The importance and ubiquity of glycosides in both compounds of interest and biological processes make these biomolecules an interesting topic of study. The development of unnatural analogues is equally compelling and has already led to the production of several marketed drugs. The discovery of novel...

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Main Author: Ferry, Angélique
Format: Article
Language:English
Published: Académie des sciences 2025-02-01
Series:Comptes Rendus. Chimie
Subjects:
Online Access:https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.373/
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author Ferry, Angélique
author_facet Ferry, Angélique
author_sort Ferry, Angélique
collection DOAJ
description The importance and ubiquity of glycosides in both compounds of interest and biological processes make these biomolecules an interesting topic of study. The development of unnatural analogues is equally compelling and has already led to the production of several marketed drugs. The discovery of novel carbohydrates is thus a field of interest. In order to open up this chemical space, it is necessary to set up new and efficient synthetic methods, which lead to diverse unnatural glycosides, some of which could become beneficial new compounds. This account deals with the benefits presented by metal-catalyzed reactions, especially cross-couplings and C–H functionalization, to enable glycoside diversity.
format Article
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institution Kabale University
issn 1878-1543
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series Comptes Rendus. Chimie
spelling doaj-art-d2a6c0dfaa53459e95488ccb595190982025-08-20T03:58:18ZengAcadémie des sciencesComptes Rendus. Chimie1878-15432025-02-0128G119921310.5802/crchim.37310.5802/crchim.373Ferry, Angélique0https://orcid.org/0000-0001-9141-5479CY Cergy-Paris Université, BioCIS, CNRS, 5 mail Gay-Lussac, 95000 Cergy-Pontoise cedex, France; Institut universitaire de France (IUF), France; Université Paris-Saclay, CNRS, BioCIS, 91400, Orsay, FranceThe importance and ubiquity of glycosides in both compounds of interest and biological processes make these biomolecules an interesting topic of study. The development of unnatural analogues is equally compelling and has already led to the production of several marketed drugs. The discovery of novel carbohydrates is thus a field of interest. In order to open up this chemical space, it is necessary to set up new and efficient synthetic methods, which lead to diverse unnatural glycosides, some of which could become beneficial new compounds. This account deals with the benefits presented by metal-catalyzed reactions, especially cross-couplings and C–H functionalization, to enable glycoside diversity.https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.373/Metal catalysisGlycalsCross-couplingC–H functionalization
spellingShingle Ferry, Angélique
Comptes Rendus. Chimie
Metal catalysis
Glycals
Cross-coupling
C–H functionalization
topic Metal catalysis
Glycals
Cross-coupling
C–H functionalization
url https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.373/