 2022-01-01
Series:Adsorption Science & Technology
Online Access:http://dx.doi.org/10.1155/2022/2323836
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author Andy G. Kumi
Mona G. Ibrahim
Manabu Fujii
Mahmoud Nasr
author_facet Andy G. Kumi
Mona G. Ibrahim
Manabu Fujii
Mahmoud Nasr
author_sort Andy G. Kumi
collection DOAJ
description Petrochemical industrial wastewater (PIW)contains toluene and xylene (TX), and various organic and inorganic pollutants, causing severe risks to human health if improperly released into the environmental matrices. For the long-term reliability of environmental conservation, this study illustrates the interlinkage between PIW treatment and the three pillars of sustainable development. Sewage sludge biochar was modified with eggshell, showing a relatively high fixed C content (increase in carbonization degree), and small O/C and N/C ratios. The prepared biochar was employed for TX adsorption in mono-component solutions, giving removal efficiencies of 79.1% (T) and 86.6% (X), at pH =10, adsorbent dosage =2 g/L, and Co =40 mg/L within 60 min. The main adsorption mechanism was physisorption, including precipitation/pore-filling, π-π dispersive interaction, and van der Waals force. The modified biochar also treated real PIW under five adsorption/regeneration cycles, providing essential steps toward large-scale applications. According to an economic feasibility estimation, the biochar application for treating 1 m3 of PIW would offer a payback period of 6.9 yr. The study outputs could be linked to the restoration of water-related ecosystems, biochar modification for industrial applications, and climate change mitigation, adopting the 2030 agenda and its sustainable development goals (SDGs).
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institution Kabale University
issn 2048-4038
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publishDate 2022-01-01
publisher SAGE Publishing
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series Adsorption Science & Technology
spelling doaj-art-d3a8c8e82fee431aa6b191792bc004462025-01-02T22:54:08ZengSAGE PublishingAdsorption Science & Technology2048-40382022-01-01202210.1155/2022/2323836Petrochemical Wastewater Treatment by Eggshell Modified Biochar as Adsorbent: Atechno-Economic and Sustainable ApproachAndy G. Kumi0Mona G. Ibrahim1Manabu Fujii2Mahmoud Nasr3Environmental Engineering DepartmentEnvironmental Engineering DepartmentEnvironmental Engineering DepartmentEnvironmental Engineering DepartmentPetrochemical industrial wastewater (PIW)contains toluene and xylene (TX), and various organic and inorganic pollutants, causing severe risks to human health if improperly released into the environmental matrices. For the long-term reliability of environmental conservation, this study illustrates the interlinkage between PIW treatment and the three pillars of sustainable development. Sewage sludge biochar was modified with eggshell, showing a relatively high fixed C content (increase in carbonization degree), and small O/C and N/C ratios. The prepared biochar was employed for TX adsorption in mono-component solutions, giving removal efficiencies of 79.1% (T) and 86.6% (X), at pH =10, adsorbent dosage =2 g/L, and Co =40 mg/L within 60 min. The main adsorption mechanism was physisorption, including precipitation/pore-filling, π-π dispersive interaction, and van der Waals force. The modified biochar also treated real PIW under five adsorption/regeneration cycles, providing essential steps toward large-scale applications. According to an economic feasibility estimation, the biochar application for treating 1 m3 of PIW would offer a payback period of 6.9 yr. The study outputs could be linked to the restoration of water-related ecosystems, biochar modification for industrial applications, and climate change mitigation, adopting the 2030 agenda and its sustainable development goals (SDGs).http://dx.doi.org/10.1155/2022/2323836
spellingShingle Andy G. Kumi
Mona G. Ibrahim
Manabu Fujii
Mahmoud Nasr
Petrochemical Wastewater Treatment by Eggshell Modified Biochar as Adsorbent: Atechno-Economic and Sustainable Approach
Adsorption Science & Technology
title Petrochemical Wastewater Treatment by Eggshell Modified Biochar as Adsorbent: Atechno-Economic and Sustainable Approach
title_full Petrochemical Wastewater Treatment by Eggshell Modified Biochar as Adsorbent: Atechno-Economic and Sustainable Approach
title_fullStr Petrochemical Wastewater Treatment by Eggshell Modified Biochar as Adsorbent: Atechno-Economic and Sustainable Approach
title_full_unstemmed Petrochemical Wastewater Treatment by Eggshell Modified Biochar as Adsorbent: Atechno-Economic and Sustainable Approach
title_short Petrochemical Wastewater Treatment by Eggshell Modified Biochar as Adsorbent: Atechno-Economic and Sustainable Approach
title_sort petrochemical wastewater treatment by eggshell modified biochar as adsorbent atechno economic and sustainable approach
url http://dx.doi.org/10.1155/2022/2323836
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AT manabufujii petrochemicalwastewatertreatmentbyeggshellmodifiedbiocharasadsorbentatechnoeconomicandsustainableapproach
AT mahmoudnasr petrochemicalwastewatertreatmentbyeggshellmodifiedbiocharasadsorbentatechnoeconomicandsustainableapproach