Research progress on the synthesis of energetic N-oxides based on diazine, triazine and tetrazine

The skeleton structures of azine (including diazine, triazine and tetrazine) are widely used as important candidate for building good performance energetic materials due to their uniform electron distribution, planar aromaticity, multi reactive sites and low ring tension. Introducing N-oxide coordin...

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Main Authors: Jiarong Zhang, Huan Huo, Lianjie Zhai, Fuqiang Bi, Bozhou Wang
Format: Article
Language:English
Published: KeAi Communications Co. Ltd. 2025-06-01
Series:FirePhysChem
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Online Access:http://www.sciencedirect.com/science/article/pii/S2667134424000725
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author Jiarong Zhang
Huan Huo
Lianjie Zhai
Fuqiang Bi
Bozhou Wang
author_facet Jiarong Zhang
Huan Huo
Lianjie Zhai
Fuqiang Bi
Bozhou Wang
author_sort Jiarong Zhang
collection DOAJ
description The skeleton structures of azine (including diazine, triazine and tetrazine) are widely used as important candidate for building good performance energetic materials due to their uniform electron distribution, planar aromaticity, multi reactive sites and low ring tension. Introducing N-oxide coordination bonds into azine framework turns out to be an important and highly rewarding protocol for the construction of energetic compounds with balanced performances. A variety of energetic compounds with good comprehensive performances have been designed and synthesized by introducing NO coordination bonds to azine skeletons. In this work, a review of recent research in the synthesis and physicochemical properties of N-oxides energetic compounds based on diazine, triazine and tetrazine skeleton is presented. And the application research progress of typical N-oxides energetic compounds are introduced.
format Article
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institution Kabale University
issn 2667-1344
language English
publishDate 2025-06-01
publisher KeAi Communications Co. Ltd.
record_format Article
series FirePhysChem
spelling doaj-art-d2233014eb1142bda4dc342e9b1a154c2025-08-20T03:26:31ZengKeAi Communications Co. Ltd.FirePhysChem2667-13442025-06-015325127310.1016/j.fpc.2024.10.004Research progress on the synthesis of energetic N-oxides based on diazine, triazine and tetrazineJiarong Zhang0Huan Huo1Lianjie Zhai2Fuqiang Bi3Bozhou Wang4Xi'an Modern Chemistry Research Institute, Xi'an, Shaanxi 710065, ChinaXi'an Modern Chemistry Research Institute, Xi'an, Shaanxi 710065, ChinaXi'an Modern Chemistry Research Institute, Xi'an, Shaanxi 710065, ChinaCorresponding authors.; Xi'an Modern Chemistry Research Institute, Xi'an, Shaanxi 710065, ChinaCorresponding authors.; Xi'an Modern Chemistry Research Institute, Xi'an, Shaanxi 710065, ChinaThe skeleton structures of azine (including diazine, triazine and tetrazine) are widely used as important candidate for building good performance energetic materials due to their uniform electron distribution, planar aromaticity, multi reactive sites and low ring tension. Introducing N-oxide coordination bonds into azine framework turns out to be an important and highly rewarding protocol for the construction of energetic compounds with balanced performances. A variety of energetic compounds with good comprehensive performances have been designed and synthesized by introducing NO coordination bonds to azine skeletons. In this work, a review of recent research in the synthesis and physicochemical properties of N-oxides energetic compounds based on diazine, triazine and tetrazine skeleton is presented. And the application research progress of typical N-oxides energetic compounds are introduced.http://www.sciencedirect.com/science/article/pii/S2667134424000725N-oxide energetic compoundDiazineTriazineTetrazineSynthesisPerformances
spellingShingle Jiarong Zhang
Huan Huo
Lianjie Zhai
Fuqiang Bi
Bozhou Wang
Research progress on the synthesis of energetic N-oxides based on diazine, triazine and tetrazine
FirePhysChem
N-oxide energetic compound
Diazine
Triazine
Tetrazine
Synthesis
Performances
title Research progress on the synthesis of energetic N-oxides based on diazine, triazine and tetrazine
title_full Research progress on the synthesis of energetic N-oxides based on diazine, triazine and tetrazine
title_fullStr Research progress on the synthesis of energetic N-oxides based on diazine, triazine and tetrazine
title_full_unstemmed Research progress on the synthesis of energetic N-oxides based on diazine, triazine and tetrazine
title_short Research progress on the synthesis of energetic N-oxides based on diazine, triazine and tetrazine
title_sort research progress on the synthesis of energetic n oxides based on diazine triazine and tetrazine
topic N-oxide energetic compound
Diazine
Triazine
Tetrazine
Synthesis
Performances
url http://www.sciencedirect.com/science/article/pii/S2667134424000725
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AT lianjiezhai researchprogressonthesynthesisofenergeticnoxidesbasedondiazinetriazineandtetrazine
AT fuqiangbi researchprogressonthesynthesisofenergeticnoxidesbasedondiazinetriazineandtetrazine
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