Fabrication of SO42--ISE based on Copolymer of Methyl methacrylate-butyl acrylate (MB28) Thin-film and Graphite Pencil Electrode (GPE)

The SO42- -ISE sensor fabrication process based on MB28 and GPE membranes has been successfully implemented. In this study, the MB28 membrane was prepared using the photo-polymer technique on the surface of a polypyrrole with KCl as a dopant layer previously coated on the GPE surface. In this study,...

Full description

Saved in:
Bibliographic Details
Main Authors: Alva Sagir, Arwati I Gusti Ayu, Hasbullah Siti Aisyah, Aziz Aiman Sajidah Abdul, Khaerudini Deni Shidqi
Format: Article
Language:English
Published: EDP Sciences 2025-01-01
Series:BIO Web of Conferences
Online Access:https://www.bio-conferences.org/articles/bioconf/pdf/2025/10/bioconf_safe24_03005.pdf
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1825206597848137728
author Alva Sagir
Arwati I Gusti Ayu
Hasbullah Siti Aisyah
Aziz Aiman Sajidah Abdul
Khaerudini Deni Shidqi
author_facet Alva Sagir
Arwati I Gusti Ayu
Hasbullah Siti Aisyah
Aziz Aiman Sajidah Abdul
Khaerudini Deni Shidqi
author_sort Alva Sagir
collection DOAJ
description The SO42- -ISE sensor fabrication process based on MB28 and GPE membranes has been successfully implemented. In this study, the MB28 membrane was prepared using the photo-polymer technique on the surface of a polypyrrole with KCl as a dopant layer previously coated on the GPE surface. In this study, the optimum composition of the MB28 membrane consisted of 1 mg of lipophilic salt TDDACl and a 1:2 mole ratio sulfate ionophore, where the resulting slope approached the Nernstian number with a linear range between 0.1 -10-6 M. Meanwhile, selectivity tests were carried out using the FIM, where SO42--ISE provides good selectivity to I-, Cl- and NO3- ions. This fabricated sensor can work for 12 days at pH 3-9 and provides performance comparable to the gravimetric method according to SNI 19-6964.5-2003.
format Article
id doaj-art-d3716145c43943eba8b29757ceecc597
institution Kabale University
issn 2117-4458
language English
publishDate 2025-01-01
publisher EDP Sciences
record_format Article
series BIO Web of Conferences
spelling doaj-art-d3716145c43943eba8b29757ceecc5972025-02-07T08:20:35ZengEDP SciencesBIO Web of Conferences2117-44582025-01-011590300510.1051/bioconf/202515903005bioconf_safe24_03005Fabrication of SO42--ISE based on Copolymer of Methyl methacrylate-butyl acrylate (MB28) Thin-film and Graphite Pencil Electrode (GPE)Alva Sagir0Arwati I Gusti Ayu1Hasbullah Siti Aisyah2Aziz Aiman Sajidah Abdul3Khaerudini Deni Shidqi4Mechanical Engineering Department, Universitas Mercu BuanaMechanical Engineering Department, Universitas Mercu BuanaDepartment of Chemical Sciences, Faculty of Science and Technology, Universiti Kebangsaan MalaysiaFlexible Electronics Lab, MIMOS BerhadMechanical Engineering Department, Universitas Mercu BuanaThe SO42- -ISE sensor fabrication process based on MB28 and GPE membranes has been successfully implemented. In this study, the MB28 membrane was prepared using the photo-polymer technique on the surface of a polypyrrole with KCl as a dopant layer previously coated on the GPE surface. In this study, the optimum composition of the MB28 membrane consisted of 1 mg of lipophilic salt TDDACl and a 1:2 mole ratio sulfate ionophore, where the resulting slope approached the Nernstian number with a linear range between 0.1 -10-6 M. Meanwhile, selectivity tests were carried out using the FIM, where SO42--ISE provides good selectivity to I-, Cl- and NO3- ions. This fabricated sensor can work for 12 days at pH 3-9 and provides performance comparable to the gravimetric method according to SNI 19-6964.5-2003.https://www.bio-conferences.org/articles/bioconf/pdf/2025/10/bioconf_safe24_03005.pdf
spellingShingle Alva Sagir
Arwati I Gusti Ayu
Hasbullah Siti Aisyah
Aziz Aiman Sajidah Abdul
Khaerudini Deni Shidqi
Fabrication of SO42--ISE based on Copolymer of Methyl methacrylate-butyl acrylate (MB28) Thin-film and Graphite Pencil Electrode (GPE)
BIO Web of Conferences
title Fabrication of SO42--ISE based on Copolymer of Methyl methacrylate-butyl acrylate (MB28) Thin-film and Graphite Pencil Electrode (GPE)
title_full Fabrication of SO42--ISE based on Copolymer of Methyl methacrylate-butyl acrylate (MB28) Thin-film and Graphite Pencil Electrode (GPE)
title_fullStr Fabrication of SO42--ISE based on Copolymer of Methyl methacrylate-butyl acrylate (MB28) Thin-film and Graphite Pencil Electrode (GPE)
title_full_unstemmed Fabrication of SO42--ISE based on Copolymer of Methyl methacrylate-butyl acrylate (MB28) Thin-film and Graphite Pencil Electrode (GPE)
title_short Fabrication of SO42--ISE based on Copolymer of Methyl methacrylate-butyl acrylate (MB28) Thin-film and Graphite Pencil Electrode (GPE)
title_sort fabrication of so42 ise based on copolymer of methyl methacrylate butyl acrylate mb28 thin film and graphite pencil electrode gpe
url https://www.bio-conferences.org/articles/bioconf/pdf/2025/10/bioconf_safe24_03005.pdf
work_keys_str_mv AT alvasagir fabricationofso42isebasedoncopolymerofmethylmethacrylatebutylacrylatemb28thinfilmandgraphitepencilelectrodegpe
AT arwatiigustiayu fabricationofso42isebasedoncopolymerofmethylmethacrylatebutylacrylatemb28thinfilmandgraphitepencilelectrodegpe
AT hasbullahsitiaisyah fabricationofso42isebasedoncopolymerofmethylmethacrylatebutylacrylatemb28thinfilmandgraphitepencilelectrodegpe
AT azizaimansajidahabdul fabricationofso42isebasedoncopolymerofmethylmethacrylatebutylacrylatemb28thinfilmandgraphitepencilelectrodegpe
AT khaerudinidenishidqi fabricationofso42isebasedoncopolymerofmethylmethacrylatebutylacrylatemb28thinfilmandgraphitepencilelectrodegpe