Calcium Pretreated Hevea brasiliensis Sawdust for Copper Removal: Batch and Column Study

Calcium pretreated Hevea brasiliensis sawdust has been used as an effective and efficient adsorbent for the removal of copper ion from the contaminated water. Batch experiment was conducted to check the effect of pH, initial concentration, contact time, and adsorbent dose. The results conclude that...

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Main Authors: Swarup Biswas, Umesh Mishra
Format: Article
Language:English
Published: Wiley 2015-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2015/495257
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author Swarup Biswas
Umesh Mishra
author_facet Swarup Biswas
Umesh Mishra
author_sort Swarup Biswas
collection DOAJ
description Calcium pretreated Hevea brasiliensis sawdust has been used as an effective and efficient adsorbent for the removal of copper ion from the contaminated water. Batch experiment was conducted to check the effect of pH, initial concentration, contact time, and adsorbent dose. The results conclude that adsorption capacity of adsorbent was influenced by operating parameters. Maximum adsorption capacity found from the batch adsorption process was 37.74 mg/g at pH of 5.6. Various isotherm models like Langmuir, Freundlich, and Temkin were used to compare the theoretical and experimental data, whereas the pseudo-first-order, pseudo-second-order, and intraparticle diffusion models were applied to study the kinetics of the batch adsorption process. Dynamic studies were also conducted in packed-bed column using different bed depths and the maximum adsorption capacity of 34.29 was achieved. Characterizations of the adsorbent were done by Fourier transform infrared spectroscopy, scanning electron microscope, and energy dispersive X-ray spectroscopy.
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spelling doaj-art-d2dc83f442f94b1b842166d94a182cb72025-02-03T01:07:26ZengWileyJournal of Chemistry2090-90632090-90712015-01-01201510.1155/2015/495257495257Calcium Pretreated Hevea brasiliensis Sawdust for Copper Removal: Batch and Column StudySwarup Biswas0Umesh Mishra1Department of Environmental Engineering, NIT Agartala, Tripura 799046, IndiaDepartment of Civil Engineering NIT Agartala, Tripura 799046, IndiaCalcium pretreated Hevea brasiliensis sawdust has been used as an effective and efficient adsorbent for the removal of copper ion from the contaminated water. Batch experiment was conducted to check the effect of pH, initial concentration, contact time, and adsorbent dose. The results conclude that adsorption capacity of adsorbent was influenced by operating parameters. Maximum adsorption capacity found from the batch adsorption process was 37.74 mg/g at pH of 5.6. Various isotherm models like Langmuir, Freundlich, and Temkin were used to compare the theoretical and experimental data, whereas the pseudo-first-order, pseudo-second-order, and intraparticle diffusion models were applied to study the kinetics of the batch adsorption process. Dynamic studies were also conducted in packed-bed column using different bed depths and the maximum adsorption capacity of 34.29 was achieved. Characterizations of the adsorbent were done by Fourier transform infrared spectroscopy, scanning electron microscope, and energy dispersive X-ray spectroscopy.http://dx.doi.org/10.1155/2015/495257
spellingShingle Swarup Biswas
Umesh Mishra
Calcium Pretreated Hevea brasiliensis Sawdust for Copper Removal: Batch and Column Study
Journal of Chemistry
title Calcium Pretreated Hevea brasiliensis Sawdust for Copper Removal: Batch and Column Study
title_full Calcium Pretreated Hevea brasiliensis Sawdust for Copper Removal: Batch and Column Study
title_fullStr Calcium Pretreated Hevea brasiliensis Sawdust for Copper Removal: Batch and Column Study
title_full_unstemmed Calcium Pretreated Hevea brasiliensis Sawdust for Copper Removal: Batch and Column Study
title_short Calcium Pretreated Hevea brasiliensis Sawdust for Copper Removal: Batch and Column Study
title_sort calcium pretreated hevea brasiliensis sawdust for copper removal batch and column study
url http://dx.doi.org/10.1155/2015/495257
work_keys_str_mv AT swarupbiswas calciumpretreatedheveabrasiliensissawdustforcopperremovalbatchandcolumnstudy
AT umeshmishra calciumpretreatedheveabrasiliensissawdustforcopperremovalbatchandcolumnstudy