Synthese neuer perfluorierter Selenocarbonylverbindungen und 1,3-Diselenetane

Reacting Hg(SeC2F5)2 with AlI3 or (C2H5)2AlI in octamethylcyclotetrasiloxane at 40-45 °C and 5∙10-3 Torr gives trifluoromethylselenocarbonylfluoride (1). The deep purple product polymerizes at low temperatures to a white solid, which after pyrolysis leads to a mixture of 1 and cis/trans-2,4-difluor...

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Bibliographic Details
Main Authors: Alois Haas, Michael Spehr
Format: Article
Language:deu
Published: Swiss Chemical Society 1988-08-01
Series:CHIMIA
Online Access:https://www.chimia.ch/chimia/article/view/9864
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