Features of styrene heterogegeous polymerisation under statistic conditions in the presence of emusifiers and co-surfactants
The kinetics of styrene microemulsion formation in the presence of cetyl alcohol, n-dodecylmercaptan (n-DDM), and mixtures of both substances under conditions close to the emulsion polymerization was investigated. It was shown that cetyl alcohol and dodecylmercaptan differently influence under simil...
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| Format: | Article |
| Language: | Russian |
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MIREA - Russian Technological University
2011-08-01
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| Series: | Тонкие химические технологии |
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| Online Access: | https://www.finechem-mirea.ru/jour/article/view/819 |
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| author | S. V. Zhachenkov I. A. Gritskova S. M. Levachev M Khaddazh |
| author_facet | S. V. Zhachenkov I. A. Gritskova S. M. Levachev M Khaddazh |
| author_sort | S. V. Zhachenkov |
| collection | DOAJ |
| description | The kinetics of styrene microemulsion formation in the presence of cetyl alcohol, n-dodecylmercaptan (n-DDM), and mixtures of both substances under conditions close to the emulsion polymerization was investigated. It was shown that cetyl alcohol and dodecylmercaptan differently influence under similar conditions on the intensity of the microdroplet creation on the phase boundary and on the rate of polymerization. It was shown that the concentration of n-DDM in the place of the polymerization corresponds to its value in the polymerization recipe only in the case of presence of more surface-active emulsifiers than n-DDM. |
| format | Article |
| id | doaj-art-d2835ac0f83a46afadc7e50002f1cd5c |
| institution | Kabale University |
| issn | 2410-6593 2686-7575 |
| language | Russian |
| publishDate | 2011-08-01 |
| publisher | MIREA - Russian Technological University |
| record_format | Article |
| series | Тонкие химические технологии |
| spelling | doaj-art-d2835ac0f83a46afadc7e50002f1cd5c2025-08-20T03:56:24ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752011-08-01648588813Features of styrene heterogegeous polymerisation under statistic conditions in the presence of emusifiers and co-surfactantsS. V. Zhachenkov0I. A. Gritskova1S. M. Levachev2M Khaddazh3M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571МГУ им. М.В.ЛомоносоваThe kinetics of styrene microemulsion formation in the presence of cetyl alcohol, n-dodecylmercaptan (n-DDM), and mixtures of both substances under conditions close to the emulsion polymerization was investigated. It was shown that cetyl alcohol and dodecylmercaptan differently influence under similar conditions on the intensity of the microdroplet creation on the phase boundary and on the rate of polymerization. It was shown that the concentration of n-DDM in the place of the polymerization corresponds to its value in the polymerization recipe only in the case of presence of more surface-active emulsifiers than n-DDM.https://www.finechem-mirea.ru/jour/article/view/819quasispontanuous emulsifying of monomer at the interface surfaceadsorption layerco-surfactantcetyl alcoholn-dodecylmercaptanmolecular mass of polymerpolystyrene molecular mass distribution |
| spellingShingle | S. V. Zhachenkov I. A. Gritskova S. M. Levachev M Khaddazh Features of styrene heterogegeous polymerisation under statistic conditions in the presence of emusifiers and co-surfactants Тонкие химические технологии quasispontanuous emulsifying of monomer at the interface surface adsorption layer co-surfactant cetyl alcohol n-dodecylmercaptan molecular mass of polymer polystyrene molecular mass distribution |
| title | Features of styrene heterogegeous polymerisation under statistic conditions in the presence of emusifiers and co-surfactants |
| title_full | Features of styrene heterogegeous polymerisation under statistic conditions in the presence of emusifiers and co-surfactants |
| title_fullStr | Features of styrene heterogegeous polymerisation under statistic conditions in the presence of emusifiers and co-surfactants |
| title_full_unstemmed | Features of styrene heterogegeous polymerisation under statistic conditions in the presence of emusifiers and co-surfactants |
| title_short | Features of styrene heterogegeous polymerisation under statistic conditions in the presence of emusifiers and co-surfactants |
| title_sort | features of styrene heterogegeous polymerisation under statistic conditions in the presence of emusifiers and co surfactants |
| topic | quasispontanuous emulsifying of monomer at the interface surface adsorption layer co-surfactant cetyl alcohol n-dodecylmercaptan molecular mass of polymer polystyrene molecular mass distribution |
| url | https://www.finechem-mirea.ru/jour/article/view/819 |
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