Enhanced photoconductive response of ZnO thin films with the impact of annealing temperatures on structural and optical properties

Abstract Zinc oxide (ZnO) is a versatile material widely used in optoelectronic devices due to its broad bandgap (3.37 eV), high electron mobility, and significant exciton binding energy (60 meV). In this study, ZnO thin films were fabricated on SiO₂/Si substrates via thermal evaporation, followed b...

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Main Authors: Rajkumar C, Arunachalam Arulraj
Format: Article
Language:English
Published: Nature Portfolio 2025-08-01
Series:Scientific Reports
Subjects:
Online Access:https://doi.org/10.1038/s41598-025-02177-7
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author Rajkumar C
Arunachalam Arulraj
author_facet Rajkumar C
Arunachalam Arulraj
author_sort Rajkumar C
collection DOAJ
description Abstract Zinc oxide (ZnO) is a versatile material widely used in optoelectronic devices due to its broad bandgap (3.37 eV), high electron mobility, and significant exciton binding energy (60 meV). In this study, ZnO thin films were fabricated on SiO₂/Si substrates via thermal evaporation, followed by annealing at 400 °C and 600 °C to investigate the effect of thermal treatment on their structural, optical, and photoconductive properties. X-ray diffraction (XRD) analysis confirmed the formation of the hexagonal wurtzite ZnO structure, with improved crystallinity observed at higher annealing temperatures. The photoconductivity of the films demonstrated enhanced response times and self-powered behavior, particularly in the sample annealed at 600 °C. These findings highlight the potential of ZnO thin films for fast-response photodetection applications and show that controlled annealing significantly influences photosensitivity.
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spelling doaj-art-d275dcebfa0f449c9695412da29ee9b62025-08-20T03:05:27ZengNature PortfolioScientific Reports2045-23222025-08-0115111010.1038/s41598-025-02177-7Enhanced photoconductive response of ZnO thin films with the impact of annealing temperatures on structural and optical propertiesRajkumar C0Arunachalam Arulraj1SANKEN (The Institute of Scientific and Industrial Research), The University of OsakaDepartamento de Electricidad, Facultad de Ingeniería, Universidad Tecnológica MetropolitanaAbstract Zinc oxide (ZnO) is a versatile material widely used in optoelectronic devices due to its broad bandgap (3.37 eV), high electron mobility, and significant exciton binding energy (60 meV). In this study, ZnO thin films were fabricated on SiO₂/Si substrates via thermal evaporation, followed by annealing at 400 °C and 600 °C to investigate the effect of thermal treatment on their structural, optical, and photoconductive properties. X-ray diffraction (XRD) analysis confirmed the formation of the hexagonal wurtzite ZnO structure, with improved crystallinity observed at higher annealing temperatures. The photoconductivity of the films demonstrated enhanced response times and self-powered behavior, particularly in the sample annealed at 600 °C. These findings highlight the potential of ZnO thin films for fast-response photodetection applications and show that controlled annealing significantly influences photosensitivity.https://doi.org/10.1038/s41598-025-02177-7ZnOPhotodetectorSelf-poweredThin filmsPhotoconductivityPhotocurrent
spellingShingle Rajkumar C
Arunachalam Arulraj
Enhanced photoconductive response of ZnO thin films with the impact of annealing temperatures on structural and optical properties
Scientific Reports
ZnO
Photodetector
Self-powered
Thin films
Photoconductivity
Photocurrent
title Enhanced photoconductive response of ZnO thin films with the impact of annealing temperatures on structural and optical properties
title_full Enhanced photoconductive response of ZnO thin films with the impact of annealing temperatures on structural and optical properties
title_fullStr Enhanced photoconductive response of ZnO thin films with the impact of annealing temperatures on structural and optical properties
title_full_unstemmed Enhanced photoconductive response of ZnO thin films with the impact of annealing temperatures on structural and optical properties
title_short Enhanced photoconductive response of ZnO thin films with the impact of annealing temperatures on structural and optical properties
title_sort enhanced photoconductive response of zno thin films with the impact of annealing temperatures on structural and optical properties
topic ZnO
Photodetector
Self-powered
Thin films
Photoconductivity
Photocurrent
url https://doi.org/10.1038/s41598-025-02177-7
work_keys_str_mv AT rajkumarc enhancedphotoconductiveresponseofznothinfilmswiththeimpactofannealingtemperaturesonstructuralandopticalproperties
AT arunachalamarulraj enhancedphotoconductiveresponseofznothinfilmswiththeimpactofannealingtemperaturesonstructuralandopticalproperties