Highly efficient synthesis of pyrimidine-5-carbonitrile derivatives over a robust biowaste bone char-Bronsted solid acid catalyst
Abstract In this study, the conversion of bones (waste of food industry) into bone char is described. The presence of calcium phosphate and graphitic carbon gives bone char unique properties, with different possible uses. The catalytic behavior of bone char modified with chlorosulfonic acid is teste...
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Nature Portfolio
2024-12-01
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| Series: | Scientific Reports |
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| Online Access: | https://doi.org/10.1038/s41598-024-82040-3 |
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| author | Zahra Siahpour Maryam Hajjami |
| author_facet | Zahra Siahpour Maryam Hajjami |
| author_sort | Zahra Siahpour |
| collection | DOAJ |
| description | Abstract In this study, the conversion of bones (waste of food industry) into bone char is described. The presence of calcium phosphate and graphitic carbon gives bone char unique properties, with different possible uses. The catalytic behavior of bone char modified with chlorosulfonic acid is tested as reusable and eco-friendly solid acid biocatalyst in synthesis of pyrimidine-5-carbonitrile derivatives. The catalyst properties were characterized by different techniques such as FT-IR, BET, SEM, TEM, TGA, EDS and XRD. The bone char catalyst can be reused several times without reducing catalyst efficiency. In addition to the various reported benefits, the first use of bone char as a catalyst support for organic synthesis is an important novelty of this study. |
| format | Article |
| id | doaj-art-d32f9f8d75ae47f7838b4d880a358d6f |
| institution | OA Journals |
| issn | 2045-2322 |
| language | English |
| publishDate | 2024-12-01 |
| publisher | Nature Portfolio |
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| series | Scientific Reports |
| spelling | doaj-art-d32f9f8d75ae47f7838b4d880a358d6f2025-08-20T02:20:45ZengNature PortfolioScientific Reports2045-23222024-12-0114111610.1038/s41598-024-82040-3Highly efficient synthesis of pyrimidine-5-carbonitrile derivatives over a robust biowaste bone char-Bronsted solid acid catalystZahra Siahpour0Maryam Hajjami1Department of Organic Chemistry, Faculty of Chemistry and Petroleum Sciences, Bu-Ali Sina UniversityDepartment of Organic Chemistry, Faculty of Chemistry and Petroleum Sciences, Bu-Ali Sina UniversityAbstract In this study, the conversion of bones (waste of food industry) into bone char is described. The presence of calcium phosphate and graphitic carbon gives bone char unique properties, with different possible uses. The catalytic behavior of bone char modified with chlorosulfonic acid is tested as reusable and eco-friendly solid acid biocatalyst in synthesis of pyrimidine-5-carbonitrile derivatives. The catalyst properties were characterized by different techniques such as FT-IR, BET, SEM, TEM, TGA, EDS and XRD. The bone char catalyst can be reused several times without reducing catalyst efficiency. In addition to the various reported benefits, the first use of bone char as a catalyst support for organic synthesis is an important novelty of this study.https://doi.org/10.1038/s41598-024-82040-3Bone charPyrimidine-5-carbonitrileNano catalystGreen catalystHydroxy apatite |
| spellingShingle | Zahra Siahpour Maryam Hajjami Highly efficient synthesis of pyrimidine-5-carbonitrile derivatives over a robust biowaste bone char-Bronsted solid acid catalyst Scientific Reports Bone char Pyrimidine-5-carbonitrile Nano catalyst Green catalyst Hydroxy apatite |
| title | Highly efficient synthesis of pyrimidine-5-carbonitrile derivatives over a robust biowaste bone char-Bronsted solid acid catalyst |
| title_full | Highly efficient synthesis of pyrimidine-5-carbonitrile derivatives over a robust biowaste bone char-Bronsted solid acid catalyst |
| title_fullStr | Highly efficient synthesis of pyrimidine-5-carbonitrile derivatives over a robust biowaste bone char-Bronsted solid acid catalyst |
| title_full_unstemmed | Highly efficient synthesis of pyrimidine-5-carbonitrile derivatives over a robust biowaste bone char-Bronsted solid acid catalyst |
| title_short | Highly efficient synthesis of pyrimidine-5-carbonitrile derivatives over a robust biowaste bone char-Bronsted solid acid catalyst |
| title_sort | highly efficient synthesis of pyrimidine 5 carbonitrile derivatives over a robust biowaste bone char bronsted solid acid catalyst |
| topic | Bone char Pyrimidine-5-carbonitrile Nano catalyst Green catalyst Hydroxy apatite |
| url | https://doi.org/10.1038/s41598-024-82040-3 |
| work_keys_str_mv | AT zahrasiahpour highlyefficientsynthesisofpyrimidine5carbonitrilederivativesoverarobustbiowastebonecharbronstedsolidacidcatalyst AT maryamhajjami highlyefficientsynthesisofpyrimidine5carbonitrilederivativesoverarobustbiowastebonecharbronstedsolidacidcatalyst |