Calcium Pretreated Hevea brasiliensis Sawdust for Copper Removal: Batch and Column Study
Calcium pretreated Hevea brasiliensis sawdust has been used as an effective and efficient adsorbent for the removal of copper ion from the contaminated water. Batch experiment was conducted to check the effect of pH, initial concentration, contact time, and adsorbent dose. The results conclude that...
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Wiley
2015-01-01
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Series: | Journal of Chemistry |
Online Access: | http://dx.doi.org/10.1155/2015/495257 |
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author | Swarup Biswas Umesh Mishra |
author_facet | Swarup Biswas Umesh Mishra |
author_sort | Swarup Biswas |
collection | DOAJ |
description | Calcium pretreated Hevea brasiliensis sawdust has been used as an effective and efficient adsorbent for the removal of copper ion from the contaminated water. Batch experiment was conducted to check the effect of pH, initial concentration, contact time, and adsorbent dose. The results conclude that adsorption capacity of adsorbent was influenced by operating parameters. Maximum adsorption capacity found from the batch adsorption process was 37.74 mg/g at pH of 5.6. Various isotherm models like Langmuir, Freundlich, and Temkin were used to compare the theoretical and experimental data, whereas the pseudo-first-order, pseudo-second-order, and intraparticle diffusion models were applied to study the kinetics of the batch adsorption process. Dynamic studies were also conducted in packed-bed column using different bed depths and the maximum adsorption capacity of 34.29 was achieved. Characterizations of the adsorbent were done by Fourier transform infrared spectroscopy, scanning electron microscope, and energy dispersive X-ray spectroscopy. |
format | Article |
id | doaj-art-d2dc83f442f94b1b842166d94a182cb7 |
institution | Kabale University |
issn | 2090-9063 2090-9071 |
language | English |
publishDate | 2015-01-01 |
publisher | Wiley |
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series | Journal of Chemistry |
spelling | doaj-art-d2dc83f442f94b1b842166d94a182cb72025-02-03T01:07:26ZengWileyJournal of Chemistry2090-90632090-90712015-01-01201510.1155/2015/495257495257Calcium Pretreated Hevea brasiliensis Sawdust for Copper Removal: Batch and Column StudySwarup Biswas0Umesh Mishra1Department of Environmental Engineering, NIT Agartala, Tripura 799046, IndiaDepartment of Civil Engineering NIT Agartala, Tripura 799046, IndiaCalcium pretreated Hevea brasiliensis sawdust has been used as an effective and efficient adsorbent for the removal of copper ion from the contaminated water. Batch experiment was conducted to check the effect of pH, initial concentration, contact time, and adsorbent dose. The results conclude that adsorption capacity of adsorbent was influenced by operating parameters. Maximum adsorption capacity found from the batch adsorption process was 37.74 mg/g at pH of 5.6. Various isotherm models like Langmuir, Freundlich, and Temkin were used to compare the theoretical and experimental data, whereas the pseudo-first-order, pseudo-second-order, and intraparticle diffusion models were applied to study the kinetics of the batch adsorption process. Dynamic studies were also conducted in packed-bed column using different bed depths and the maximum adsorption capacity of 34.29 was achieved. Characterizations of the adsorbent were done by Fourier transform infrared spectroscopy, scanning electron microscope, and energy dispersive X-ray spectroscopy.http://dx.doi.org/10.1155/2015/495257 |
spellingShingle | Swarup Biswas Umesh Mishra Calcium Pretreated Hevea brasiliensis Sawdust for Copper Removal: Batch and Column Study Journal of Chemistry |
title | Calcium Pretreated Hevea brasiliensis Sawdust for Copper Removal: Batch and Column Study |
title_full | Calcium Pretreated Hevea brasiliensis Sawdust for Copper Removal: Batch and Column Study |
title_fullStr | Calcium Pretreated Hevea brasiliensis Sawdust for Copper Removal: Batch and Column Study |
title_full_unstemmed | Calcium Pretreated Hevea brasiliensis Sawdust for Copper Removal: Batch and Column Study |
title_short | Calcium Pretreated Hevea brasiliensis Sawdust for Copper Removal: Batch and Column Study |
title_sort | calcium pretreated hevea brasiliensis sawdust for copper removal batch and column study |
url | http://dx.doi.org/10.1155/2015/495257 |
work_keys_str_mv | AT swarupbiswas calciumpretreatedheveabrasiliensissawdustforcopperremovalbatchandcolumnstudy AT umeshmishra calciumpretreatedheveabrasiliensissawdustforcopperremovalbatchandcolumnstudy |